Concentrations of metals
(As, Cr, Cd, Fe, Ni, Pb, Sb, and Zn) in soil samples from Kombo-Laka were
investigated. The area under study is subjected to traditional gold mining and
receives various wastes from miners and mining activities. Direct observations
on the field displayed the destruction of soils by this activity. An assessment
of pollution was performed using an Enrichment Factor (EF) and geoaccumulation
index (Igeo). Levels of
As, Cr, Cd, Cu, Pb and Sb in soil samples were above average in the Upper
Continental Crust (UCC). EF revealed anthropogenic sources for Cd, As and Sb in
these soils. Igeo indicates that Kombo-Laka soils are moderately to extremely polluted with As
and Sb. There are high
to very high positive correlations among the metals suggesting their possible
common sources. This study reveals that traditional gold mining activities in the area are harmful to the
environment.
References
[1]
Ahmad, A.K. and Al-Mahaqeri, S.A. (2014) Assessment of Abandoned Mine Impacts on Concentrations and Distribution of Heavy Metals in Surface Sediments of Catchments Around Sungai Lembing Abandoned Tin Mine. Iranica Journal of Energy & Environment, 5, 453-460.
[2]
Ameh, E.G. (2014) Geochemical Distribution of Heavy Metals in Soil around Itakpe Iron-Ore Mining Area—A Statistical Approach. Research Journal of Environmental and Earth Sciences, 6, 118-126.
[3]
Mathilda, C.G.M. (2013) L’évaluation environnementale et analyse des risques dans le domaine de l’exploitation minière: Les conséquences du non-respect des obligations environnementales. 9 p.
[4]
Taylor, H., Appleton, J.D., Lister, R., Smith, B., Chitamweba, D., Mkumbo, O., Machiwa, J.F., Tesha, A.L. and Beinhoff, C. (2005) Environmental Assessment of Mercury Contamination from the Rwamagasa Artisanal Gold Mining Centre, Geita District, Tanzania. Science of the Total Environment, 343, 111-133. http://dx.doi.org/10.1016/j.scitotenv.2004.09.042
[5]
Ouedraogo, A.H. (2006) Impact de l’exploitation artisanale de l’or (orpaillage) sur la santé et l’environnement. Gestion des substances toxiques, portail Afrique de l’Ouest.
[6]
Andriamasinoro, F. and Angel, J.M. (2012) Artisanal and Small-Scale Gold Mining in Burkina Faso: Suggestion of Multi-Agent Methodology as a Complementary Support in Elaborating a Policy. Resources Policy, 37, 385-396. http://dx.doi.org/10.1016/j.resourpol.2012.04.004
[7]
Bamba, O., Pelede, S., Sako, A., Kagambega, N. and Miningou, M. (2013) Impact de l’artisanat minier sur les sols d’un environnement agricole aménagé au Burkina Faso. Journal des Sciences, 13, 1-11.
[8]
Maradan, D., Ouédraogo, B., Thiombiano, N., Thiombiano, T. and Zein, K. (2011) Analyse économique du secteur des mines liens pauvreté et environnement. sba-Ecosys-CEDRES. Rapport MECV Burkina Faso-mai, 69 p.
[9]
Ekengele, N.L., Jung, M.C., Ombolo, A., Ngounou, N.B., Ekodeck, G. and Mbome, L. (2008) Metals Pollution in Freshly Deposited Sediments from River Mingoa, Main Tributary to the Municipal Lake of Yaounde, Cameroon. Geosciences Journal, 12, 337-347. http://dx.doi.org/10.1007/s12303-008-0034-5
[10]
Espinosa, E., Armienta, M.A., Cruz, O., Aguayo, A. and Ceniceros, N. (2009) Geochemical Distribution of Arsenic, Cadmium, Lead and Zinc in River Sediments Affected by Tailings in Zimapán, a Historical Polymetalic Mining Zone of México. Environmental Geology, 58, 1467-1477. http://dx.doi.org/10.1007/s00254-008-1649-6
[11]
Olatunde, K.A., Arowolo, T.A., Bada, B.S., Taiwo, A.M. and Ojekunle, Z.O. (2014) Distribution and Enrichment of Metals in Sediments of the Ogun River within Abeokuta, South- Western Nigeria. African Journal of Aquatic Science, 39, 17-22. http://dx.doi.org/10.2989/16085914.2014.882287
[12]
Liu, M., Yang, Y., Yun, X., Zhang, M. and Wang, J. (2015) Concentrations, Distribution, Sources, and Ecological Risk Assessment of Heavy Metals in Agricultural Topsoil of the Three Gorges Dam Region, China. Environmental Monitoring and Assessment, 187, 147. http://dx.doi.org/10.1007/s10661-015-4360-6
