全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

氯仿在悬浮tio2体系中的降解

DOI: 10.3969/j.issn.1671-7627.2004.04.002, PP. 5-9

Keywords: tio2,氯仿,光催化,溶氧量

Full-Text   Cite this paper   Add to My Lib

Abstract:

分别用光还原沉积法制备的掺铂tio2纤维和商用tio2作为催化剂,对氯仿进行光催化降解.通过测定cl-浓度发现不同通o2方式对氯仿的光降解有很大影响,o2的存在,促进了氯仿的降解;并进一步对溶液中的溶氧量(do)测定,发现do值呈线性下降且氯仿降解过程中有氧降解和无氧降解2种机理是共存的;同时发现上述2种催化剂的反应现象大相径庭,并结合了有机质液相吸附理论对其反应现象进行分析,发现纤维状微观结构是其高光催化性能的直接原因.

References

[1]  annlorettepruden,davidfo.degradationofchloroformbyphotoassistedheterogeneouscatalysisindiluteaqueoussuspensionsoftitaniumdioxide[j].environmentalscienceandtechnology,1983.628-631.doi:10.1021/es00116a013.
[2]  杨祝红,暴宁钟,刘畅.tio2纤维的制备及其光催化活性研究[j].高等学校化学学报,2002(7):1371-1375.doi:10.3321/j.issn:0251-0790.2002.07.033.
[3]  maryeannefox,mariatdulay.heterogeneousphotocatalysis[j].chemicalreviews,1993.341-357.
[4]  史月萍,杨祝红,冯新.掺铂二氧化钛纤维光催化降解氯仿的研究[j].催化学报,2003(9):663-668.doi:10.3321/j.issn:0253-9837.2003.09.007.
[5]  qingzhongyuan,ravikrishnar,valsarajkt.reusableadsorbentsfordilutesolutionseparation.5:photodegradationoforganiccompoundsonsurfactant-modifiedtitania[j].separationandpurificationtechnology,2001.309-318.doi:10.1016/s1383-5866(01)00136-8.
[6]  hongfeilin,ravikrishar,valsarajkt.reusableadsorbentsfordilutesolutionseparation.6:batchandcontinuousreactorsfortheadsorptionanddegradationof1,2-dichlorobenzenefromdilutewastewaterstreamsusingtitaniaasaphotocatalyst[j].separationandpurificationtechnology,2002,(2):87-102.doi:10.1016/s1383-5866(02)00017-5.
[7]  amyllinsebigler,guanquanlu,johntyates.photocatalysisontio2surfaces:principles,mechanisms,andselectedresults[j].chemicalreviews,1995,(3):735-758.doi:10.1021/cr00035a013.
[8]  李太友,李华禄,童言秀.水中氯仿的非均相光催化降解反应动力学研究[j].湖北化工,1994.23-26.
[9]  luxh,baonzh,jixy.meanactivitycoefficientsinthenacl-nh4hco3-h2osystemat293.15-308.15k[j].fluidphaseequilibria,2001,(1/2):259-270.
[10]  陆小华,暴宁钟,吉晓燕.溶解和离子交换反应中k+的快速测定[j].化工学报,2002(3):241-245.doi:10.3321/j.issn:0438-1157.2002.03.006.
[11]  jixy,luxh,lish.activitycoefficientsofhclinthehcl+nh4cl+h2osystemsat298.15and313.15k[j].journalofchemicalandengineeringdata,2000,(1):29-32.doi:10.1021/je990139t.
[12]  mariadhernondez-alonson,juanmcoronado,javiermariaa.ozoneenhancedactivityofaqueoustitaniumdioxidesuspensionsforphotocatalyticoxidationoffreecyanideions[j].appliedcatalysisb:environmental,2002,(3):257-267.doi:10.1016/s0926-3373(02)00119-4.
[13]  kormannc,bahnemanndw,hoffmannmr.photolysisofchloroformandotherorganicmoleculesinaqueous[j].environmentalscienceandtechnology,1991.494-500.doi:10.1021/es00015a018.
[14]  carlosamartin,miguelabaltanas,albertoecassano.photocatalyticdecompositionofchloroforminafullyirradiatedheterogeneousphotoreactorusingtitaniumoxideparticulatesuspensions[j].catalysistoday,1996.221-227.doi:10.1016/0920-5861(95)00191-3.
[15]  machaelrhoffmann,scottmartin,wonyongchoi.environmentalapplicationsofsemiconductorphotocatalysis[j].chemicalreviews,1995.69-96.
[16]  choiwy,hoffmannmr.novelphotocatalyticmechanismsforchcl3,chbr3,andccl3co2-degradationandthefateofphotogeneratedtrihalomethylradicalsontio2[j].environmentalscienceandtechnology,1997.89-95.doi:10.1021/es960157k.
[17]  叶振华.化工吸附分离过程[m].北京:中国石化出版社,1992.57.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133