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可交联硅烷接枝聚乙烯共混物的性能

Keywords: 可交联硅烷按枝聚乙烯共混物,熔体流动速率

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Abstract:

?研究了可交联硅烷接枝聚乙烯共混物(pebx)的熔体流动速率(mfr),维卡软化点试过程中的温度变形关系,拉伸性能及结晶行为等性质。研究结果表明:(ι)纯聚乙烯共混物(peb)的mfr基本上不随时间变化,而pebx的mfr随时间减小;(ⅱ)在相同的温度下,交联后的聚乙烯共混物(cpebx)的变形量小于peb和pebx的,在维卡软化点附近的温度,cpebx的变形速率远小于peb和pebx的;(ⅲ)cpebx有交联,但其断裂伸长率与pebx和peb的相近,未受到交联的影响,其屈服应力高于pebx和peb的;(ⅳ)cpebx的熔点和熔程与pebx及peb的差不多,但结晶度比后两者的有所升高。讨论了产生上述特性的原因。

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