[13]
Cao, T., An, L., Wang, M., Lou, Y.X., Yu, Y.H., Wu, J.M., Zhu, Z.R., Qing, Y.K. and Glime, J. (2008) Spatial and Temporal Changes of Heavy Metal Concentrations in Mosses and Its Indication to the Environments in the Past 40 Years in the City of Shanghai, China. Atmospheric Environment, 42, 5390-5402. http://dx.doi.org/10.1016/j.atmosenv.2008.02.052
[14]
Chen, T., Liu, X.M., Li, X., Zhao, K.L., Zhang, J.B., Xu, J.M., Shi, J.C. and Dahlgren, R.A. (2009) Heavy Metal Sources Identification and Sampling Uncertainty Analysis in a Field- Scale Vegetable Soil of Hangzhou, China. Environmental Pollution, 157, 1003-1010. http://dx.doi.org/10.1016/j.envpol.2008.10.011
[15]
Lu, A.X., Wang, J.H., Qin, X.Y., Wang, K.Y., Han, P. and Zhang, S.Z. (2012) Multivariate and Geostatistical Analyses of the Spatial Distribution and Origin of Heavy Metals in the Agricultural Soils in Shunyi, Beijing, China. Science of the Total Environment, 425, 66-74. http://dx.doi.org/10.1016/j.scitotenv.2012.03.003
[16]
Mwamburi, J. (2003) Variations in Trace Elements in Bottom Sediments of Major Rivers in Lake Victoria’s Basin, Kenya. Lakes & Reservoirs: Research & Management, 8, 5-13. http://dx.doi.org/10.1046/j.1440-1770.2003.00212.x
[17]
Mathieu, C. and Pieltain, F. (2003) Analyse chimique des sols méthodes choisies. Editions Tec et Doc/Lavoisier, Paris, 408 p.
[18]
Wedepohl, K.H. (1995) The Composition of the Continental Crust. Geochimica et Cosmochimica Acta, 59, 1217-1232. http://dx.doi.org/10.1016/0016-7037(95)00038-2
[19]
Agunbiade, F.O. and Fawale, A.T. (2009) Use of Siam Weed Biomarker in Assessing Heavy Metal Contaminations in Traffic and Solid Waste Polluted Areas. International Journal of Environmental Science and Technology, 6, 267-276. http://dx.doi.org/10.1007/BF03327631
[20]
Schiff, K.C. and Weisberg, S.B. (1999) Iron as a Reference Element for Determining Trace metal Enrichment in Southern California Coast Shelf Sediments. Marine Environmental Research, 48, 161-176. http://dx.doi.org/10.1016/S0141-1136(99)00033-1
[21]
Reinmann, C., Siewers, U., Tarvaunen, T., Bityukova, L., Eriksson, J. and Gilucis, A. (2000) Baltic Soil Survey: Total Concentrations of Major and Selected Elements in Arable Soils from 10 Countries around the Baltic Sea. Science of the Total Environment, 257, 5084- 5091.
[22]
Liu, W., Zhao, J., Ouyang, Z., Soderlund, L. and Liu, G. (2005) Impacts of Sewage Irrigation on Heavy Metal Distribution and Contamination in Beijing, China. Environment International, 31, 805-812. http://dx.doi.org/10.1016/j.envint.2005.05.042
[23]
Fang, T.H., Hwang, J.S., Hsiao, S.H. and Chen, H.Y. (2006) Trace Metals in Seawater and Copepods in the Ocean Outfall Area off the Northern Taiwan Coast. Marine Environmental Research, 61, 224-243. http://dx.doi.org/10.1016/j.marenvres.2005.10.002
[24]
Acevedo-Figueroa, D., Jiménez, B.D. and Rodríguez-Sierra, C.J. (2006) Trace Metals in Sediments of Two Estuarine Lagoons from Puerto Rico. Environmental Pollution, 141, 336- 342. http://dx.doi.org/10.1016/j.envpol.2005.08.037
[25]
Müller, G. (1969) Index of Geoaccumulation in Sediments of the Rhine River. GeoJournal, 2, 108-118.
[26]
Brallier, S., Harrison, R.B., Henry, C.L. and Dongsen, X. (1996) Liming Effects on Availability of Cd, Cu, Ni and Zn in a Soil Amended with Sewage Sludge 16 Years Previously. Water, Air and soil Pollution, 86, 195-206. http://dx.doi.org/10.1007/BF00279156
[27]
Martinelli, I. (1999) Infiltration des eaux de ruissellement pluvial et transfert de polluants associes dans le sol urbain. Vers une approche globale et pluridisciplinaire. Thèse de Doctorat, spécialité Conception en batiment et techniques urbaines, Institut National des Sciences Appliquées de Lyon, 207 p.
[28]
Kabata-Pendias, A. (2004) Soil-Plant Transfer of Trace Elements—An Environmental Issue Geoderma, 122, 143-149.
