|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
高温型pvdf/pssa复合膜的质子传导性能
Keywords: 聚偏氟乙烯,聚苯乙烯磺酸,复合膜,半互穿网络
Abstract:
？通过自由基加聚反应制备了聚偏氟乙烯(pvdf)/聚苯乙烯磺酸(pssa)复合膜,通过sem、edx、电化学阻抗谱(eis)和tg等方法表征复合膜的微结构、电化学及尺寸稳定性和力学性能等性能与反应时间的关系。结果表明,随着反应时间的延长，pvdf/pssa复合膜的含水率、质子传导率逐渐增大。反应时间为8h的复合膜,其含水率在常温下达到4.4%,质子传导率达到0.375s/cm,抗拉强度为32.1mpa。这表明,在采用自由基加聚反应制备的复合膜中形成了稳固的半互穿网络(sipn)结构,在保持一定的热稳定性能、尺寸稳定性以及力学性能的条件下,其质子传导性能明显改善。
| [1] | 1yibaolian,fuelcells–principletechnologyapplication(beijing,chemicalindustrypress,2003)p.351
|
| [2] | (衣宝廉,燃料电池--原理？技术？应用(北京,化学工业出版社,2003)p.351)
|
| [3] | 2s.j.c.cleghorn,x.ren,t.e.springer,m.s.wilson,c.zawodzinski,t.a.zawodzinski,s.gottesfeld,pemfuelcellsfortransportationandstationarypowergenerationapplications,journalofhydrogenenergy,22,1137(1997)
|
| [4] | 3w.g.grot,perfluorinatedionexchangepolymersandtheiruseinresearchandindustry,macromol.symp.,82(1),161(1994)
|
| [5] | 7zhangyaoxia,zhuxiuling,jianxigao,preparationofsulfonatedpoly(phthalazinoneetherketoneketone)andpropertiesofthecompositemembranessppekk/bpo4,chinesejournalofmaterialsresearch,23(2),215(2009)
|
| [6] | 10a.d.jenkins,p.kratochvfl,r.f.t.stepto,u.w.suter,glossaryofbasictermsinpolymerscience,pureandappliedchemistry,68(12),2287(1996)
|
| [7] | 11j.r.millar,interpenetratingpolymernetworksstyrene–divinylbenzenecopolymerswithtwoandthreeinterpenetratingnetworksandtheirsulphonates,journalofthechemicalsociety,236,1311(1960)
|
| [8] | 12hechunqing,zhangshaoping,wangshaojie,wangguiyou,huchunpu,freevolumepropertiesofinterpenetratingpolymernetworksprobedbypositronannihilation,wuhanuniversityjournal:neo–confucianismversion,46(1),63(2000)
|
| [9] | (何春清,戴益群,张少平,王少阶,王贵友,胡春圃,穿网络聚合物的自由体积特性,武汉大学学报:理学版,46(1),63(2000))
|
| [10] | 4maozongqiang,xiexiaofeng,lutianhong,fuelcells(beijing,chemicalindustrypress,2005)p.2
|
| [11] | (毛宗强,谢晓峰,陆天虹,燃料电池(北京,化学工业出版社,2005)p.2)
|
| [12] | 5rensuzhen,sungongquan,wuzhimou,lichennan,jinwei,xinqin,yangxuefeng,blendmembranesofsulfonatedpolyetherether,ketone/polyvinylidenefluoride,chinesejournalofpowersources,30(3),200(2006)
|
| [13] | (任素贞,孙公权,吴智谋,李辰楠,金巍,辛勤,杨学锋,化聚醚醚酮/聚偏氟乙烯共混膜的研究,电源技术,30(3),200(2006))
|
| [14] | 6s.m.zaidi,s.d.mikhailenko,g.p.robertson,protonconductingcompositemembranesfrompolyetheretherketoneandheteropolyacidsforfuelcellapplications,journalofmembranescience,173(1),17(2000)
|
| [15] | (张耀霞,朱秀玲,蹇锡高,磺化聚芳醚酮酮的制备及磷酸硼复合膜的性能,材料研究学报,23(2),215(2009))
|
| [16] | 8y.m.shang,x.f.xie,h.jin,j.w.guo,y.w.wang,s.g.feng,s.b.wang,j.m.xue,synthesisandcharacterizationofnovelsulfonatednaphthalenicpolyimidesasprotonconductivemembranefordmfcapplications,europeanpolymerjournal,42(11),2987(2006)
|
| [17] | 9l.h.sperling,interpenetratingpolymernetworksandrelated
|
| [18] | materials(newyork,plenumpress,1981)p.2
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
