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Estimation of Nucleation Thermodynamical Parameters of La2Sr2xCuO4 (LSCO) and YBa2Cu2O7–δ (YBCO) Crystallizing from High Temperature Solution

DOI: 10.4236/csta.2016.52002, PP. 17-23

Keywords: LSCO, YBCO, Interfacial Energy, Metastable Zone-Width

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Abstract:

The growth kinetics of LSCO and YBCO single crystals from high temperature solution of LSCO-CuO solute-solvent and YBCO-CuO solute-solvent systems has been investigated. Based on regular solution model and classical nucleation theory, the thermodynamical data investigated for the systems are used to determine the nucleation parameters: interfacial free energy, metastable zone-width, volume free energy, critical energy barrier for nucleation and radius of critical nucleus for LSCO and YBCO which leads to the understanding of the nucleation phenomena of LSCO and YBCO.

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