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基于团簇结构模型的低活化铁素体/马氏体钢成分设计*

Keywords: 金属材料,铁基合金,低活化铁素体/马氏体钢,团簇结构模型,成分设计

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Abstract:

?使用“团簇加连接原子”结构模型研究了低活化铁素体/马氏体钢的成分特征,确定了bccfe-cr二元基础团簇式[cr-fe14](cr0.5fe0.5),其中团簇[cr-fe14]是以溶质原子cr为心周围被14个基体fe包围的菱形十二面体。根据团簇式自洽放大和相似组元替代原则,添加v、mn、mo、w、nb和c等合金元素得到2个系列团簇成分式,无c系列[cr16fe224](cr8(v,nb,mn,mo,w,fe)8)和含c系列{[cr16fe224](cr8(v,nb,mn,mo,w,fe)8)}c1。使用铜模吸铸快冷技术制备直径6mm的合金棒,将其在1323k保温0.5h+水冷,随后在1023k保温1h+水冷。结果表明,无c系列置换固溶体合金为单一铁素体组织,含c系列合金的微观组织随着合金化组元种类和含量的不同而变化;合金的硬度随着组织的改变而改变,且置换固溶体系列合金的硬度随着合金体电子浓度vec/ra3的增加而单调降低。

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