This work presents the results of five-year investigations (2010-2014) on the content of water-soluble fraction of heavy metals in atmospheric precipitation in Pribaikalye (Russia). The studies have been performed at the urban (Irkutsk) and rural (Listvyanka) sites within the EANET program (Monitoring of Acid Deposition in East Asia) since 2000. Precipitation was sampled during continuous monitoring. In warm period (May-October), atmospheric precipitation was collected by automatic “wet-only” samplers. In cold season, plastic containers were used for snow sampling. Maximal concentrations of the majority of elements were recorded at site Irkutsk, which is subject to higher anthropogenic impact. The exception was for Pb, Ni and Zn characterized by higher acidity, whose content was higher at the rural site. Maximal concentrations of the majority of elements were recorded in spring during the driest period of the year and minimal in summer with the annual maximal amount of precipitation. Correlation analysis revealed high coefficient of interconnection V and Mn with major acid-forming anions and . Maximal correlation coefficient (0.98) was recorded for Co and at site Listvyanka. There was no correlation between pH of atmospheric precipitation and concentrations of all heavy metals, except Pb. The results obtained show higher level of pollution of atmospheric precipitation by heavy metals at monitoring sites in Pribaikalye compared to some European countries.
References
[1]
Nriagu, J.O. and Pacyna, J.M. (1988) Quantitative Assessment of Worldwide Contamination of Air, Water and Soils by Trace Metals. Nature, 333, 134-139.
https://doi.org/10.1038/333134a0
[2]
Pacyna, E.G. and Pacyna, J.M. (2002) Global Emission of Mercury from Anthropogenic Sources in 1995. Water, Air, and Soil Pollution, 137, 143-165.
https://doi.org/10.1023/A:1015502430561
[3]
Kleeman, M.J., Riddle, S.G., Robert, M.A. and Jakober, C.A. (2008) Lubricating oil and Fuel Contributions to Particulate Matter Emissions from Light-Duty Gasoline and Heavy-Duty Diesel Vehicles. Environmental Science & Technology, 42, 235-242. https://doi.org/10.1021/es071054c
[4]
Wiseman, C.L. and Zereini, F. (2009) Airborne Particulate Matter, Platinum Group Elements and Human Health: A Review of Recent Evidence. Science of the Total Environment, 407, 2493-2500. https://doi.org/10.1016/j.scitotenv.2008.12.057
[5]
Dubiella-Jackowska, A., Polkowska, Z. and Namiennik, J. (2009) Platinum Group Elements in the Environment: Emissions and Exposure. Reviews of Environmental Contamination and Toxicology, 199, 111-135.
[6]
Spada, N., Bozlaker, A. and Chellam, S. (2012) Multi-Elemental Characterization of Tunnel and Road Dusts in Houston, Texas Using Dynamic Reaction Cell-Quadrupled-Inductively Coupled Plasma-Mass Spectrometry: Evidence for the Release of Platinum Group and Anthropogenic Metals from Motor Vehicles. Analytica Chimica Acta, 735, 1-8. https://doi.org/10.1016/j.aca.2012.05.026
Dabakhov, M.V., Dabakhova, E.V. and Titova, V.I. (2005) Ekotoksikologiya i problemi standartizatsii. Nizhegorodskaya Gosudarstvennaya Selskokhozyaistvennaya Akademiya. VVAGS, N. Novgorod.
[9]
Berg, T., Aas, W., Pacyna, J., Uggerud, H.T. and Vadset, M. (2008) Atmospheric Trace Metal Concentrations at Norwegian Background Sites during 25 Years and Its Relation to European Emissions. Atmospheric Environment, 42, 7494-7501.
https://doi.org/10.1016/j.atmosenv.2008.05.020
[10]
Kummer, U., Pacyna, J., Pacyna, E. and Friedrich, R. (2009) Assessment of Heavy Metal Releases from the Use Phase of Road Transport in Europe. Atmospheric Environment, 43, 640-647. https://doi.org/10.1016/j.atmosenv.2008.10.007
[11]
Bacardit, M. and Camarero, L. (2010) Atmospherically Deposited Major and Trace Elements in the Winter Snowpack along a Gradient of Altitude in the Central Pyrenees: The Seasonal Record of Long-Range Fluxes over SW Europe. Atmospheric Environment, 44, 582-595. https://doi.org/10.1016/j.atmosenv.2009.06.022
[12]
Connan, O., Maro, D., Hebert, D., Roupsard, P., Goujon, R., Letellier, B. and Le Cavelier, S. (2013) Wet and Dry Deposition of Particles Associated Metals (Cd, Pb, Zn, Ni, Hg) in a Rural Wetland Site, Marais Vernier, France. Atmospheric Environment, 67, 394-403. https://doi.org/10.1016/j.atmosenv.2012.11.029
[13]
Obzor fonovogo sostoyaniya okruzhayuschey sredi na territorii stran Soyuza Nezavisimikh Gosudarstv v 2013 (2014) Institut Globalnogo Klimatai Ekologii Rosgidrometi Rossiyskoy Akademii Nauk, Moskva.
