|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
全沉积型铅酸液流电池石墨毡正极的性能
Keywords: 无机非金属材料,石墨毡,pbo2/pb(ii)电对,铅酸液流电池,循环伏安特性
Abstract:
？以石墨毡为电极材料,以甲基磺酸和甲基磺酸铅溶液为电解液组成全沉积型铅酸液流电池体系,研究了pbo2/pb(ii)电对在石墨毡电极上的电化学反应动力学特征和电极表面改性处理对pbo2/pb(ii)电对反应动力学行为的影响。结果表明:实验测得的pbo2/pb(ii)电对在石墨毡电极上的平衡电极电位值为1.25v,与理论值接近,且电极反应在平衡状态下的动力学特性较好；循环伏安曲线的氧化峰与还原峰电位分别为1.54v和1.238v,表明石墨毡电极pb(ii)与pbo2之间的还原反应比氧化反应更容易；在浓酸、热、热与酸结合三种表面改性方法中,以浓甲基磺酸处理的石墨毡表面电化学活性最好。
| [1] | 1zuochunmei,zhangping,yufang,wangcheng,maozongqiang,reviewaboutanovelleadacidflowbatterybasedonanelectrolytewithsolublelead(ii),chinesejournalofpowersources,33(10),919(2009)
|
| [2] | (左春梅,张萍,余芳,王诚,毛宗强,一种新型液流式铅酸蓄电池的研究进展.电源技术,33(10),919(2009))
|
| [3] | 2zhaoping,yangjiaxing,zhouqi,wangliyuan,studyonlead-acidflowbatterybasedonanelectrolytewithsolublelead(ii),chinesejournalofpowersources,33(10),1011(2009)
|
| [4] | (赵平,杨佳星,周\\琦,王立媛,基于可溶性铅(ii)离子电解液的铅酸液流电池,电源技术,33(10),1011(2009))
|
| [5] | 3penghaiyan,liweishan,liquidflowbatterybasedondepositionreaction,chinesebatteryindustry,12(1),66(2007)
|
| [6] | (彭海燕,李伟善,全沉积型铅酸液流电池概况,电池工业,12(1),66(2007))
|
| [7] | 4ahmedhazza,derekpletcherandrichardwills.anovelflowbattery:aleadacidbatterybasedonanelectrolytewithsolublelead(ii)parti.preliminarystudies.phys.chem.chem.phys.,6,1773(2004)
|
| [8] | 5derekpletcherandrichardwills.anovelflowbattery:aleadacidbatterybasedonanelectrolytewithsolublelead(ii)partii.flowcellstudies.chem.chem.phys.,6,1779(2004)
|
| [9] | 6derekpletcher,hantaozhou,garethkear,c.t.johnlow,frankc.walsh,anovelflowbattery:aleadacidbatterybasedonanelectrolytewithsolublelead(ii)partvi.studiesoftheleaddioxidepositiveelectrode[j].journalofpowersources,180,630(2008)
|
| [10] | 7xiaohongli,derekpletcher,frankc.walsh,anovelflowbattery:aleadacidbatterybasedonanelectrolytewithsolublelead(ii)partvii.furtherstudiesoftheleaddioxidepositiveelectrode.electrochimicaacta,54,4688(2009)
|
| [11] | 8johncollins,xiaohongli,derekpletcher,ravichandratangirala,frankc.walsh,caipingzhang,anovelflowbattery:aleadacidbatterybasedonanelectrolytewithsolublelead(ii)partix.electrodeandelectrolyteconditioningwithhydrogenperoxide.journalofpowersources,195,2975(2010)
|
| [12] | 9h.y.peng,h.y.chen.astudyonthereversibilityofpb(ii)/pbo2conversionfortheapplicationofflowliquidbattery.journalofpowersources,128,269(2007)
|
| [13] | 10liudi,tanning,huangkelong,liusuqin,electrochemicaloxidationofgraphitefeltmaterialsforvanadiumredoxflowbatteryapplication,chinesejournalofpowersources,30(3),224(2006)
|
| [14] | (刘迪,谭宁,黄可龙,刘素琴,全钒液流电池用石墨毡电极材料的电化学处理,电源技术,30(3),224(2006))
|
| [15] | 11wuqiumei,huangkelong,sangshangbin,l1usuqin,llxiaogang,studyofpangraphitefeltelectrodeinthevanadiumredoxflowbattery,chinesejournalofpowersources,29(7),456(2005)
|
| [16] | (伍秋美,黄可龙,桑商斌,刘素琴,李晓刚,全钒液流电池用聚丙烯腈石墨毡电极研究,电源技术,29(7),456(2005))
|
| [17] | 12lixiaogang,huangkelong,tanning,liusuqin,chenliquan,electrochemicalmodificationofgraphitefeltelectrodeforvanadiumredoxflowbattery,journalofinorganicmaterials,21(5),1114(2006)
|
| [18] | (李晓刚,黄可龙,谭宁,刘素琴,陈立泉,钒液流电池用石墨毡电极的电化学修饰,无机材料学报,21(5),1114(2006))
|
| [19] | 13yuezr,jiangw,wangl.surfacecharacteritizationofelectrochemicallyoxidizedcarbonfibers.carbon,37,1785(1999)
|
| [20] | 14sunb,skyllas-kazacosm.modificationofgraphiteelectrodematerialsforvanadiumredoxflowbatteryapplication-ithermaltreatment.jelectrochimacta,37(7),1253(1992)
|
| [21] | 15sunb,skyllas-kazacosm.chemicalmodificationofgraphiteelectrodematerialsforvanadiumredoxflowbatteryapplication-partiiacidtreatments.jelectrochimacta,37(13),2459(1992)
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
