OALib Journal期刊
ISSN: 2333-9721
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苯乙烯-甲基丙烯酸甲酯无皂核壳乳液合成及表征
Keywords: 溶液聚合,无皂,核壳乳液
Abstract:
?采用溶液聚合法制得苯乙烯(st)与苯乙烯磺酸钠(nass)共聚物的种子乳液,将其用于甲基丙烯酸甲酯(mma)的无皂种子乳液聚合,制得了一系列不同核壳单体配比的核壳乳液。通过对溶液聚合动力学、产物的结构与相对分子质量、种子粒径以及将其用于乳液聚合时所得产物的结构与粒子形态分析,结果表明:以溶液聚合法制得的苯乙烯型种子乳液能成功制备无皂核壳乳液,从而为制备无皂核壳乳液提供了新的途径。
References
[1] | songxj,huj,wangcc,etal.synthesisofhighlysurfacefunctionalizedmonodispersedpoly(stdvbgma)nanosphereswithsoap-freeemulsionpolymerizationfollowedbyfacile“clickchemistry”withfunctionalizedalkylthiols[j].colloidsandsurfacesa:physicochemicalandengineeringaspects,2011,380(1-3):250-256.
|
[2] | dengw,lirl,zhangmj,etal.influencesofmaaontheporousmorphologyofp(st-maa)latexparticlesproducedbybatchsoap-freeemulsionpolymerizationfollowedbystepwisealkaliacidpost-treatment[j].journalofcolloidandinterfacescience,2010,349(1):122-126.
|
[3] | khanak,raybc,doluisk.preparationofcore-shellemulsionpolymerandoptimizationofshellcompositionwithrespecttoopacityofpaintfilm[j].progressinorganiccoatings,2008,62(1):65-70.
|
[4] | muyc,qiut,lixy.monodisperseandmultilayercore-shelllatexviasurfacecross-linkingemulsionpolymerization[j].materialsletters,2009,63(18-19):1614-1617.
|
[5] | rahmanmm,chehimimm,fessih,etal.highlytemperatureresponsivecore-shellmagneticparticles:synthesis,characterizationandcolloidalproperties[j].journalofcolloidandinterfacescience,2011,360(2):556-564.
|
[6] | leesm,leesj,kimjh,etal.synthesisofpolystyrenepolythiophenecoreshellnanoparticlesbydualinitiation[j].polymer,2011,52(19):4227-4234.
|
[7] | leej,hongck,choes,etal.synthesisofpolystyrenesilicacompositeparticlesbysoap-freeemulsionpolymerizationusingpositivelychargedcolloidalsilica[j].journalofcolloidandinterfacescience,2007,310(1):112-120.
|
[8] | dziomkinanv,hempeniusma,vancsogj.synthesisofcationiccore-shelllatexparticles[j].europeanpolymerjournal,2006,42(1):81-91.
|
[9] | 高庆,陈正国,程时远,等.苯乙烯丙烯酸丁酯丙烯酸溶液共聚合动力学研究[j].高分子材料科学与工程,2002,18(4):52-56.
|
[10] | 李克友,耿克斌,朱弼忠.种子乳液共聚合聚氨酯-聚丙烯酸酯胶乳粒子的“反相核-壳”结构[j].合成橡胶工业,1998,21(3):158-160.
|
[11] | yanr,zhangyy,wangxh,etal.synthesisofporouspoly(styrene-co-acrylicacid)microspheresthroughone-stepsoap-freeemulsionpolymerization:whysandwherefores[j].journalofcolloidandinterfacescience,2012,368(1):220-225.
|
[12] | lirl,kancy,lizp,etal.preparationofmultihollowp(st-maa)particlesbysequencesoap-freesoapemulsionpolymerizationandfollowedbystepwisealkaliacidposttreatment[j].chinesechemicalletters,2007,18(6):741-743.
|
[13] | kimg,lims,leebh,etal.effectofhomogeneityofmethanolwatermonomermixtureonthemodeofpolymerizationofmma:soap-freeemulsionpolymerizationversusdispersionpolymerization[j].polymer,2010,51(5):1197-1205.
|
[14] | lum,heb,wangls,etal.preparationofpolystyrene-polyisoprenecore-shellnanoparticlesforreinforcementofelastomers[j].compositespartb:engineering,2012,43(1):50-56.
|
[15] | prez-carrillola,pucam,rabelerom,etal.effectofparticlesizeonthemechanicalpropertiesofpolystyreneandpoly(butylacrylate)coreshellpolymers[j].polymer,2007,48(5):1212-1218.
|
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