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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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ti3alc2的高温临氢行为
Keywords: 无机非金属材料,临氢,高温,tialc
Abstract:
？研究了ti3alc2体材料在氢气氛中的高温(1100~1400℃)热稳定性。采用xrd、sem、sims和raman分析等手段对ti3alc2临氢反应前后的物相组成、表面形貌进行了表征;使用热力学软件factsage计算了反应过程中的气态产物。结果表明,在1100~1400℃氢气氛条件下有少量h溶解在ti3alc2材料中,ti3alc2发生了以al元素缺失为特征的有限程度的分解反应。缺失的al元素与气氛中极微量的氧反应形成了均匀但不致密的al2o3膜;而当反应温度为1400℃时,al2o3膜发生了明显的脱落。使用热力学软件的计算结果预测,部分缺失al元素与h2反应生成气体产物alh。初步的研究结果表明,在1300℃以下ti3alc2具有较好的耐氢性能。
| [1] | 2y.c.zhou,z.m.sun,electronicstructureandbondingpropertiesinlayeredternarycarbideti3sic2,j.phys:condens.mat.,12,457(2000)
|
| [2] | 3y.c.zhou,z.m.sun,electronicstructureandbondingpropertiesoflayeredmachinableti2alcandti2alnceramincs,phys.rev.b,61,12570(2000)
|
| [3] | 5m.w.barsoum,tel-raghy,synthesisandcharacterizationofaremarkableceramic:ti3sic2,j.am.ceram.soc.,79,1953(1996)
|
| [4] | 7y.c.zhou,z.m.sun,micro-scaleplasticdeformationofpolycrystallineti3sic2underroom-temperaturecompression,j.euro.ceram.soc.,21,1007(2001)
|
| [5] | 8y.w.bao,w.wang,y.c.zhou,investigationoftherelationshipbetweenelasticmodulusandhardnessbasedondepth-sensingindentationmeasurements,actamater.,52,5297(2004)
|
| [6] | 10j.c.nappé,ph.grosseau,f.audubert,b.guilhot,m.beauvy,m.benabdesselam,i.monnet,damagesinducedbyheavyionsintitaniumsiliconcarbide:effectsofnuclearandelectronicinteractionsatroomtemperature,journalofnuclearmaterials,385,304(2009)
|
| [7] | 12c.x.wang,t.f.yang,s.y.kong,j.r.xiao,j.m.xue,q.wang,c.f.hu,q.huang,y.g.wang,effectsofheirradiationonti3alc2:damageevolutionandbehaviorofhebubbles,journalofnuclearmaterials,440,606(2013)
|
| [8] | 13x.d.qu,y.x.wang,l.q.shi,w.ding,m.wang,y.s.zhu,effectofhydrogen-dopingonbondingpropertiesofti3sic2,physicab,406(23),4460(2011)
|
| [9] | 14wangxiaohui,thesynthesisandperformanceoflayeredmachinableceramicsti3alc2,ti2alc,phdthesis,instituteofmetalresearch,chineseacademyofsciences,shenyang(2005)(王晓辉,层状可加工陶瓷ti3alc2、ti2alc的合成与性能,中国科学院金属研究所博士论文,沈阳(2005))
|
| [10] | 15h.b.zhang,volkerpresser,christophberthold,klausgeorgnickel,x.wang,mechanismsandkineticsofthehydrothermaloxidationofbulktitaniumsiliconcarbide,journalofamericanceramicsociety,93(4),1148(2010)
|
| [11] | 16j.y.wang,y.c.zhou,t.liao,afirst-principlesinvestigationofthephasestabilityofti2alcwithalvacancies,scriptamaterialia,58,227(2008)
|
| [12] | 1h.nowotny,struktuchemieeinigerverbindungenderubergangsmetallemitdenelementerc,si,ge,sn,prog.solidstatechem.,2,27(1970)
|
| [13] | 4g.hug,electronicstructuresofandcompositiongapsintheternaryti2mc,phys.rev.b,74,184113(2006)
|
| [14] | 6m.w.barsoum,m.ali,t.el-raghy,processingandcharacterizationofti2alc,ti2alnandti2alc0.5n0.5,metall.mater.,trans.a,31,1857(2000)
|
| [15] | 9a.heinzel,g.müller,a.weisenburger,compatibilityofti3sic2withliquidpbandpbbicontainingoxygen,journalofnuclearmaterials,392,255(2009)
|
| [16] | 11k.r.whittle,m.g.blackford,r.d.aughterson,s.moricca,g.r.lumpkin,d.p.riley,n.j.zaluzec,radiationtoleranceofmn+1axn,phases,ti3alc2andti3sic2,actamater.,58,4362(2010)
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