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OALib Journal期刊
ISSN: 2333-9721
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胶原蛋白在乙酸酯类离子液体中的溶解及再生性能
DOI: 10.3969/j.issn.1671-7627.2015.01.004, PP. 20-26
Keywords: 胶原蛋白,乙酸酯类离子液体,溶解,再生
Abstract:
合成了2种乙酸酯类离子液体3-甲基-1-乙氧羰基甲基咪唑氯盐([etmim]cl)、3-甲基-1-乙氧羰基甲基咪唑溴盐([etmim]br),通过核磁共振氢谱(1hnmr)和元素分析确认目标产物化学结构。比较胶原蛋白分别在2种离子液体中的溶解能力大小,并分别探讨了4种不同再生试剂对胶原蛋白再生情况的影响,如去离子水、甲醇、乙醇、丙酮。对以([etmim]cl)离子液体为溶剂、甲醇为再生剂的再生前后胶原蛋白进行傅里叶变换红外光谱(ft-ir)分析。结果表明:2种离子液体都是胶原蛋白的直接溶剂,且([etmim]cl)对胶原蛋白的溶解时间比1-烯丙基-3-甲基咪唑氯盐[amim]cl和1-丁基-3-甲基咪唑氯盐[bmim]cl缩短了15%～20%,在140℃时,[etmim]cl溶解固体质量分数为8%的胶原蛋白仅需15min,同时胶原蛋白再生前后结构并未发生变化。
| [1] | waffenschmidth,wsserseheidp.ionicliquidsinregioselectiveplatinumcatalyzedhydroformylation[j].journalofmolecularcatalysisa:chemical,2000,164(1):61-67.
|
| [2] | przemyslawk.applicationofionicliquidsassolventsforpolymerizationprocesses[j].progressinpolymerscience,2004,29(1):3-12.
|
| [3] | swatloskirp,spearsk,holbreyjd,etal.dissolutionofcellulosewithionicliquids[j].journaloftheamericanchemicalsociety,2002,124(18):4974-4975.
|
| [4] | 郭立颖,史铁钧,李忠,等.新型功能化离子液体[heeim]cl的合成及其对棉纤维的溶解性能[j].高等学校化学学报,2008,29(9):1901-1907.
|
| [5] | 朱海霖,冯新星,陈建勇,等.丝素蛋白在室温离子液体中的溶解与再生性能研究[j].功能材料,2008,39(10):1710-1713.
|
| [6] | biswasa,shogrenrl,stevensondg.ionicliquidsassolventsforbiopolymers:acylationofstarchandzeinprotein[j].carbohydratepolymers,2006,66(4):546-550.
|
| [7] | phillipsd,drummylf,conradydg,etal.dissolutionandregenerationofbombyxmorisilkfibroinusingionicliquids[j].journaloftheamericanchemicalsociety,2004,126(44):14350-14351.
|
| [8] | 陈洪章,刘丽英.使用离子液体溶解动物毛制备再生胶原蛋白纤维的方法:中国,200510077289.8[p].2006-12-27.
|
| [9] | maf,hannama.biodieselproduction:areview[j].bioresourcetechnology,1999,70(1):1-15.
|
| [10] | janaunj,ellisn.perspectivesonbiodieselasasustainablefuel[j].renewableandsustainableenergyreviews,2010,14(4):1312-1320.
|
| [11] | laurentb.atomicforcemicroscopyofcollagenstructureinboneanddentinerevealedbyosteoclasticresorption[j].ultramicroscopy,2005,105(1):79-89.
|
| [12] | bhattacharjeea,bansalm.collagenstructure:themadrastriplehelixandthecurrentscenario[j].iubmblife,2005,57(3):161-172.
|
| [13] | dilulloga,sweeneysm,korkkoj.mappingtheligand-bindingsitesanddisease-associatedmutationsonthemostabundantproteininthehuman,typeicollagen[j].journalofbiologicalchemistry,2002,277(6):4223-4231.
|
| [14] | 蒋挺大.胶原与胶原蛋白[m].北京:化学工业出版社,2006.
|
| [15] | brenneckejf,maginnej.ionicliquids:innovativefluidsforchemicalprocessing[j].aichejournal,2001,47(11):2384-2389.
|
| [16] | gathergoodn,garciamt,scammellspj.biodegradableionicliquids:ⅰ.concept,preliminarytargetsandevaluation[j].greenchemistry,2004,6(3):166-175.
|
| [17] | 顾彦龙,石峰,邓友全.室温离子液体浸取分离牛磺酸与硫酸钠固体混合物[j].化学学报,2004,62(5):532-536.
|
| [18] | mengzj,zhengxj,tangky,etal.dissolutionandregenerationofcollagenfibersusingionicliquid[j].biologicalmacromolecules,2012,51(4):440-448.
|
| [19] | rabotyagovaos,cebep,kaplandl.collagenstructuralhierarchyandsusceptibilitytodegradationbyultravioletradiation[j].materialsscienceandengineeringc,2008,28(8):1420-1429.
|
| [20] | petiboisc,gouspilloug,wehbek,etal.analysisoftypeiandivcollagensbyft-irspectroscopeandimagingforamolecularinvestigationofskeletalmuscleconnectivetissue[j].analyticalandbioanalyticalchemistry,2006,386(7):1961-1966.
|
| [21] | kaminskaa,sionkowskaa.effectofuvradiationontheinfraredspectraofcollagen[j].polymerdegradationandstability,1996,51(1):19-26.
|
| [22] | 张玲.胶原多肽在离子液体中的溶解及溶液流变性的研究[d].济南:山东轻工业学院,2011.
|
| [23] | 刘苏锐,王坤余,琚海燕.猪皮ⅰ型胶原蛋白的提取及其结构表征[j].中国皮革,2007,36(7):43-49.
|
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