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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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m(c_3s_5)_2型分子导体的制备及其电磁和电荷转移性质
Keywords: 分子导体,m(c_3s_3)_2,制备,导电性,电荷转移
Abstract:
？制备了晶态分子导体m(c3s3)2,pd(c3s3)2;pt(c3s3)和无定形分子导体cu(c3s3)2,测定了它们的电阻-温度曲线,磁化率-温度曲线.结合ehmo理论计算与波谱分析,得出导电组元的分子轨道形式.计算tni(c3s5)2晶体的能带,在此基础上阐明ni(c3s5)2的导电机理和半导体→导体相变的机理讨论了[m(c3s3)2]2-与[m(c3s3)2]-,[m(c3s3)2]0,以及[m(c3s3)]2]2-与[m(c3s3)2]0之间的电荷转移
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