Single crystals of the 4,4’-diamoniumdiphenylmethan sulfate hydrate, denoted DDPS, were grown by slow evaporation solution technique at room temperature. The compound was characterized by single crystal X-ray diffraction, IR and thermal analysis (TG-DTA). It crystallizes in the monoclinic system (space group C2/c) with the following unit cell dimensions: a = 17.7635(10) ？, b = 9.3796(10) ？, c = 27.5676(10) ？, β = 97.37(2)°, V = 4555.2(6) ？. The structure was solved by the direct method and refined to final R value of 0.0472 for 2108 independent reflections. The anions are hydrogen bonded to each other, forming clusters [HS2O8]3﹣ parallel to the plan (a, b). The water molecules connect these clusters via O-H···O hydrogen bonds. The organic cations are attached to the clusters through N-H···O hydrogen bonds, forming an infinite three-dimensional network.
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