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涂料工业  2011 

高固含量水性聚氨酯的合成及其主要影响因素

Keywords: 水性聚氨酯,高固含量,分散体,涂料

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Abstract:

?以异佛尔酮二异氰酸酯(ipdi)和六亚甲基二异氰酸酯(hdi)为硬段,聚醚二元醇(n-220)及聚酯二元醇(pba)为软段,二羟甲基丙酸(dmpa)为亲水性物质,乙二胺(eda)为后扩链剂等,合成了固含量约为50%的环氧树脂(e-20)及甲基丙烯酸甲酯(mma)复合改性的水性聚氨酯分散体(pud)。并探讨了—nco/—oh物质的量比、软段类型和软段相对分子质量对高固含量水性聚氨酯性能的影响,同时对制得的pud进行红外、透射电镜等测试分析,从而制备出性能较好、较稳定的高固含量水性聚氨酯分散体。

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