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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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环氧大豆油-乳酸改性水性聚氨酯乳液的制备及性能研究
Keywords: 环氧大豆油,乳酸,改性,水性聚氨酯
Abstract:
？以异佛尔酮二异氰酸酯（ipdi）、2，2-二羟甲基丙酸（dmpa）、大豆油（soy）、乳酸（la）为主要原料合成了水性聚氨酯乳液（wpu）。通过红外分析（ft-ir）的手段对环氧大豆油-乳酸多元醇的结构进行了表征；利用透射电镜（tem）、热重分析（tga）、差示扫描量热法（dsc）及拉伸力学性能测试等方法探讨了水性聚氨酯乳液的形态、稳定性及其涂膜的耐热性能和机械性能。结果表明：利用环氧大豆油-乳酸开环聚酯多元醇合成的水性聚氨酯乳液具有良好的稳定性，粒子形态均一，乳液流平所制得的涂膜耐热性能及力学性能优异。
| [1] | luys,larockrc.newhybridlatexesfromasoybeanoil-basedwaterbonrepolyurethaneandacrylicsviaemulsionpolymerization[j].biomacromolecules,2007,8（10）:3108-3114.
|
| [2] | luys,larockrc.soybean-oil-basedwatrebornepolyurethanedispersiospolyurethanedispersions:effectsofpolyolfunctionalityandhardsegmentcontentonproperties[j].biomacromolecules,2008,9（11）:3332-3340.
|
| [3] | kimbs,kimbk.enhancementofhydrolyticstabilityandadhesionofwaterbornepolyurethanes[j].journalofappliedpolymerscience,2005,97（5）:1961-1969.
|
| [4] | jhonyk,cheongiw,kimjh.chainextensionstudyofaqueouspolyurethanedispersions[j].colloidsandsurfacesa:physicochemicalandengineeringaspects,2001,179（1）:71-78.
|
| [5] | coutinhofmb,delpechmc.somepropertiesoffilmscastfrompolyurethaneaqueousdispersionsofpolyether-basedanionomerextendedwithhydrazine[j].polymertesting,1996,15（2）:103-113.
|
| [6] | kimbk,seojw,jeonghm.morphologyandpropertiesofwaterbornepolyurethaneclaynanocomposites[j].europeanpolymerjournal,2003,39（1）:85-91.
|
| [7] | gandinia.polymersfromrenewableresources:achallengeforthefutureofmacromolecularmaterials[j].macromolecules,2008,41（24）:9491-9504.
|
| [8] | biermannu,friedtw,langs,etal.newsyntheseswithoilsandfatsasrenewablerawmaterialsforthechemicalindustrybiermann[j].angewandtechemiteinternationaledition,2000,39（13）:2206-2224.
|
| [9] | williamsck,hillmyerma.polymersfromrenewableresources:aperspectiveforaspecialissueofpolymerreviews[j].polymerreviews,2008,48（1）:1-10.
|
| [10] | petroviczs.polyurethanesfromvegetableoils[j].polymerreviews,2008,48（1）:109-155.
|
| [11] | meiermar,metzqerjo,schubertus.plantoilrenewableresourcesasgreenalternativesinpolymerscience[j].chemicalsocietyreviews,2007,36（11）:1788-1802.
|
| [12] | 郭文杰,傅和青,司徒粤,等.环氧大豆油改性水性聚氨酯胶粘剂[j].包装工程,2008,29（8）:1-3,9.[13]胡国文,沈慧芳,司徒粤,等.羟基化环氧大豆油改性水性聚氨酯-丙烯酸酯涂料的研制[j].涂料工业,2008,38（11）:33-36.
|
| [13] | sureshki.rigidpolyurethanefoamsfromcardanol:synthesis,structuralcharacterization,andevaluationofpolyolandfoamproperities[j].acssustainablechemistry＆engineering,2013,1（2）:232-242.
|
| [14] | leesj,kimbk.covalentincorporationofstarchderivativeintowaterborneforbiodegradability[j].carbohydratepolymers,2012,87（2）:1803-1809.
|
| [15] | zlatanica,lavec,zhangw,etal.effectofstructureonpropertiesofpolyolsandpolyurethanesbasedondifferentvegetableoils[j].journalofpolymersciencepartb:polymerphysics,2004,42（5）:809-819.
|
| [16] | 颜萍,陈文求,徐祖顺.大豆油衍生物的制备及其在涂料中的应用[j].现代涂料与涂装,2013,16（2）:1-4,11.
|
| [17] | zhangm,songf,wangyz.developmentofsoyproteinisolate/waterbornepolyurethaneblendfilmswithimprovedproperities[j].colloidsandsurfacesb:biointerfaces,2012(100):16-21.
|
| [18] | changcw,lukt.naturalcastoroilbased2-packagewaterbornepolyurethanewoodcoatings[j].progressinorganiccoatings,2012,75（4）:435-443.
|
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