[29]
Arthin, E., Apea, O.B. and Zango, M.S. (2015) Trace Elements Distributions at Datoko- Shega Artisanal Mining Site, Northern Ghana. Environmental Geochemistry and Health, 38, 203-218. http://dx.doi.org/10.1007/s10653-015-9705-0
[30]
Pahimi, H., Panda, C.R., Ngassoum, M.B. and Tchameni, R. (2015) Environmental Impacts of Mining in the Volcano-Sedimentary Basins of Cameroon: Case Study of Artisanal Gold Mine Tailings (Betare Oya, East-Cameroon). International Journal of Energy, Sustainability and Environmental Engineering, 2, 5-15.
[31]
Hailin, Y., Mengchang, H. and Xiangqin, W. (2015) Concentration and Speciation of Antimony and Arsenic in Soil Profiles around the World’s Largest Antimony Metallurgical Area in China. Environmental Geochemistry and Health, 37, 21-33. http://dx.doi.org/10.1007/s10653-014-9627-2
[32]
Bril, H. and Floc’h, J.P. (2001) Le devenir de métaux provenant des anciennes mines; l’exemple du massif Central fran?ais. Géologues, 233-241.
[33]
Perrono, P. (1999) Les micropolluants métalliques des boues de stations d’épuration urbaine et l’épandage agricole. Mém DUESS, DEP, Université de Picardie, Amiens.
[34]
Sterckeman, T., Douay, F., Proix, N. and Fourrier, H. (2000) Vertical Distribution of Cd, Pb and Zn in Soils near Smelters in the North of France. Environmental Pollution, 107, 377- 389. http://dx.doi.org/10.1016/S0269-7491(99)00165-7
[35]
Arbos, P. (1932) La production de l’antimoine en France. Annale de Géographie, 41, 549- 550. http://dx.doi.org/10.3406/geo.1932.10762
[36]
Fernandez, C. (2006) Devenir du Zn, Pb et Cd issus des retombées atmosphériques dans les sols, à différentes échelles d’étude. Influence de l’usage des sols sur la distribution et la mobilité des métaux. Thèse de doctorat spécialité Environnement et Agronomie, Institut National d’Agronomie Paris Grignon, France, 171 p.
[37]
Praveena, S.M., Aris, A.Z. and Radojevic, M. (2010) Heavy Metals Dyanamics and Source in Intertidal Mangrove Sediment of Sabah Borneo Island. Environment Asia, 3, 79-83.
[38]
Barakat, A., El Baghdadi, M., Rais, J. and Nadem, S. (2012) Assessment of Heavy Metal in Surface Sediments of Day River at Beni-Mellal Region, Morocco. Research Journal of Environmental and Earth Sciences, 4, 797-806.
[39]
Bhuiyan, M.A.H., Parvez, L., Islam, M.A., Dampare, S.B. and Suzuki, S. (2010) Heavy Metal Pollution of Coal Mine Affected Agricultural Soils in the Northern Part of Bangladesh. Journal of Hazardous Materials, 173, 384-392. http://dx.doi.org/10.1016/j.jhazmat.2009.08.085
[40]
Bam, P.K.E., Akiti, T.T., Osea, D.S., Ganyaglo, Y.S. and Gibrilla, A. (2011) Multivariate Cluster Analysis of Some Major and Trace Elements Distribution in an Unsaturated Zone Profile, Densu River Basin, Ghana. African Journal of Environmental Science and Tech- nology, 5, 155-167.
[41]
Al Abdullah, J., Michèl, H., Funel, G.B. and Féraud, G. (2014) Distribution and Baseline Values of Trace Elements in the Sediment of Var River Catchment, Southeast France. Environmental Monitoring and Assessment, 186, 8175-8189. http://dx.doi.org/10.1007/s10661-014-3996-y
[42]
Tessier, A., Carignan, R. and Belzile, N. (1994) Processes Occurring at the Sediment-Water Interface: Emphasis on Trace Elements. In: Buffle, J. and DeVitre, R.R., Eds., Chemical and Biological Regulation of Aquatic System, Lewis Publishers, Boca Raton, 137-173.
[43]
Rubio, B., Nombela, M.A. and Vilas, F. (2000) Geochemistry of Major and Trace Elements in Sediments of the Ria de Vigo (NW Spain): An Assessment of Metal Pollution. Marine Pollution Bulletin, 40, 968-980. http://dx.doi.org/10.1016/S0025-326X(00)00039-4
[44]
Liaghati, T., Preda, M. and Cox, M. (2003) Heavy Metal Distribution and Controlling Factors within Coastal Plain Sediments, Bells Creek Catchment, Southeast Queensland, Australia. Environment International, 29, 935-948. http://dx.doi.org/10.1016/S0160-4120(03)00060-6