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含钛高炉渣催化剂的光催化活性

Keywords: 硫酸掺杂的含钛高炉渣催化剂,catio3/tio2晶相比,so42?含量,光催化还原

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Abstract:

?以攀钢含钛高炉废渣为原料,在不同温度下煅烧合成了钙钛矿型硫酸掺杂的含钛高炉渣催化剂(sulfuricacid-modifiedtitanium-bearingblastfurnaceslag,stbbfs),研究了混晶结构和硫掺杂对含钛高炉渣光催化活性的影响.结果表明,含钛高炉渣催化剂具有钙钛矿/锐钛矿混晶结构,粉体的颗粒形状不规则,煅烧后粒径变大;在紫外区域具有很强的光吸收能力.stbbfs催化剂的光催化活性由cr(vi)的还原率评价.煅烧温度为400℃时,stbbfs催化剂的表面存在含量较高的so2-4和较高的catio3/tio2晶相比,具有较高的光催化活性.用500w中压汞灯照射10h,可将浓度为20mg???l-1的六价铬废水完全降解.

References

[1]  1c.h.lu,c.y.hu,c.h.wu,preparationandcharacterizationofnewvisible-light-drivenbaco0.5nb0.5o3photocatalystcharactersofperovskite-typelacoo3preparedbyreactivegrinding,mater.lett.,61,3959(2007)
[2]  2l.huang,m.bassir,s.kaliaguine,charactersofperovskite-typelacoo3preparedbyreactivegrinding,mater.chem.phys.,101,259(2007)
[3]  3x.m.lu,j.m.xie,h.m.shu,microwave-assistedsynthesisofnanocrystallineyfeo3andstudyofitsphotoactivity,mater.sci.eng.b.,138,289(2007)
[4]  4s.g.hur,t.w.kim,s.j.hwang,influencesofa-andb-sitecationsonthephysicochemicalpropertiesofperovskitestructureda(in1/3nb1/3b1/3)o3(a=sr,ba;b=sn,pb)photocatalysts,j.photoche.photobiol.a.,183,176(2006)
[5]  5y.yang,y.b.sun,y.s.jiang,photoinducedstructuraltransformationofsrfeo3andca2fe2o5duringphotodegradationofmethylorange,mater.chem.phys.,96,234(2006)
[6]  6y.yang,y.s.jiang,y.w.wang,photoinduceddecompositionofbafeo3duringphotodegradationofmethylorange,j.mol.catal.a:chem.,270,56(2007)
[7]  8weiyuelin,huangyunfang,chenhaiting,wujihuai,effectoftantalumsubstitutionfortitaniuminlayeredperovskitetypek2la2ti3o10photocatalyticproperty,chinesejournalofmaterialsresearch,22(1),93(2008)
[8]  (魏月琳,黄昀fang,陈海庭,吴季怀,担掺杂对层状钙钦矿斓钦酸钾光催化性能的影响,材料研究学报,22(1),93(2008))
[9]  9niuxinshu,caozhimin,progressinphotocatalysisofperovskiteoxides,chemicalresearchandapplication,18,770(2006)
[10]  (牛新书,曹志民,钙钛矿型复合氧化物光催化研究进展,化学研究与应用,18,770(2006))
[11]  10wangguiyun,wangyanji,qinya,songbaojun,theeffectofcalcinationconditionsonthephotocatalyticperformanceofcatio3,materialsscience&technology,15(6),831(2007)
[12]  (王桂yun,王延吉,秦娅,宋宝俊,焙烧条件对catio3光催化性能的影响,材料科学与工艺,15(6),831(2007))
[13]  11g.colon,j.m.sanchez-espana,m.c.hidalgo,j.a.navio,effectoftio2acidicpre-treatmentonthephotocatalyticpropertiesforphenoldegradation,j.photochem.photobiol.a,179,20(2006)
[14]  12f.jiang,z.zheng,z.y.xu,aqueouscr(vi)photoreductioncatalyzedbytio2andsulfatedtio2,j.hazard.mater.b,134,94(2006)
[15]  13l.k.noda,r.m.almeida,n.s.goncalves,tio2withahighsulfatecontent-thermogravimetricanalysis,determinationofacidsitesbyinfraredspectroscopyandcatalyticactivity,catal.today,85,69(2003)
[16]  16pengwenshi,liugaokui,infraredspectraofinorganiccompound(beijing,sciencepress,1982)p.508
[17]  (彭文世,刘高魁,矿物红外光谱图集(北京,科学出版社,1982)p.508)
[18]  7dengjiguang,wangguozhi,zhangyujuan,daihongxing,hehong,qiuwenge,advancementofpreparationstrategiesandphotocatalyticperformanceofperovskite-typeoxides,journalofthechineserareearthsociety,24,80(2006)
[19]  (邓积光,王国志,张玉娟,戴洪兴,何洪,邱文革,钙钛矿型氧化物的制备与光催化性能研究进展,中国稀土学报,24,80(2006))
[20]  14zhangxia,zhaoyan,zhangcaibei,menghao,thephotocatalyticactivityofnano-tio2powderwithmixedcrystalstructure,chinesejournalofmaterialsresearch,20(5),454(2005)
[21]  (张霞,赵岩,张彩碚,孟皓,混晶结构纳米tio2粉的光催化活性,材料研究学报,20(5),454(2005))
[22]  15a.bojinova,r.kralchevska,i.poulios,c.dushkin,anatase/rutiletio2composites:influenceofthemixing
[23]  ratioonthephotocatalyticdegradationofmalachitegreenandorangeiiinslurry,mater.chem.phys.,106,187(2007)
[24]  17d.g.taylor,c.m.nenadic,j.v.crable,infraredspectraformineralidentification,am.ind.hyg.ass.j.,31,100(1970)
[25]  18k.nakamoto,infraredspectraofinorganicandcoordinationcompounds,thirdedition(newyork,johnwileyandsons,inc.,1978)p.448
[26]  19j.m.hunt,m.p.wisherd,l.c.bonham,infraredabsorptionspectraofmineralsandotherinorganiccompounds,analyt.chem.,22,1478(1950)
[27]  20j.p.lyon,infraredabsorptionspectra,thefrontpage(london,academicpress,1967)p.508

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