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涂料工业  2011 

梯度共聚物的最新进展

Keywords: 梯度共聚物,原子转移自由基聚合,可逆加成-断裂链转移聚合,梯度共聚物的表征

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Abstract:

?阐述了梯度共聚物的概念及梯度共聚物的研究意义,介绍了梯度共聚物分类及特点,以及与这些特点相对应的各种用途。重点综述了近年来各种梯度共聚物的制备方法如常规乳液聚合、原子转移自由基聚合(atrp)、可逆加成-断裂链转移聚合(rafp)和氮氧调控自由基聚合(nmcrp)等,以及梯度共聚物的各种表征方法,如红外光谱(ft-ir)、核磁共振(nmr)、薄层色谱(tlc)以及x射线光电子能谱(xps),并进一步分析了梯度共聚物的研究方向和研究重点。

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