|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
杂原子mcm--41分子筛的合成和催化性能
Keywords: 无机非金属材料,介孔分子筛,mcm--41,邻苯二甲酸二(2--乙基己)酯
Abstract:
？采用水热合成法合成了金属原子(zn,ni,fe,al,cu,ce)掺杂的mcm--41介孔分子筛(简称t--mcm--41),并将其应用于邻苯二甲酸二(2--乙基己)酯(dop)的合成反应,研究了不同原子的掺杂对t--mcm--41的结构、比表面积和孔径、酸性及催化性能的影响.结果表明,所制备的t--mcm--41仍然具有六方有序排列结构,比表面积较高(550--900m2/g)、孔径大(3nm左右),杂原子的引入使t--mcm--41产生了酸中心,从而使其对dop的合成具有很好的催化活性和选择性.用t--mcm--41(t=zn,fe,al,cu)催化dop的合成反应,在5h的反应时间内苯酐的转化率可以达到95.5%以上,dop的选择性可达到96.5%以上.t--mcm--41催化剂具有很好的稳定性,al--mcm--41在重复使用5次后仍具有较好的催化活性.
| [1] | (张建国,蒋庆哲,郑成国,宋昭峥,柯明,si--mcm--41的合成及其影响因素,中国石油大学学报(自然科学版),32(1),113(2008))
|
| [2] | 8c.blanco,c.pesquera,f.gonzzlez,synthesisandcharacterizationofmcm–41withdifferentsi/almolarratiosanddifferentsiliconsources.studiesinsurfacescienceandcatalysis,154,432(2004)
|
| [3] | 9r.wojcieszak,s.monteverdi,m.mercy,i.nowak,m.ziolek,m.m.bettahar,nickelcontainingmcm–41andalmcm–41mesoporousmolecularsieves:characteristicsandactivityinthehydrogenationofbenzene,appliedcatalysisa:general,268,241(2004)
|
| [4] | 10v.parvulescu,b.l.su,iron,cobaltornickelsubstitutedmcm–41molecularsievesforoxidationofhydrocarbons,catalysistoday,69,315(2001)
|
| [5] | 11r.r.sever,r.alcala,j.a.dumesic,t.w.root,vapor–phasesilylationofmcm–41andti–mcm–41,microporousandmesoporousmaterials,66(1),53(2003)
|
| [6] | 12cuirong,liuxiaoqin,shanjiahui,preparationofce–mcm–41adsorbentanditsperformanceinmodelgasofinedesulfurization,naturalgaschemicalengineering,33(2),11(2008)
|
| [7] | (崔榕,刘晓勤,单佳慧,ce--mcm--41分子筛吸附剂的制备及其在模拟汽油脱硫中的性能,天然气化工,33(2),11(2008))
|
| [8] | 13kongyan,xuxinjie,wuyong,zhangrui,wangjun,effectofpromotersonthecatalyticactivityofmcm–41withhighcoppercontentinbenzenehydroxylation,chinesejournalofcatalysis,29(4),385(2008)
|
| [9] | 14c.mahendiran,p.sangeetha,p.vijayan,s.j.sardharbasha,k.shanthi,vapourphaseoxidationoftetralinovercrandfesubstitutedmcm–41molecularsieves,journalofmolecularcatalysisa:chemical,275,84(2007)
|
| [10] | 18f.t.sejidov,y.mansoori,n.goodarzi,esterificationreactionusingsolidheterogeneousacidcatalystsundersolvent–lesscondition,journalofmolecularcatalysisa:chemical,240,186(2005)
|
| [11] | 19m.ziolek,i.nowak,b.kilos,i.sobczak,p.decyk,m.trejda,j.c.volta,templatesynthesisandcharacterisationofmcm–41mesoporousmolecularsievescontainingvarioustransitionmetalelements-tme(cu,fe,nb,v,mo),journalofphysicsandchemistryofsolids,65,571(2004)
|
| [12] | 20s.ajaikumar,a.pandurangan,esterificationofalkylacidswithalkanolsovermcm–41molecularsieves:influenceofhydrophobicsurfaceoncondensationreaction,journalofmolecularcatalysisa:chemical,266,1(2007)
|
| [13] | 21m.bhagiyalakshmi,k.shanmugapriya,m.palanichamy,b.arabindooandv.murugesan,esterificationofmaleicanhydridewithmethanoloversolidacidcatalysts:anovelroutefortheproductionofheteroesters,appliedcatalysisa:general,267,77(2004)
|
| [14] | 22doumaofeng,j1nshengming,fuling,changyan,guanhaoyuan,yangmin,preparationandstructureofmesoporousmolecularsievesti–mcm–4l,journalofthechineseceramicsociety,36(1),65(2008)
|
| [15] | 24huangshiyong,wanghaitao,songyanfen,gaowenyi,fanlirong,lianpiyong,synthesisofmesoporousmcm–41molecularsievescontainingheteroatomsandstudyofcyclohexaneoxidation,finechemicals,21(1),41(2004)
