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热力发电  2014 

选择性催化还原工艺中硫酸氢铵形成机理及影响因素

, PP. 75-78

Keywords: 烟气脱硝,选择性催化还原,硫酸氢铵,氨逃逸,空气预热器

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Abstract:

论述了选择性催化还原(scr)烟气脱硝过程中硫酸氢铵(abs)的形成机理,并分析了温度、氨逃逸量、so?3浓度、飞灰等对abs形成的影响规律。分析表明:abs的形成温度为190~240℃;当温度在320~345℃时abs为气相,当温度高于345℃时abs开始分解;为减少abs的生成量,可通过控制nh?3/no??x?摩尔比在0.8~1.2之间,以减少氨逃逸量,同时尽可能减少烟气中so?2氧化率;调节scr工艺运行温度,控制abs在催化剂中的沉积,可避免催化剂堵塞和腐蚀。

References

[1]  张强,许世森,王志强,等.选择性催化还原烟气脱硝技术进展及工程应用[j].热力发电,2004(4):1�6.zhangqiang,xushishen,wangzhiqiang.advancementandengineeringapplicationoffluegasdenitrificationtechnologybyusingselectivecatalyticreductionmethod[j].thermalpowergeneration,2004(4):1�6.�
[2]  杨�.氮氧化物减排技术与烟气脱硝工程[m].北京:冶金工业出版社,2007.yangyang.noxreductiontechnologyandfluegasdenitrificationproject[m].beijing:metallurgicalindustrypress,2007(inchinese).�
[3]  马双忱,金鑫,孙云雪,等.scr烟气脱硝过程硫酸氢铵的生成机理与控制[j].热力发电,2010,39(8):12�17.mashuangchen,jinxin,sunyunxue,etal.theformationmechanismofammoniumbisulfateinscrfluegasdenitrificationprocessandcontrolthereof[j].thermalpowergeneration,2010,39(8):12�17.�
[4]  chothanic.ammoniumbisulfate(abs)measurementforscrno��x�controlandairheaterprotection[r].carnegie:breenenergysolution,2008:1�13.�
[5]  赵宗让.电厂锅炉scr烟气脱硝系统设计优化[j].中国电力,2005,38(11):69�74.zhaozongrang.designoptimizationofscrsystemforcoal�firedboilers[j].electricpower:2005,38(11):69�74.�
[6]  shikadet,obat,fujimotok,etal.chemicalproductresearchanddevelopment[j].industrialengineering,1984,23:417.�
[7]  sutulara,huntjb.stoichiometryandkineticsofthedecompositionofsomecobalt(iii)amminesinmoltenammoniumbisulfateandconcentratedsulfuricacid[j].inorganicchemistry1972,11(8):1879�1886.�
[8]  wilburnrt,wrighttl.scrammoniaslipdistributionincoalplanteffluentsanddependenceuponso�3[j].powerplantchemistry,2004,6:295�314.�
[9]  burkejm,johnsonkl.ammoniumsulfateandbisulfateformationinairpreheaters[r].washington:unitedstatesenvironmentprotectionagency,1982.�
[10]  andoj.noxabetementforstationarysourcesinjapan[r].washington:unitedstatesenvironmentprotectionagency,1979.�
[11]  nenads.improvingtheperformanceofboilerauxiliaries,parti[j].coalpower,2010(10):1�35.�
[12]  wrightt,delallom.increasedso�3andammoniaslipfromscr:balancingairheaterdeposits,ammoniaineffluentdischarge,andso3plume[c]//proceedingsof2002conferenceonselectivecatalyticreduction(scr)andselectivenon�catalyticreduction(sncr)fornox�control.pittsburgh,pennsylvania:nationalenergytechnologylaboratory(netl).2002.
[13]  andoj.recentdevelopmentsinso�2andnox�abatementtechnologyforstationarysourcesinjapan[j].1985.�
[14]  liuz,woosi.recentadvancesincatalyticdeno��x�scienceandtechnology[j].catalysisreviews,2006,48(1):43�89.�
[15]  bondurantlp,countermanws,rhodesrb.minimizingtheimpactofscr/sncrretrofitsontheljungstromairpreheater[r].wellsville:alstompowerairpreheaterinc,1999:1�6.�
