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OALib Journal期刊
ISSN: 2333-9721
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3-对甲基苯基-4-氨基-5-(2-喹啉基)-1,2,4-三氮唑及其fe(ⅱ)配合物的合成
DOI: 10.3969/j.issn.1671-7627.2014.03.022, PP. 115-118
Keywords: 三氮唑,fe(ⅱ)配合物,光谱表征
Abstract:
根据分子设计的原理,以2-喹啉甲酰肼为起始原料,经三步反应合成了1个新的三取代-1,2,4-三氮唑配体3-对甲基苯基-4-氨基-5-(2-喹啉基)-1,2,4-三氮唑(l),产率为74.7%,配体l经熔点、红外光谱(ft-ir)、核磁共振氢谱(1hnmr)、电喷雾质谱(esi-ms)和元素分析表征。用配体l与fe(ⅱ)离子反应,制备了配合物[fel2(ncs)2](1),对其进行了红外和元素分析表征。
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