The metal-doping into the photocatalyst was evaluated for the photocatalytic degradation of bisphenol
A in aqueous solution with ZnO powder. Au/ZnO, Ag/ZnO and Cu/ZnO were tested in the
present work. Ag-doping ZnO was effective for the improvement of efficiency for the photocatalytic
degradation of bisphenol A in water. The optimum doping concentration of silver was found to
be 3 wt%. The pseudo first-order rate constant with 3 wt% Ag/ZnO was 1.3 times better compared
with bare ZnO. The photocatalytic degradation of treatment for the wastewater containing bisphenol
A is simple, easy handling and low cost.
References
[1]
Harries, J.E., Runnalls, T., Hill, E., Harris, C.A., Maddix, S., Sumpter, J.P. and Tyler, C.R. (2000) Development of a Reproductive Performance Test for Endocrine Disrupting Chemicals Using Pair-Breeding Fathead Minnows (Pimephalespromelas). Environmental Science & Technology, 34, 3003-3011. http://dx.doi.org/10.1021/es991292a
[2]
Staples, C.A., Dome, P.B., Klecka, G.M., Oblock, S.T. and Harris, L.R. (2002) A Review of the Environmental Fate, Effects, and Exposures of Bisphenol A. Chemosphere, 36, 2149-2173. http://dx.doi.org/10.1016/S0045-6535(97)10133-3
[3]
Krishnan, A.V., Stathis, P., Permuth, S.F., Tokes, L. and Feldman, D. (1993) Bisphenol-A: An Estrogenic Substance Is Released from Polycarbonate Flasks during Autoclaving. Endocrinology, 132, 2279-2286.
[4]
Luo, L., Yang, Y., Xiao, M., Bian, L., Yuan, B., Liu, Y., Jiang, F. and Pan, X. (2015) A Novel Biotemplated Synthesis of TiO2/Wood Charcoal Composites for Synergistic Removal of Bisphenol A by Adsorption and Photocatalytic Degradation. Chemical Engineering Journal, 262, 1275-1283. http://dx.doi.org/10.1016/j.cej.2014.10.087
[5]
Doong, R. and Tsai, C. (2015) Synergistic Effect of Cu Adsorption on the Enhanced Photocatalytic Degradation of Bisphenol A by TiO2/Titanate Nanotubes Composites. Journal of the Taiwan Institute of Chemical Engineers, 57, 69-76. http://dx.doi.org/10.1016/j.jtice.2015.05.013
[6]
Kaneco, S., Rahman, M.A., Suzuki, T., Katsumata, H. and Ohta, K. (2005) Optimization of Solar Photocatalytic Degradation Conditions of Bisphenol A in Water Using Titanium Dioxide. Journal of Photochemistry and Photobiology A: Chemistry, 163, 419-424. http://dx.doi.org/10.1016/j.jphotochem.2004.01.012
[7]
Rahman, M.A., Kaneco, S., Suzuki, T., Katsumata, H. and Ohta, K. (2004) Solar Photocatalytic Degradation of Bisphenol A in Water with ZnO. Photo/Electrochemistry & Photobiology in the Environment, Energy and Fuel, 3, 199- 205.
[8]
Rahman, M.A., Kaneco, S., Suzuki, T., Katsumata, H. and Ohta, K. (2004) Optimized Conditions for the Solar Photocatalytic Degradation of Bispehnol A in Water with Zinc Oxide. Annali di Chimica, 95, 715-719. http://dx.doi.org/10.1002/adic.200590083
[9]
Takai, A. and Kamat, P.V. (2011) Capture, Store, and Discharge. Shuttling Photogenerated Electrons across TiO2-Silver Interface. ACS Nano, 5, 7369-7376. http://dx.doi.org/10.1021/nn202294b