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涂料工业  2009 

so2气体对不同石材防护涂料的影响

Keywords: so2,防护涂料,石灰岩,腐蚀,老化

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Abstract:

?大气中so2气体是造成石灰质文物化学腐蚀的最重要因素之一。设计了一套so2老化装置来评价两种有机硅防护涂料(pelicoat和mellerud),在浓度30mg/m3so2下的防护石材效果情况。使用毛细管吸收量评价防护涂料的保护程度,使用接触角评价防护涂料的疏水性,使用离子色谱测定石灰岩腐蚀层中形成的硫酸盐,根据硫酸盐的量决定石灰岩的腐蚀程度。实验结果表明,两种防护涂料老化480h后,其保护系数均有不同程度的减少。随着老化时间的增加,用pelicoat、mellerud涂覆的样品接触角逐渐减少,pelicoat的降幅要大于mellerud,两种防护涂料抗so2防护效果下降。sem电镜发现样品经过老化涂覆后,试样表面孔隙变大、孔隙数增加。

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