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管式氧化石墨烯膜用于乙醇脱水过程

DOI: 10.3969/j.issn.1671-7627.2015.05.001, PP. 1-5

Keywords: 乙醇脱水,渗透汽化,氧化石墨烯,膜分离

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Abstract:

为了研究新型二维氧化石墨烯膜材料在乙醇脱水过程中的应用,采用改进的hummers法制备氧化石墨烯,通过傅里叶变换红外光谱仪(ft-ir)、热分析仪(tg-dsc)和场发射扫描电子显微镜(fesem)等表征氧化石墨烯的微结构及性质。以管式陶瓷超滤膜为支撑体,采用浸渍提拉法制备完整无缺陷的氧化石墨烯膜。结果表明:将所制备的氧化石墨烯陶瓷复合膜用于乙醇脱水过程,此膜对水分子表现出优先选择透过性。当原料液中水质量分数为10%,操作温度为60℃时,乙醇-水的分离因子可以达到36以上,渗透通量达到2.5kg/(m2·h)。氧化石墨烯陶瓷复合膜可以操作100h以上,并保持一定的分离性能,具有较好的稳定性。

References

[1]  ligh,shil,zenggf,etal.efficientdehydrationoftheorganicsolventsthroughgrapheneoxide(go)/ceramiccompositemembranes[j].rscadvances,2014,4:52012-52015.
[2]  fuhrerms.criticalmassingraphene[j].science,2013,340:1413-1414.
[3]  gasteigerha,markovicnm.justadream:orfuturereality[j].science,2009,324:48-49.
[4]  pauldr.creatingnewtypesofcarbon-basedmembranes[j].science,2012,335:413-414.
[5]  徐秀娟,秦金贵,李振.石墨烯研究进展[j].化学进展,2009,21(12):2559-2567.
[6]  徐超.基于石墨烯材料的制备及其性能的研究[d].南京:南京理工大学,2010.
[7]  yangh,wangy,songy,etal.assemblingofgrapheneoxideinanisolateddissolvingdroplet[j].softmatterial,2012,8:11249-11254.
[8]  jeonjh,cheedaralark,keecd,etal.drytypeartificialmusclesbasedonpendentsulfonatedchitosanandfunctionalizedgrapheneoxideforgreatlyenhancedionicinteractionsandmechanicalstiffness[j].advancedfunctionalmaterials,2013,23(48):6007-6018.
[9]  ail,jiangj.removalofmethylenebluefromaqueoussolutionwithself-assembledcylindricalgraphene-carbonnanotubehybrid[j].chemicalengineeringjournal,2012,192:156-163.
[10]  ganeshbm,islooram,ismailaf.enhancedhydrophilicityandsaltrejectionstudyofgrapheneoxide-polysulfonemixedmatrixmembrane[j].desalination,2013,313:199-207.
[11]  boukhvalovdw,katsnelsonmi,sonyw.originofanomalouswaterpermeationthroughgrapheneoxidemembrane[j].nanoletters,2013,13(8):3930-3935.
[12]  louy,liug,lius,etal.afacilewaytoprepareceramic-supportedgrapheneoxidecompositemembraneviasilane-graftmodification[j].appliedsurfacescience,2014,307:631-637.
[13]  huangk,liug,louy,etal.agrapheneoxidemembranewithhighlyselectivemolecularseparationofaqueousorganicsolution[j].angewandtechemieinternationaledition,2014,53(27):6929-6932.
[14]  黄虎彪.氧化石墨烯超滤分离膜[d].杭州:浙江大学,2014.
[15]  nairrr,wuha,jayarampn,etal.unimpededpermeationofwaterthroughhelium-leak-tightgraphene-basedmembranes[j].science,2012,335:442-444.
[16]  hany,xuz,gaoc.ultrathingraphenenanofiltrationmembraneforwaterpurification[j].advancedfunctionalmaterials,2013,23(29):3693-3700.
[17]  hum,mib.enablinggrapheneoxidenanosheetsaswaterseparationmembranes[j].environmentalscience&technology,2013,47(8):3715-3723.
[18]  wangn,jis,zhangg,etal.self-assemblyofgrapheneoxideandpolyelectrolytecomplexnanohybridmembranesfornanofiltrationandpervaporation[j].chemicalengineeringjournal,2012,213:318-329.
[19]  杨勇辉,孙红娟,彭同江,等.石墨烯薄膜的制备和结构表征[j].物理化学学报,2011,27(3):736-742.
[20]    
[21]  zhuy,jamesdk,tourjm.newroutestographene,grapheneoxideandtheirrelatedapplications[j].advancedmaterials,2012,24(36):4924-4955.
[22]  lid,muellermb,giljes,etal.processableaqueousdispersionsofgraphenenanosheets[j].naturenanotechnology,2008,3(2):101-105.

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