|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
纳米三聚氰胺氰尿酸盐的合成、表征及其在酚醛泡沫中的应用*
Keywords: 有机高分子材料,材料合成,纳米三聚氰胺氰尿酸盐,溶剂热方法,酚醛泡沫
Abstract:
？以三聚氰胺和氰尿酸为原料,采用溶剂热方法制备出纳米三聚氰胺氰尿酸盐(nmc)。分别利用傅里叶变换红外光谱(ftir)、x射线衍射(xrd)、扫描电镜(sem)等手段对其组成和结构进行表征,研究了不同溶剂(蒸馏水、无水乙醇和苯)、不同类型的表面活性剂(十二烷基硫酸钠(sds)、十六烷基三甲基溴化铵(ctab)、壬基酚聚氧乙烯醚(np))、反应温度和反应时间对产物粒径的影响。结果表明,只有用水为溶剂才能合成出nmc;采用苯和无水乙醇溶剂时产物的粒径较大,为微米级。用ctab和sds为表面活性剂制备的产物平均粒径约为100nm,而用np活性剂制备的产物平均粒径则达到3.1μm。制备nmc合适的反应温度为150℃,反应时间为1-3h。比较了nmc和微米级三聚氰胺氰尿酸盐(mmc)在增韧酚醛泡沫中的阻燃性能和力学性能。结果表明,与mmc增韧酚醛泡沫相比,nmc阻燃增韧酚醛泡沫的氧指数和弯曲强度都有所提高。
| [1] | 1y.liu,q.wang,theinvestigationontheflameretardancymechanismofnitrogenflameretardantmelaminecyanurateinpolyamide-6,j.polym.res.,16(5),583(2009)
|
| [2] | 2x.lu,x.qiao,t.yang,k.sun,x.chen,preparationandpropertiesofenviron-mentalfriendlynonhalogenflameretardantmelaminecyanurate/nylon66composites,j.appl.polym.sci.,122(3),1688(2011)
|
| [3] | 3y.xu,y.liu,q.wang,melaminepolyphosphate/silicon-modifiedphenolicresinflameretardantglassfiberreinforcedpolyamide-6,j.appl.polym.sci.,129(4),2171(2013)
|
| [4] | 4k.zhang,k.wu,y.zhang,h.liu,m.shen,w.hu,flammabilitycharacteristicsandperformanceofflame-retardedepoxycompositebasedonmelaminecyanurateandammoniumpolyphosphate,polym.plast.tech.eng.,52(5),525(2013)
|
| [5] | 5w.yang,h.lu,q.tai,z.qiao,y.hu,flameretardancymechanismsofpoly(1,4-butyleneterephthalate)containingmicroencapsulatedammoniumpoly-phosphateandmelaminecyanurate,polym.adv.tech.,22(12),2136(2011)
|
| [6] | 6liukaiyu,tangyougen,theproductionofmcafameretardant,finechem.inter.,31(4),27(2001)
|
| [7] | (刘开宇,唐有根,新型氮系阻燃剂的制备,精细化工中间体,31(4),27(2001))
|
| [8] | 7h.kato,y.kawano,y.wakimura,t.yoshiyama,granularmelaminecyanurateandpreparationprocessthereof,u.s.pat.5493023a(2012).
|
| [9] | 8yangshulan,xiaojijun,liyantao,chiweijie,songpanlong,thesyntheticprocessoftheflameretardantandlubricantmelaminecyanurateacid,j.hebeiacad.sci.,17(4),219(2000)
|
| [10] | (杨淑兰,肖继君,李彦涛,匙伟杰,宋盘龙,阻燃润滑剂三聚氰胺氰尿酸盐的合成,河北省科学院学报,17(4),219(2000))
|
| [11] | (张宏宇,杜长海,阻燃润滑剂氰尿酸三聚氰胺盐的一步法合成研究,化工新型材料,34(11),32(2006))
|
| [12] | 11k.wang,d.duan,r.wang,d.liu,l.tang,t.cui,b.liu,q.cui,j.liu,b.zou,g.zou,pressure-inducedphasetransitioninhydrogen-bondedsupra-molecularadductformedbycyanuricacidandmelamine,j.phys.chem.b,113(44),14719(2009)
|
| [13] | 13wangyanxiang,fanxueyun,yuxi,effectsofsurfactantsontheperformanceofthehydrothermalsynthesisnanoznopowder,chinaceramics,44(12),26(2008)
|
| [14] | (王艳香,范学运,余熙,表面活性剂对水热合成纳米氧化锌粉性能的影响,中国陶瓷,44(12),26(2008))
|
| [15] | 14z.li,y.xiong,y.xie,selected-controlsynthesisofznonanowiresandnanorodsviaapeg-assistedroute,inorg.chem.,42(24),8105(2003)
|
| [16] | 17miyuhong,zhangxiaobin,jizhenguo,nihualiang,zhuhuayun,zhoushengming,controllablesynthesisandformationmachanismofspherical,cubicandhollowcubicpbsnanocrystals,j.inorg.mater.,25(9),1363(2009)
|
| [17] | (糜裕宏,张孝彬,季振国,倪华良,祝华云,周胜名,球状立方状及空心立方状pbs纳米晶的控制合成及其形成机理,无机化学学报,25(9),1563(2009))
|
| [18] | 18liwenjun,shierwei,tianmingyuan,wangbuguo,zhongweizhuo,synthesisofznofibersandnanometerpowdersbyhydrothermalmethod,sci.inchina(seriese),28(3),212(1998)
|
| [19] | (李汶军,施尔畏,田明原,王步国,仲维卓,水热法合成氧化锌纤维和纳米粉末,中国科学(e辑),28(3),212(1998))
|
| [20] | 19shierwei,xiachangtai,wangguobu,theaggregationgrowthinceramicpowdersmadebyhydrothermalmethod,sci.inchina(seriese),27(2),126(1997)
|
| [21] | (施尔畏,夏长泰,王国步,水热法制备陶瓷粉体中的聚集生长,中国科学(e辑),27(2),126(1997))
|
| [22] | 9zhanghongyu,duchanghai,studyonsynthesisofflameretardantlubricantmcabyone-step,chem.newmater.34(11),32(2006)
|
| [23] | 10l.perdig?o,n.champness,p.beton,surfaceself-assemblyofthecyanuricacid-melaminehydrogenbondednetwork,chem.commun.,(5),538(2006)
|
| [24] | 12y.chen,q.wang,w.yan,h.tang,preparationoffameretardantpolyamide6compositewithmelaminecyanuratenanoparticlesinsituformedinextrusionprocess,polym.degrad.stab.,91(11),2632(2006)
|
| [25] | 15sunjian,lixiaoyan,wangyanxiang,studyonpegsofttemplatehydrothermalsynthesisofznopowder,j.ceramics,31(2),331(2010)
|
| [26] | (孙健,李小燕,王艳香,peg软模板水热合成纳米氧化锌粉的研究,陶瓷学报,31(2),331(2010))
|
| [27] | 16miyuhong,zhangxiaobin,jizhenguo,nihualiang,zhuhuayun,zhoushengming,assemblysynthesisandformationmechanismofdendriticandsphericalpbsnanostructures,j.inorg.mater.,15(2),135(2010)
|
| [28] | (糜裕宏,张孝彬,季振国,倪华良,祝华云,周胜名,树枝状与球状pbs纳米结构的组装合成及其形成机理研究,无机材料学报,15(2),135(2010))
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
