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la2o3-y2o3-zro2纳米陶瓷粉末制备及高温相稳定性

Keywords: 无机非金属材料,?稀土共掺杂二氧化锆,?纳米粉末,?共沉淀,相稳定性

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Abstract:

?用化学共沉淀法制备4.5%y2o3--zro2(ysz)和0.6%la2o3--ysz、0.8%la2o3--ysz、1.2%la2o3--ysz(0.6la、0.8la、1.2la)(摩尔分数)纳米复合陶瓷粉末,研究了四组粉末的高温相稳定性。结果表明:采用正向滴淀方法制备的0.6la粉末(粒径~50nm)团聚严重,而用反向滴淀方法制备的0.6la粉末(粒径~20nm),粉末团聚少;各组前躯体粉末在600℃煅烧2h后都呈单一四方相结构;在1200℃烧结100h后0.6la、0.8la坯体呈单一四方相结构,无相变,ysz和1.2la坯体都有立方相且1.2la坯体有锆酸镧相生成;在1300℃烧结100h后0.6la,0.8la,1.2la坯体呈四方相和立方相结构,其中1.2la坯体有锆酸镧相生成,在相同条件下烧结的ysz坯体有少量(~1.5\%)单斜相产生;在1400℃烧结100h后各组份中四方相已不能保持稳定,转化为单斜相和立方相,0.6la、0.8la、1.2la、ysz坯体单斜相含量分别为30.5%,32%,35%,46.0%。在ysz中添加少量la2o3在1300℃烧结能有效改善其高温相的稳定性。

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