|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
硅胶/聚苯乙烯--丙烯酸核壳结构复合粒子的制备和表征
Keywords: 无机非金属材料,？复合粒子,？核壳结构,？相转化法,？孔结构
Abstract:
？以硅胶(sio2)和聚苯乙烯--丙烯酸(psa)为原料制备sio2/psa核壳结构型复合粒子。在相转化法制备聚合物薄膜的基础上,为避免粒子团聚提出以蒸汽方式代替传统的液滴方式,将非溶剂缓慢而均匀地加入sio2与psa溶液的混合物中。采用红外光谱、扫描电子显微镜、激光粒度分析仪、热重分析、压汞仪和氮气吸附/脱附等方法对粒子的化学组成、形貌、粒径分布以及多孔结构特性作了分析和表征。结果表明,sio2/psa复合粒子具有核壳结构,颗粒的分散性较好,psa利用率几乎达到100%。聚合物溶液的浓度直接影响核壳粒子的表面形貌。与纯硅胶颗粒相比,由于致密的psa膜覆盖在多孔硅胶上,sio2/psa核壳复合粒子的孔隙率、比表面积、孔体积和平均孔径都大幅下降。
| [1] | 3c.b.liu,t.tang,b.t.huang,preparationandapplicationofanovelcore–shell–particle–supportedzirconocenecatalyst,jpolymsci,parta:polymchem,39,2085(2001)
|
| [2] | 4y.guo,x.q.zhang,w.m.dong,organic–inorganichybridsupportedzirconocenecatalystsforethylenepolymerization,j.mol.catal.a:chem.,237,45(2005)
|
| [3] | 5d.zhang,g.x.jin,radicalcopolymerizationofdiiminedibromidenickel(ii)functionalizedolefinwithstyrene:synthesisofpolymer–incorporatednickel(ii)α–diiminecatalystsforethylenepolymerization,appl.catal.a,262,13(2004)
|
| [4] | 6s.kaur,g.singh,u.c.makwana,v.k.gupta,immobilizationoftitaniumtetrachlorideonmixedsupportofmgcl2·xeb/poly(methylacrylate–co–1–octene):catalystforsynthesisofbroadmwdpolyethylene,catallett,87,132(2009)
|
| [5] | 7m.ulbricht,advancedfunctionalpolymermembranes,polymer,47,2217(2006)
|
| [6] | 8h.zhang,h.g.ni,x.p.wang,x.b.wang,w.zhang,effectofchemicalgroupsofpolystyrenemembranesurfaceonistpervaporationperformance,j.membr.sci.,281,626(2006)
|
| [7] | 13c.stropnik,l.germic,b.zerjal,morphologyvarietyandformationmechanismsofpolymericmembranespreparedbywetphaseinversion,j.appl.polym.sci.,61,1821(1996)
|
| [8] | 14h.l.luo,j.sheng,y.z.wan,preparationandcharacterizationoftio2/polystyrenecore-shellnanospheresviamicrowave–assistedemulsionpolymerization,mater.lett.,62,37(2008)
|
| [9] | 1wutianbin,keyangchuan,wangyuehong,dongpeng,thepreparationofmonodispersesio2/pscompositesparticles,actapolymericasinica,2,289(2005)
|
| [10] | (吴天斌,柯扬船,王月红,董鹏,单分散sio2/psa复合粒子的制备,高分子学报,2,289(2005))
|
| [11] | 2ouyuchun,fangxiaoping,guotingtai,fengyupeng,anewtechniqueforpreparationofrigidparticletougheningandreinforcingpolymercomposites,chinesejournalofmaterialsresearch,15,110(2001)
|
| [12] | (欧玉春,方晓萍,郭庭泰,冯宇鹏,刚性粒子增强增韧聚合物复合材料的制备新技术,材料研究学报,15,110(2001))
|
| [13] | 9yjwang,yxiong,fchen,gsluo.preparationofcore–shellglassbead/polysulfonemicrosphereswithtwo–stepsol–gelprocess.j.appl.polym.sci.,99,3365(2006)
|
| [14] | 10wangjingdai,dulijun,liwei,fanlina,jiangbinbo,huangzhengliang,yangyongrong,thepreparationofinorganic/organiccompositeparticleswithcore-shellstructure,chinapatent,200910098802.x,2009–05–18.
|
| [15] | (王靖岱,杜丽君,历伟,范丽娜,蒋斌波,黄正梁,阳永荣,具有核壳结构的无机/有机复合载体的制备方法,中国专利,200910098802.x,2009--05--18)
|
| [16] | 11k.zhang,w.wu,h.meng,k.guo,j.f.chen,pickeringemulsionpolymerization:preparationofpolystyrene/nano–sio2compositemicrosphereswithcore–shellstructure,powdertechnol.,190,393(2009)
|
| [17] | 12h.y.lee,s.p.rwei,l.wang,p.h.chen,preparationandcharacterizationofcore-shellpolyaniline-polystyrenesulfonate@fe3o4nanoparticles,mater.chem.phys.,112,805(2008)
|
| [18] | 15t.j.yao,q.lin,k.zhang,d.f.zhao,h.lv,j.h.zhang,b.yang,preparationofsio2@polystyrene@polypyrrolesandwichcompositesandhollowpolypyrrolecapsuleswithmovablesio2spheresinside,j.colloidinterfacesci.,315,434(2007)
|
| [19] | 16t.h.young,l.w.chen,poreformationmechanismofmembranesfromphaseinversionprocess,desalination,103,233(1995)
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