|
| [16] | 25lifuxiang,zhangxiangdi,liruifeng,xiekechang,synthesisandcharacterizationofmesoporouszr–mcm–41,journaloffuelchemidtryandtechnology,32(4),471(2004)
|
| [17] | (李福祥,张香娣,李瑞丰,谢克昌,zr--mcm--41的合成及其表征,燃料化学学报,32(4),471(2004))
|
| [18] | 26wushujie,huangjiahui,wutonghao,songke,wanghongsu,xinglihong,xuhaiyan,xuling,guanjingqi,kanqiubin,synthesis,characterization,andcatalyticperformanceofmesoporousal–sba–15fortert–butylationofphenol,chinesejournalofcatalysis,27(1),9(2006)
|
| [19] | 1j.s.beck,j.c.vartuli,w.j.roth,m.e.leonowicz,c.t.kresge,k.d.schmitt,c.t–w.chu,d.h.olson,e.w.sheppard,s.b.mccullen,j.b.higgins,j.l.schlenkert,anewfamilyofmesoporousmolecularsievespreparedwithliquidcrystaltemplates,journaloftheamericanchemicalsociety,114,10834(1992)
|
| [20] | 2zhangjianguo,jiangqingzhe,zhengchengguo,songzhaozheng,keming,synthesismethodanditsinfluencefactorsofsi–mcm–41,journalofchinauniversityofpetroleum(naturalscienceedition),32(1),113(2008)
|
| [21] | 3menghuadong,zhangjuntao,dingliqin,liangshengrong,wangxiaoquan,synthesisandcharacterizationofmesoporousmolecularsieveal–mcm–41,journalofxianshiyouuniversity(naturalscienceedition),22(3),104(2007)
|
| [22] | (孟华东,张君涛,丁丽芹,梁生荣,王小泉,al--mcm--41介孔分子筛的合成与表征,西安石油大学学报(自然科学版),22(3),104(2007))
|
| [23] | 4y.r.wang,n.c.lang,a.tuel,natureandacidityofaluminumspeciesalmcm–41withahighaluminumcontent(si/al=1.25),microporousandmesoporousmaterials,93,46(2006)
|
| [24] | 5qiaokui,zhangfumin,panduoli,zhangniaofei,jianpanming,synthesis,characterizationandcatalyticoxidationperformanceofhighti–containingti–mcm–41molecularsieves,chinesejournalofinorgnicchemistry,24(5),748(2008)
|
| [25] | (乔亏,张富民,潘多丽,张鸟飞,菅盘铭,高钛ti--mcm--41分子筛的合成、表征与催化氧化性能考察,无机化学学报,24(5),748(2008))
|
| [26] | 6s.udayakumar,a.pandurangan,p.k.sinha,para–selectiveethylationofphenolwithdiethylcarbonateovermesoporousal–mcm–41molecularsieves,appliedcatalysisa:general,272,267(2004)
|
| [27] | 7m.j.b.souza,a.s.araujo,a.m.g.pedrosa,b.a.marinkovic,p.m.jardim,e.m.jr.,texturalfeaturesofhighlyorderedal–mcm–41molecularsievestudiedbyx–raydiffraction,nitrogenadsorptionandtransmissionelectronmicroscopy,materialsletters,60,2682(2006)
|
| [28] | 15s.s.bhoware,a.p.singh,characterizationandcatalyticactivityofcobaltcontainingmcm–41preparedbydirecthydrothermal,graftingandimmobilizationmethods,journalofmolecularcatalysisa:chemical,266,118(2007)
|
| [29] | 16l.f.chen,j.a.wang,l.e.norena,j.aguilar,j.navarrete,p.salas,j.a.montoya,p.delangel,synthesisandphysicochemicalpropertiesofzr–mcm–41mesoporousmolecularsievesandpt/h3pw12o40/zr–mcm–41catalysts,journalofsolidstatechemistry,180,2958(2007)
|
| [30] | 17jiangpingping,luguanzhong,developmentofsolidcatalystincatalyticsynthesisofdop,chemicalindustryandengineeringprocess,21(5),328(2002)
|
| [31] | (蒋平平,卢冠忠,固体酸催化合成邻苯二甲酸二辛酯,化工进展,21(5),328(2002))
|
| [32] | (豆茂峰,金胜明,付英,常燕,关豪元,杨敏,介孔分子筛ti--mcm--41的制备和结构,硅酸盐学报,36(1),65(2008))
|
| [33] | 23r.luque,j.m.campelo,d.luna,j.m.marinas,a.a.romero,nh4feffectinpost–synthesistreatmentofal–mcm–41mesoporousmaterials,microporousandmesoporousmaterials,84,11(2005)
|
| [34] | (黄世勇,王海涛,宋艳芬,高文艺,樊丽荣,连丕勇,杂原子mcm--41分子筛的合成及对环己烷氧化的研究,精细化工,21(1),41(2004))
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
