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热力发电  2014 

等转化率法对生物质热解动力学的研究

, PP. 57-60

Keywords: 生物质,玉米芯,花生壳,热解,动力学分析,等转化率法

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Abstract:

采用starink等转化率法对玉米芯和花生壳的热解过程进行了动力学求解,在不同的转化率下玉米芯的活化能变化较小,基本在(208.11±7.11)kj/mol,而花生壳的活化能则变化较大。同时,采用主曲线法对玉米芯热解过程进行机理函数筛选,当转化率小于0.6时,玉米芯热解过程遵循四级反应;当转化率大于0.6时,玉米芯热解过程遵循三级反应。

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