|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
聚硼硅氮烷先驱体的合成及其目标陶瓷sibnc的性能
Keywords: 无机非金属材料,sibnc陶瓷,聚硼硅氮烷
Abstract:
？以三氯化硼、甲基氢二氯硅烷、六甲基二硅氮烷为起始原料,通过共缩合路径合成了sibnc陶瓷先驱体－聚硼硅氮烷(pbsz),将pbsz在氨气气氛中高温热解可得sibnc陶瓷.对先驱体及其陶瓷产物的组成、结构和高温结晶性能进行了研究.结果表明,先驱体的骨架结构为-si-n-b-,其中,b、n以硼氮六环形式存在.1000℃的陶瓷产率为61%,陶瓷中碳含量低于0.5%,具有较好的热稳定性能,能够在1700℃以上保持非晶,在1850℃部分结晶,主要由si3n4、bn和少量sic组成,1500℃-1850℃间质量损失约为10%.
| [1] | 1p.baldus,m.jansen,d.sporn,ceramicfibersformatrixcompositesinhigh-temperatureengineapplications,sci-ence,285,699(1999)
|
| [2] | 17k.su,e.e.remsen,g.a.zank,l.g.sneddon,synthe-sis,characterization,andceramicconversionreactionsofborazine-modifiedhydridopolysilazane:newpolymericprecursorstosincbceramiccomposites,chem.mater.,5,547(1993)
|
| [3] | 18c.gervais,j.maquet,f.babonneau,c.duriez,e.framery,m.vaultier,p.florian,d.massiot,chemicallyderivedbnceramics:extensive~(11)band~(15)nsolidstate-nmrstudyofapreceramicpolyborazilene,chem.mater.,13,1700(2001)
|
| [4] | 19f.cheng,b.toury,s.j.archibald,j.s.bradley,synthesisandstructureof2,4,6-tris[tris(dimethylamino)silylamino]borazine:{[(ch_3)_2n]_3sinh}_3b_3n_3h_3,j.organomet.chem.,657,71(2002)
|
| [5] | 20p.miele,b.toury,d.cornu,s.bernard,boryborazinesasnewprecursorsforboronnitridefibers,j.organomet.chem.,690,2809(2005)
|
| [6] | 21d.seyferth,h.plenio,borasilazanepolymericprecursorsforborosiliconnitride,j.am.ceram.soc.,73,2131(1990)
|
| [7] | 24a.müller,p.gerstel,m.weinmann,j.bill,f.aldinger,correlationofboroncontentandhightemperaturesta-bilityinsi-b-c-nceramics,j.eur.ceram.soc.,20,2665(2000)
|
| [8] | 25m.monthioux,o.delverdier,thermalbehaviorof(organosilicon)polymer-derivedceramics.v:mainfactsandtrends,j.eur.ceram.soc.,16,721(1996)
|
| [9] | 2r.riedel,a.kienzle,w.dressleer,l.ruwisch,j.bill,f.aldinger,asilicoboroncarbonitrideceramicstableto2000℃,nature,382,796(1996)
|
| [10] | 3m.jansen,b.jschke,t.jschke,amorphousmultinaryceramicsinthesi-b-n-csystem,structureandbonding,101,137(2002)
|
| [11] | 4d.w.johnson,a.g.evans,r.w.goettler,ceramicfibersandcoatings:advancedmaterialsforthetwenty-firstcentury(washingtond.c.,nationalacademypress,1998)
|
| [12] | 5t.wideman,e.cortez,e.e.remsen,g.a.zank,p.j.carroll,l.g.sneddon,reactionofmonofunc-tionalboraneswithhydridopolysilazane:synthesis,characterization,andceramicconversionreactionsofnewproccssibleprecursorstosincbceramicmaterials,chem.mater.,9,2218(1997)
|
| [13] | 6m.jansen,t.jschke,preparation,crystalstructure,andspectroscopiccharacterizationof[(ch_3)_3si]nh(bcl_2),z.anorg.allg.chem.,625,1957(1999)
|
| [14] | 7t.jschke,m.jansen,improveddurabilitysi/b/n/cran-dominorganicnetworks,j.eur.ceram.soc.,25,211(2005)andreferencestherein
|
| [15] | 8s.bernard,m.weinmann,p.geratel,p.miele,f.aldinger,boron-modifiedpolysilazaneasanovelsingle-sourcepre-cursorforsibcnceramicfibers:synthesis,melt-spinning,curingandceramicconversion,j.mater.chem.,15,289(2005)
|
| [16] | 9m.weinmann,j.schuhmacher,h.kummer,s.prinz,j.peng,h.j.seifert,m.christ,k.müller,j.bill,f.aldinger,synthesisandthermalbehaviorofnovelsi-b-c-nceramicprecursors,chem.mater.,12,623(2000)
|
| [17] | 10w.r.schmidt,d.m.narsavage-heald,d.m.jones,p.s.marchetti,d.raker,g.e.msciel,poly(borosilazane)precursorstoceramicnanocomposites,chem.mater.,11,1455(1999)
|
| [18] | 11j.haberecht,r.nesper,h.grützmacher,aconstructionkitforsi-b-c-nceramicmaterialsbasedonborazineprecursors,chem.mater.,17,2340(2005)
|
| [19] | 12m.weinmann,m.hrz,f.berger,a.müller,k.müller,f.aldinger,dehydrocouplingoftris(hydridosilylethyl)boranesandcyanamide:anovelaccesstoboron-containingpolysilycarbodiimides,j.organomet.chem.,659,29(2002)
|
| [20] | 13t.jschke,m.jansen,anewborazine-typesinglesourceprecursorforsi/b/n/cceramics,j.mater.chem.,16,2792(2006)
|
| [21] | 14d.f.shriver,m.a.drezdz,themanipulationofair-sensitivecompounds(newyork,wiley,1986)
|
| [22] | 15wangjun,tangyun,lixiaodong,liwenhua,wanghao,xiezhengfang,anovelpolyborosilazaneandmethodsforitsproduction,chinanationaldefensepatent,200710081156.7(2007)(王军，唐云，李效东，李文华，王浩，谢征芳，一种新型聚硼硅氮烷及其制备方法，中国国防专利，200710081156．7(2007))
|
| [23] | 16q.d.nghiem,j.-k.jeon,l.-y.hong,d.-p.kim,poly-merderivedsi-c-b-nceramicsviahydroborationfromborazinederivativesandtrivinylcyclotrisilazane,j.organomet.chem.,688,27(2003)
|
| [24] | 22j.p.cannady,hydrosilazanepolymersfrom[r_3si]_2nhandhsic13,uspatent4,540,803(1985)
|
| [25] | 23j.lee,d.p.butt,r.h.baney,c.r.bowers,j.s.tulenko,synthesisandpyrolysisofnovelpolysilazanetosibncceramic,j.non-crystallinesolid,351,2995(2005)
|
| [26] | 26a.müller,j.peng,h.j.seifert,j.bill,f.aldinger,sibcnceramicprecursorsderivedfromdichlorodivinylsilaneandchlorotrivinylsilane.2.ceramizationofpolymersandhigh-temperaturebehaviorofceramicmaterials,chem.mater.,14,3406(2002)
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