[14]
Obzor zagryazneniya i sostoyaniya okruzhayuschey sredi v Rossiyskoy Federatsii v 2014 (2015) Institut Globalnogo Klimatai Ekologii Rosgidrometi Rossiyskoy AkademiiNauk, Moskva.
[15]
Ezhegodnik. Sostoyaniye zagryazneniya atmosfery v gorodakh na territorii Rossii v 2014 (2015) Rosgidromet, Voeikov, A.I. Glavnaya Geofizicheskaya Observatoriya, Sankt-Peterburg.
[16]
Gadaskina, I.D. and Tolokontsev, N.A. (1988) Yadi vchera i segodnya: Ocherki po istorii yadov. Nauka, Leningrad.
Guidelines for Acid Deposition Monitoring in East Asia (2000) 2nd Interim Scientific Advisory Group Meeting, ADORC Press, Niigata.
[21]
Network Center (2010) Technical Manual for Wet Deposition Monitoring in East Asia. Network Center for EANET Press, Niigata.
[22]
http://kvina.niva.no/intercomparison
[23]
http://www.nilu.no
[24]
http://www.acap.asia/~interlab/os
[25]
http://www.qasac-americas.org
[26]
Izrael, Yu.A., Gruza, V.G., Katsov, V.M. and Meleshko, V.P. (2001) Global Climate Changes. Role of Anthropogenic Impacts. Izhmeneniye globalnogo klimata. Rol antropogennikh vozdeystviy. Meteorologiyai Gidrologiya, 14, 5-21.
[27]
Vinogradova, A.A., Maksimenkov, L.O. and Pogarsky, F.A. (2009) Change of Atmospheric Circulation and Pollution of Environment in Siberia by Industrial Areas of Norilsk and Urals in the Early XXI Century. Izmeneniye atmosfernoy tsirkulyatsii i zagryazneniya okruzhayuschey sredi v Sibiri ot promishlennih rayonov Norilska i Urala v nachale XXI v. Optika Atmosfery i Okeana, 22, 527-534.
[28]
Latysheva, I.V., Ivanova, A.S., Makukhin, V.L. and Mordvinov, V.I. (2004) Air synoptical Features of Southern Cyclones Coming onto Pribaikalye and Their Influence on the Lake Baikal Area. The International Society for Optical Engineering, 5743, 601-605.
[29]
EMEP/CCC (2009) Manual for Sampling and chemical Analysis. EMEP Cooperative Program for Monitoring and Heavy Metals and POP Measurements, NILU: EMEP/CCC.
[30]
Chipanina-Molozhnikova, E.V., Golobokova, L.P., Kuchmenko, E.V., Netsvetaeva, O.G. and Khodzher, T.V. (2007) Conditions for Formation of Chemical Composition of Atmospheric Aerosol and Precipitation over the Baikal Natural Territory. Usloviya formirovaniya himicheskogo sostava atmosfernogo aerosolya i osadkov nad Baikalskoy Prirodnoy Territoriey. Optika Atmosfery i Okeana, 20, 900-905.
[31]
EMEP/CCC (2012) Long-Term Changes of Heavy Metal Transboundary Pollution of the Environment (19902010). NILU: EMEP/CCC.
[32]
Concowe, R. (1999) Emission Inventory Guidebook. RoadTransport, London.
[33]
Netsvetaeva, O.G., Chipanina, E.V., Obolkin, V.A., Zimnik, E.A., Sezko, N.P., Lopatina, I.N. and Khodzher, T.V. (2013) Peculiarities of Chemistry of Atmospheric Precipitation at Stations Listvyanka (Irkutsk Region) and Primorskaya (Primorye Territory). Osobennosti himii atmosfernih osadkov stantsiy Listvyanka (Irkutskaya oblast) iPrimorskaya (Primorskiy kray).Optika Atmosfery i Okeana, 26, 466-471.
[34]
Obolkin, V.A., Netsvetaeva, O.G., Golobokova, L.P., Potemkin, V.L., Zimnik, E.A., Filippova, U.G. and Khodzher, T.V. (2013) Results of Long-Term Investigations on Acid Deposition in Southern Baikal. Rezultati mnogoletnih issledovaniy kislotnikh vipadeniy v rayone Yuzhnogo Baykala. Geografiyai Prirodniye Resursi, 2, 66-73.