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OALib Journal期刊
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环境中植酸的分布、形态及界面反应行为
DOI: 10.3724/SP.J.1145.2012.00494, PP. 494-501
Keywords: 肌-肌醇六磷酸,植酸,吸附,解吸,铁铝氧化物,粘土矿物,多价阳离子,界面反应,金属污染土壤修复
Abstract:
肌-肌醇六磷酸（myo-inositol-1,2,3,4,5,6-hexakisphosphate，ihp，myo-ip6）简称植酸（phyticacid或phytate），是大多数土壤中最为丰富的有机磷，它在环境中的界面反应影响着磷素的迁移、循环、转化、生物有效性以及环境效应.本文简要总结了环境中植酸的分布与形态，并综述了其界面反应，包括铁铝氧化物、粘土矿物、碳酸钙等对植酸的吸附解吸，多价阳离子与植酸的络合反应以及沉淀作用.土壤矿物对植酸的吸附影响其转化和生物有效性，矿物对植酸磷的吸附量一般远高于正磷酸盐.其中，弱晶质铁铝（氢）氧化物对植酸的吸附能力一般较晶形铁铝（氢）氧化物大很多.同时，分析了矿物类型、介质ph、温度、共存离子等环境条件对植酸界面反应的影响，植酸吸附对矿物表面电荷性质、颗粒大小和分散稳定性等的作用，以及植酸在金属污染土壤修复中的应用前景.最后讨论了环境中植酸的主要研究热点和方向.
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