OALib Journal期刊
ISSN: 2333-9721
费用:99美元
|
|
|
银铜双金属纳米合金的制备和电催化性质
Keywords: 金属材料,电化学沉积,银铜双金属纳米合金,催化性能
Abstract:
?采用电沉积方法制备银铜双金属纳米合金,用x射线衍射仪(xrd)及高分辨率透射电子显微镜(hrtem),扫描电子显微镜(sem)和电化学工作站分别对样品的结构、微观形貌和电催化性质进行了表征。结果表明,银铜双金属纳米合金电极在h2o2溶液中表现出较强的还原电流,可以作为阴极催化剂;随着银铜双金属纳米合金沉积电位的变负,阴极催化作用减弱,形貌由穗状晶向树枝晶转变;随着铜离子浓度的提高,阴极催化作用增强,银铜双金属纳米合金的形貌由树枝晶向棒状晶转变。这意味着,本文观察到了银铜双金属纳米合金的双金属电催化协同效应。
References
[1] | (冯瑞香,曹余良,艾新平,杨汉西,agni合金作为直接硼氢化物燃料电池的阳极催化剂,物理化学学报,23(6),932(2007))
|
[2] | 6n.a.choudhury,r.k.raman,s.sampath,a.k.shukla,analkalinedirectborohydridefuelcellwithhydrogenperoxideasoxidant,j.powersources,143(1),1(2005)
|
[3] | 7g.h.miley,n.luo,j.mather,r.burton,g.hawkins,l.f.gu,e.byrd,r.gimlin,p.j.shrestha,g.benavides,j.laystrom,d.carroll,directnabh4h2o2fuelcells,j.powersources,165(2),509(2007)
|
[4] | 8r.k.raman,n.a.choudhury,a.k.shukla,a28-wportabledirectborohydride--hydrogenperoxidefuel-cellstack,electrochem.solidstatelett.,7(12),a488(2004)
|
[5] | 9r.r.bessette,j.m.cichon,dischert.,e.g.dow,astudyofcathodecatalysisforthealuminium/hydrogenperoxidesemi-fuelcell,j.powersources,80(1),248(1999)
|
[6] | 10russellr.bessette,mariag.medeiros,charlesj.patrissi,craigm.descheneschristophern.lafratta,developmentandcharacterizationofanovelcarbonfiberbasedcathodeforsemi-fuelcellapplications,j.powersources,96(1),240(2001)
|
[7] | 11yangweiqian,yangshaohua,sunwei,sungongquan,xinqin,nanostructuredpalladium-silvercoatednickelfoamcathodeformagnesium--hydrogenperoxidefuelcells,electrochim.acta,52,9(2006)
|
[8] | 12weijianliang,wangxianyou,wanghong,yangshunyi,daichunling,peifu,performanceofnanosizedauparticleasacathodecatalystfordirectborohydride-hydrogenperoxidefuelcell,actachim.sin.,66(24),2675(2009)
|
[9] | (魏建良,王先友,王宏,杨顺毅,戴春岭,裴斧,纳米au粒子作为直接硼氢化钠--过氧化氢燃料电池阴极催化剂,化学学报,66(24),2675(2009))
|
[10] | 13yangweiqian,yangshaohua,sunwei,sungongquan,xinqin,nanostructuredsilvercatalyzednickelfoamcathodeforanaluminum--hydrogenperoxidefuelcell,j.powersources,160,1420(2006)
|
[11] | 14kexi,cuiguofeng,shengpeikang,stabilityofpd--fealloycatalysts,actaphys.chim.sin.,25(2),213(2009)
|
[12] | (吴辉煌,应用电化学基础(厦门,厦门大学出版社,2006)p.160)
|
[13] | 22changgang,jiangzucheng,pengtianyou,hubin,preparationofhigh-specific-surface-areananometer-sizedaluminabysol-gelmethodandstudyonadsorptionbehaviorsoftransitionmetalionsonthealuminapowderwithicp-aes,actachim.sin.,60(1),100(2003)
|
[14] | (樊友军,甄春花,陈声培,孙世刚,阴离子特性吸附和pt(111)电极表面结构对乙二醇解离吸附动力学的影响,物理化学学报,25(5),999(2009))
|
[15] | 1m.e.indig,r.n.snyder,aninterestinganodicfuel(1),j.electrochem.soc.,109(11),1104(1962)
|
[16] | 2s.c.amendola,p.onnerud,m.t.kelly,p.j.petillo,s.l.sharp-goldman,m.binder,anovelhighpowerdensityborohydride-aircell,j.powersources,84(1),130(1999)
|
[17] | 3s.m.lee,j.h.kim,h.h.lee,p.s.lee,j.y.lee,thecharacterizationofanalkalinefuelcellthatuseshydrogenstoragealloys,j.electrochem.soc.,149(5),a603(2002)
|
[18] | 4wangyonggang,xiayongyao,adirectborohydridefuelcellusingmno2-catalyzedcathodeandhydrogenstoragealloyanode,electrochem.commun.,8(11),1775(2006)
|
[19] | 5fengruixiang,caoyuliang,aixinping,yanghanxi,agnialloyusedasanodiccatalystfordirectborohydridefuelcells,actaphys.chim.sin.,23(6),932(2007)
|
[20] | (柯曦,崔国峰,沈培康,钯铁合金催化剂的稳定性,物理化学学报,25(2),213(2009))
|
[21] | 15wugang,karrenl.more,christinam.johnston,piotrzelenay,high-performanceelectrocatalystsforoxygenreductionderivedfrompolyaniline,iron,andcobalt,science,332,443(2011)
|
[22] | 16j.h.sinfelt,bimetalliccatalysts:discovery,concepts,andapplications(newyork,wiley,1983)p.130
|
[23] | 17g.schmid,a.lehnert,j.o.malm,j.o.bovin,ligand-stabilizedbimetalliccolloidsidentifiedbyhrtemandedx,angewandtechemieinternationaleditioninenglish,30(7),874(1991)
|
[24] | 18i.sunagawa,morphologyofcrystals(kluweracaddemic,dordrecht,1987)p.509
|
[25] | 19lizhongchun,chenxuhong,zhaoxinghong,zhaozhenyi,preparationandelectrocatalyticpropertiesofsilver-copperbimetallicnanoalloy,journalofjiangsuteachersuniversityoftechnology,16(9),49(2010)
|
[26] | (李中春,陈旭红,赵兴红,赵祯怡,ag--cu双金属纳米粒子的制备及其电催化性质,江苏技术师范学院学报,16(9),49(2010))
|
[27] | 20wangguiling,lanjian,caodianxue,sunkening,recentadvanceinresearchondirectnabh$_{4$/h$_{2$o$_{2$fuelcells,journalofchemicalindustryandengineering(china),59(4),805(2008)
|
[28] | (王贵领,兰剑,曹殿学,孙克宁,直接nabh$_{4$/h$_{2$o$_{2$燃料电池的研究进展,化工学报,59(4),805(2008))
|
[29] | 21wuhuihuang,applicationofelectrochemicalbasis(xiamen,xiamenuniversitypress,2006)p.160
|
[30] | (常钢,江祖成,彭天佑,胡斌,溶胶--凝胶法制备高比表面积的纳米氧化铝及其对过渡金属离子吸附行为的研究,化学学报,60(1),100(2003))
|
[31] | 23fanyoujun,zhenchunhua,chenshengpei,sunshigang,effectofspecificadsorptionofanionsandsurfacestructureofpt(111)electrodeonkineticsofdissociativeadsorptionofethyleneglycol,actaphys.-chim.sin.,25(5),999(2009)
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|