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长期热致吸放氢循环对载钯硅藻土储氢性能的影响

Keywords: 金属材料,,硅藻土,储氢性能,热致循环

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Abstract:

?采用pdcl2溶液浸渍--焙烧--还原的方法制备出载钯硅藻土(palladium/kieselguhr,简称pd/k),对其进行物相分析、形貌观察、吸放氢pct以及吸氢动力学测量,研究了1000次和2000次热致吸放氢循环后的储氢性能。结果表明,热致循环前后pd/k的吸放氢pct曲线基本相同,吸氢量稍有降低,动力学性能明显提高。热致循环后pd/k表面的钯颗粒发生明显粉化,1000次和2000次热致循环后粉化率(<150?μm)分别为0.21%和3.98%。

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