OALib Journal期刊
ISSN: 2333-9721
费用:99美元
|
|
|
au修饰sno2复合纳米材料的制备和气敏性能
Keywords: 复合材料,sno2,au修饰,水热合成法,气敏性能
Abstract:
?以氯金酸和乙酰丙酮氯化锡为主要材料,通过一步水热法制备了sno2和au修饰的sno2(au/sno2)纳米粒子。使用tem、eds、xrd和xps等手段对样品的形貌、组成及结构进行表征,研究了两种材料对乙醇的气敏性能。结果表明,两种纳米颗粒的尺寸都比较均一,平均直径约为9--12nm;sno2为四方金红石结构,au为面心立方结构;在au/sno2样品中,au与sno2的重量比为2.6%,au元素主要以au0的价态存在并含有少量的au3+价态;与纯sno2纳米粒子相比,au修饰可显著提高气敏元件对乙醇响应的灵敏度和选择性。
References
[1] | 2m.s.park,g.x.wang,y.m.kang,preparationandelectrochemicalpropertiesofsno2nanowiresforapplicationinlithium-ionbatteries,angew.chem.int.ed.,46(5),750(2007)
|
[2] | 3l.h.jiang,g.q.sun,z.h.zhou,size-controllablesynthesisofmonodispersedsno2nanoparticlesandapplicationinelectrocatalysts,j.phys.chem.b,109(18),8774(2005)
|
[3] | 7h.huang,c.y.ong,j.guo,t.white,m.s.tse,o.k.tan,ptsurfacemodificationofsno2nanorodarraysforcoandh2sensors,nanoscale,2(7),1203(2010)
|
[4] | 21xujianqiang,hanjianjun,xiebing,liuyun,studiesongassensitivepropertiesandmechanismofau-in2o3basedcogassensor,chinesejournalofsensorsandactuators,20(3),481(2007)
|
[5] | (徐甲强,韩建军,谢冰,刘云,au--in2o3co气体传感器的性能与机理研究,传感技术学报,20(3),481(2007)
|
[6] | 22a.kolmakov,m.moskovits,enhancedgassensingbyindividualsno2nanowiresandnanobeltsfunctionalizedwithpdcatalystparticles,nanolett.,5(4),667(2005)
|
[7] | 1x.x.xu,j.zhuang,x.wang,sno2quantumdotsandquantumwires:controllablesynthesis,self-assembled2darchitecturesandtheirgassensingproperties,j.am.chem.soc.,130(37),12527(2008)
|
[8] | 4j.kaur,r.kumar,m.c.bhatnagar,effectofindiumdopedsno2nanoparticlesonno2gassensingproperties,sensorsandactuatorsb,126(2),478(2007)
|
[9] | 5x.h.liu,j.zhang,x.z.guo,s.r.wang,s.h.wu,coreshellα–fe2o3@sno2/auhybridstructuresandtheirenhancedgassensingproperties,rscadvances,2(4),1650(2012)
|
[10] | 6j.zhang,x.h.liu,s.h.wu,m.j.xu,x.z.guo,s.r.wang,aunanoparticle-decoratedporoussno2hollowspheres:anewmodelforachemicalsensor,j.mater.chem.,20(31),6453(2010)
|
[11] | 8a.kolmakov,s.potluri,a.barinov,t.o.mentes,l.gregoratti,m.a.nino,a.locatelli,m.kiskinova,spectromicroscopyforaddressingthesurfaceandelectron
|
[12] | transportpropertiesofindividual1–dnanostructuresandtheirnetworks,acsnano,2(10),1993(2008)9y.nagasawa,t.choso,t.karasuda,s.shimomura,f.ouyang,k.tabata,y.yamaguchi,photoemissionstudyoftheinteractionofareducedthinfilmsno2withoxygen,surf.sci.,433-435,226(1999)
|
[13] | 10nistx-rayphotoelectronspectroscopydatabase,version3.5(nationalinstituteofstandardsandtechnology,gaithersburg,2003).http://srdata.nist.gov/xps/
|
[14] | 11m.seruga,h.m.metikos,t.valla,m.milun,h.hoffschultz,k.wandelt,electrochemicalandx-rayphotoelectronspectroscopystudiesofpassivefilmontinincitratebuffersolution,j.electroanal.chem.,407(1-2),83(1996)
|
[15] | 12y.c.liu,enhancementintheramanscatteringofpolypyrroleelectrodepositedonroughenedgoldsubstratescoatedwithgoldmonolayers,j.phys.chem.b,108(9),2948(2004)
|
[16] | 13x.sun,s.dong,e.wang,one-steppreparationofhighlyconcentratedwell-stablegoldcolloidsbydirectmixofpolyelectrolyteandhaucl4aqueoussolutionsatroomtemperature,journalofcolloidandinterfacescience,288(1),301(2005)
|
[17] | 14w.zhao,h.y.chen,fabrication,characterizationandapplicationofgoldnano-structuredfilm,electrochemistrycommunications,8(5),773(2006)
|
[18] | 15k.joudkazis,j.joudkazyte,v.jasulaitiene,a.lukinsas,b.sebeka,xpsstudiesonthegoldoxidesurfacelayerformation,electrochemistrycommunications,2(7),503(2000)
|
[19] | 16y.mikhlina,m.likhatskia,y.tomashevicha,a.romanchenkoa,s.erenburgb,s.trubina,xasandxpsexaminationoftheau-snanostructuresproducedviathereductionofaqueousgold(iii)bysulfideions,journalofelectronspectroscopyandrelatedphenomena,177(1),24(2010)
|
[20] | 17k.rajecv,srivastava,p.lal,sensingmechanismintinoxide-basedthick-filmgassensors,sensorsandactuatorsb,21(3),213(1994)
|
[21] | 18o.hisao,s.hirokazu,m.takahashi,sensingmechanismofsno2thinfilmgassensors,sensorsandactuatorsb,14(1-3),677(1993)
|
[22] | 19l.b.kong,y.s.shen,gas-sensingpropertyandmechanismofcaxla1?xfeo3ceramics,sensorsandactuatorsb,30(3),217(1996)
|
[23] | 20p.lu,s.shishiyanu,l.chow.nanostructuredzincoxidegassensorsbysuccessiveioniclayeradsorptionandreactionmethodandrapidphotothermalprocessing,thinsolidfilms,516(10),3338(2008)
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|