[16]  吴碧君,王述刚,方志星,等.烟气脱硝工艺及其化学反应原理分析[j].热力发电,2006(11):59�60.wubijun,wangshugang,fangzhixing,etal.fluegasdenttrification(denitrification)technologiesandanalysisoftheirchemicalreactons[j].thermalpowergeneration,2006(11):59�60.�
[17]  morettial,triscorirj,ritzenthalerdp.asystemapproachtoso3mitigation[r].ohio:thebabcock&wilcoxcompany,2006:1�6.�
[18]  hansjh,lindenhoffpi,safronovs.scrdesignissuesinreductionofnox�emissionsfromthermalpowerplants[r].frederikssund:haldortopsoeinc,2007:1�21.�
[19]  scotp,chrisd.scrcatalystmanagement:enhancingoperationalflexibility[c]//powerplantairpollutantcontrolmegasymposium.2006:1�12.�
[20]  moserre.benefitsofeffectiveso3removalincoal�firedpowerplants:beyondopacitycontrol[r].powerplantairpollutantcontrolmegasymposium,2006:1�14.�
[21]  ahmads,lindenhoffpi,slaughterjd.experiencewithdesign,installationandoperationofascrunitafterafccu[c]//catalysttechnologyatannualnprameeting.2005:1�10.�
[22]  shomatech,naylorbf.high�temperatureheatcontentsofaluminumoxide,aluminumsulfate,potassiumsulfate,ammoniumsulfateandammoniumbisulfate[j].journaloftheamericanchemicalsociety,1945,67(1):72�75.�
[23]  nenads.improvingtheperformanceofboilerauxiliaries,partii[j].coalpower,2011(2):1�35.�
[24]  thogersenjr,slabiakt,whiten,etal.ammoniumbisulphateinhibitionofscrcatalysts[r].frederikssund:haldortopsoeinc,2007:1�16.�
[25]  zhuzp,niuhx,liuzy,et.al.decompositionandreactivityofnh�4hso�4onv�2o�5/accatalystsusedfornoreductionwithammonia[j].journalofcatalysis,2000,195(2):268�278.�
[26]  李靖华,张桂恩.硫酸氢铵分解动力学及其分解机理的研究[j].物理化学学报,1992,8(1):123�127.lijinghua,zhangguien.investigationofthekineticsandmechanismofdecompositionofammoniumhydrogensulfate[j].actaphysico�chimicasinica:1992,8(1):123�127.�
[27]  deanw.insituanalysisofammoniaslipandwatervapourusingatunablediodelaserforscr/sncroptimizationandboilertubesurveillanceinpowerplants[j].instrumentation,systems,andautomationsocietyanalysisdivisionnewsletter,2004,25(1):10�16.�
[28]  nenads.improvingtheperformanceofboilerauxiliaries,partiii[j].coalpower,2011(4):1�35.�
[29]  bilirgenh,levye,romeroc,etal.optimizingcombinedboiler�scroperations[j].lehighenergyupdate,2009,27(1):1�2.�
[30]  romeroce.optimizationofscrcontroltechnologyforreducedno��x�emissions,improvedperformanceandreducedoperatingexpenses[r].bethlehem,pa:thenewyorkstateenergyresearchanddevelopmentauthority,2009:1�92.�
[31]  匡国强,徐党旗.选择性催化还原(scr)脱硝装置对锅炉结构的影响[j].热力发电,2006(10):36�39.kuangguoqiang,xudangqi.influenceofscrdenitrificationfacilityupontheboilerstructure[j].thermalpowergeneration,2006(10):36�39.�
[32]  thomas.scroperationoptimization:so�3removaltooptimizecatalystlife&nh3distributioninwastewater[r].chattanooga,tennessee,parsonsenergy&chemicals,2003.

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