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sic泡沫陶瓷/fe基双连续相复合材料的制备和性能

Keywords: 复合材料,泡沫陶瓷,sio反应阻挡层,力学性能

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Abstract:

?将sic泡沫陶瓷氧化,用挤压铸造法制备sic泡沫陶瓷/fe基双连续相复合材料并对其退火,研究了制备工艺和sic泡沫陶瓷的体积分数对其微观组织和力学性能的影响。结果表明,在1250℃氧化48h后在sic泡沫陶瓷表面生成了厚度为1mm的sio2反应阻挡层。在双连续相复合材料的制备过程中,sio2反应阻挡层抑制fe与sic的化学反应,避免了脆性化合物fe3si的生成,改善了基体与增强体的界面,使复合材料的抗弯强度提高2倍,压缩强度提高18%。当sic泡沫陶瓷的氧化时间增至72h时,sic泡沫陶瓷表面sio2的厚度过大。sio2与基体和增强体热膨胀系数不匹配,使复合材料内相界面间的残余应力增加,导致其性能下降。将sic泡沫陶瓷/fe基双连续相复合材料在600℃退火4h,可降低复合材料中的残余应力,提高复合材料的性能。sic的体积分数较低时,金属基体的桥接、偏转裂纹的作用比较大,复合材料的弯曲强度高,变形程度大。随着复合材料中sic体积分数的增大,sic骨架筋增粗,其承载能力加强,复合材料的压缩强度呈提高的趋势。

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