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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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氮对碳纤维石墨化的影响
Keywords: 无机非金属材料,石墨化,元素含量,微晶结构,取向度,石墨化度
Abstract:
？用元素分析、x射线衍射和拉曼光谱等手段对不同结构成分的石墨纤维进行表征,研究了石墨结构与纤维中氮的关系。结果表明：在高温石墨化过程中,随着氮的减少,石墨微晶堆叠厚度和宽度不断增大,纤维的晶区取向度和石墨化度提高。氮含量大于0.08%时,石墨片层中有氮原子的位置会扭曲变形,不利于石墨微晶的生长,石墨微晶大小、晶区取向度及石墨化度增长比较缓慢；当氮元素含量小于0.08%时,由氮引起的石墨片层缺陷很少,石墨微晶大小、晶区取向度及石墨化度的增长速率随氮的减少而大幅度提高。脱除氮原子虽然不能引起石墨片层的生长,但是含氮石墨片层生长的控制步骤。
| [1] | 1liuhongbo,xuzhongyu,zhanghongbo,suyuchang,theeffectofheat-treatmenttemperatureonthestructureandmechanicalpropertiesofcarbonfiber,syntheticfiberindustry,18(6),18(1995)
|
| [2] | (刘洪波,徐仲榆,张红波,苏玉长,高温热处理温度对pan基碳纤维结构和力学性能的影响,合成纤维工业,18(6),18(1995))
|
| [3] | 2liufujie,wanghaojing,fanlidong,thechangeofdensityunderhightemperatureheattreatmentinpan-basedcarbonfibers,newchemicalmaterials,35(1),43(2007)
|
| [4] | (刘福杰,王浩静,范立东,pan碳纤维在高温石墨化过程中密度的变化规律,化工新型材料,35(1),43(2007))
|
| [5] | 3r.b.mathur,v.gupta,o.p.bahl,a.tressaud,s.flandrois.improvementinthemechanicalpropertiesofpolyacryloaitrile(pan)-basedcarbonfibersafterfluorination.syntheticmetals,114(2),197(2000)
|
| [6] | 4j.kim,w.i.lee,k.lafdi,numericalmodelingofthecarbonizationprocessinthemanufactureofcarbon/carboncomposites,carbon,41(13),2625(2003)
|
| [7] | 5chentengfei,huangboyun,liaojiqiao,liugenshan,zhangfuqin,effectofheat-treatmenttemperatureonmicrostructureandmechanicalperformanceofpan-basedcarbonfibers,journaloffunctionalmaterials,33(4),447(2002)
|
| [8] | (陈腾飞,黄伯云,廖寄乔,刘根山,张福勤,热处理温度对pan基炭纤维结构的影响,功能材料,33(4),447(2002))
|
| [9] | 6chagnweipu,shenzengmin,wangqiang,manufactureofhighmodulusgraphitizedcarbonfibers,newcarbonmaterials,13(1),28(1998)
|
| [10] | (常维璞,沈曾民,王强,高模量炭纤维的研制,新型炭材料,13(1),28(1998))
|
| [11] | 7zhangweiqin,tianyanhong,yangyanfeng,zhangxiping,shengzengmin,studyonthesurfacemorphologyofthehttcarbonfibersbysem,newcarbonmaterials,16(3),52(2001))
|
| [12] | (张为芹,田艳红,杨延风,张西萍,沈曾民,高温热处理对炭纤维性能的影响,新型炭材料,16(3),52(2001))
|
| [13] | 8xuelinbing,wanghaojing,lidongfeng,effectofstressgraphitizationonthemicrostructureandmechanicalpropertiesofgraphitefibers,newcarbonmaterials,21(3),243(2006)
|
| [14] | (薛林兵,王浩静,李东风,牵伸石墨化对石墨纤维结构和力学性能的影响,新型炭材料,21(3),243(2006))
|
| [15] | 9lidongfeng,wanghaojing,xuelinbing,wangxinkui,preferredorientationofpan-basedcarbonfibersduringcontinuousgraphitization,chemicalindustryandengineeringprogress,25(9),1101(2006)
|
| [16] | (李东风,王浩静,薛林兵,王心葵,pan基碳纤维连续石墨化过程中的取向性,化工进展,25(9),1101(2006))
|
| [17] | 10xuzhongyu,liuhongbo,suyuchang,yangruizhi,gongweizhi,usinghotstretchingingraphitizationtopreparepan-basedofhighproperties,carbon,3,4(1997)
|
| [18] | (徐仲榆,刘洪波,苏玉长,杨瑞枝,龚伟志,在石墨化过程中采用热牵伸法制备高性能pan基炭纤维,炭素,3,4(1997))
|
| [19] | 11hefu,carbonfiberanditsapplicationtechnology(beijing,chemicalindustrypress,2004)p.86
|
| [20] | (贺福,碳纤维及其应用技术,(北京,化学工业出版社,2004)p.86)
|
| [21] | 12j.chen,j.y.shan,t.tsukada,f.munekane,a.kuno,m.matsuo,t.hayashi,y.a.kim,m.endo,thestructuralevolutionofthinmulti-walledcarbonnanotubesduringisothermalannealing.carbon,45,274(2007)
|
| [22] | 13a.sadezky,h.muckenhuber,h.grothe,ramanmicrospectroscopyofsootandrelatedcarbonaceousmaterials:spectrlanalysisandstructuralinformation,carbon,43,1731(2005)
|
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