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OALib Journal期刊
ISSN: 2333-9721
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存在反应的电解质溶液相平衡研究
DOI: 10.3969/j.issn.1671-7627.2006.01.023, PP. 107-112
Keywords: 电解质溶液,相平衡,高温高压,活度系数,离子选择性电极
Abstract:
从应用的角度出发,对电解质溶液模型、相平衡计算的现状与发展进行了简要的回顾,并系统地介绍和讨论了作者在这方面的工作.指出对pitzer模型和作者提出的电解质溶液水化平衡模型建立各自相应的普遍化温度关系,结合所提出的固液平衡级计算方法,可以预测工业过程所涉及的高温、高压、高浓度范围内复杂体系的热力学性质,解决此类过程集成模拟优化的瓶颈问题.此外,还介绍了离子选择性电极测定弱电解质体系热力学的方法.
| [1] | luxiaohua,zhanglüzheng,wangyanru.simultaneouspredictionofactivitycoefficientsandenthalpyforaqueouselectrolytesolutionsathightemperatures[j].fluidphaseequilibria,1996.201-208.doi:10.1016/0378-3812(96)83887-8.
|
| [2] | 吉晓燕,张吕正,陆小华.混合电解质水溶液固液平衡计算[j].化工学报,1997(5):532-539.
|
| [3] | 陆小华,王延儒,时钧.含盐溶液汽液平衡的预测(ⅰ)、(ⅱ)[j].化工学报,1989.293-301.
|
| [4] | 陆小华,王延儒,时钧.非水电解质浓溶液的热力学研究:hcl-ch3oh体系的汽液平衡[j].化工学报,1990.695-701.
|
| [5] | 陆小华,张吕正,王延儒.电解质混合溶剂体系汽液平衡的推算[j].高校化学工程学报,1992(6):97-104.
|
| [6] | tangerjc,pitzerks.thermodynamicsofnacl-h2o-anewequationofstateforthenearcriticalregionandcomparisonswithotherequationsforadjoiningregions[j].geochimicaetcosmochimicaacta,1989(5):973-987.doi:10.1016/0016-7037(89)90203-2.
|
| [7] | tangerjc,pitzerks.calculationofthethermodynamicpropertiesofaqueous-electrolytesto1000degreesand5000barfromasemi-continuummodelforionhydration[j].journalofphysicalchemistry,1989,(12):4941-4951.doi:10.1021/j100349a053.
|
| [8] | bischoffjl,rosenbauerrj,pitzerks.thesystemnacl-h2orelationsofvapor-liquidnearthecritical-temperatureofwaterandofvapor-liquid-halitefrom300degreesto500degrees[j].geochimicaetcosmochimicaacta,1986(7):1437-1444.doi:10.1016/0016-7037(86)90317-0.
|
| [9] | pitzerks,simonsonjm.thermodynamicsofmulticomponent,miscible,ionicsystems:theoryandequations[j].journalofphysicalchemistry,1986,(13):3005-3009.doi:10.1021/j100404a042.
|
| [10] | pitzerks,liyigui.thermodynamicsofaqueoussodiumchlorideto823kand1kilobar(100mpa)[j].nationalacademyofsciences(usa),1983,(24):7689-7693.doi:10.1073/pnas.80.24.7689.
|
| [11] | robinsonra,stokesrh.electrolytesolutions[m].london:butterworths,1970.
|
| [12] | butlerjn,royrn.activitycoefficientsinelectrolytesolution[m].bocaraton:crcpress,1991.
|
| [13] | zhanglüzheng,luxiaoha,wangyanru.determinationofactivity-coefficientsusingaflowemfmethod:1.hclinmethanol-watermixturesat25℃,35℃and45℃[j].journalofsolutionchemistry,1993(2):137-150.
|
| [14] | jixiaoyan,luxiaohua,lishaowu.activitycoefficientsofhclinthehcl+nh4cl+h2osystemsat298.15and313.15k[j].journalofchemicalandengineeringdata,2000(1):29-33.doi:10.1021/je990139t.
|
| [15] | jixiaoyan,luxiaohua,lishaowu.determinationoftheactivitycoefficientsofnaclinthesystemnacl-nh4cl-h2o[j].journalofsolutionchemistry,2001(5):463-473.doi:10.1023/a:1010352615827.
|
| [16] | luxiaohua,linweilu.meanactivitycoefficientsforthesystemofnacl-nahco3-h2oat293.15to308.15k[j].journalofthermodynchem,2001(9):1107-1119.doi:10.1006/jcht.2000.0827.
|
| [17] | jixiaoyan,luxiaohua,linweilu.meanactivitycoefficientsforthesystemofnacl-nh4hco3-h2osystemat293.15to308.15k[j].fluidphaseequilibria,2001,(1/2):259-270.
|
| [18] | 张吕正,陆小华,王延儒.电解质溶液相平衡预测系统的建立[j].计算机与应用化学,1995(3):199-203.
|
| [19] | 陆小华,王延儒,时钧.电解质溶液的热力学进展[j].化工进展,1988(3):13-17.
|
| [20] | pizterks.ioninteractionapproach:theoryanddatacorrelation[a].boston:crcpress,1991.
|
| [21] | luxiaohua,wangyanru,shijun.predictionofvleforelectrolytesolutionsbytheextendedpitzer(1980)model:physicalinterpretationofthemodelparameter[j].fluidphaseequilibria,1988(1):137-152.
|
| [22] | harveyah,sengerjmhl.onthenacl-h2ocoexistencecurvenearthecritical-temperatureofh2o[j].chemicalphysicsletters,1989(4):415-417.doi:10.1016/0009-2614(89)87119-2.
|
| [23] | luxiaohua,lixian,dinghao.anewthermodynamicmodelforaqueousalkali-earthmetalsolutionbasedonthesynergisticactionofassociationandhydrationundersupercriticalconditions[a].singapore:woroldscientifficpublishingco.pte.ltd,2004.
|
| [24] | pitzerks,liyigui.criticalphenomenaandthermodynamicsofdiluteaqueoussodiumchlorideto823k[j].proceedingsofthenationalacademyofsciencesoftheunitedstatesofamerica,1984(4):1268-1271.doi:10.1073/pnas.81.4.1268.
|
| [25] | 丁皓,朱宇,陆小华.高温及超临界条件下mgcl2与cacl2水溶液中离子水化与缔合的量子化学计算[j].化学学报,2004,(14):1287-1292.doi:10.3321/j.issn:0567-7351.2004.14.005.
|
| [26] | zhuyu,luxiaohua,dinghao.hydrationandassociationofalkalineearthmetalchlorideaqueoussolutionundersupercriticalcondition[j].molecularsimulation,2003.767-773.
|
| [27] | glueckaufe.theinfluenceofionichydrationonactivitycoefficientsinconcentratedelectrolytesolutions[j].transactionsofthefaradaysociety,1955(9):1235-1244.doi:10.1039/tf9555101235.
|
| [28] | 李以圭.金属溶剂萃取热力学[m].北京:清华大学出版社,1988.
|
| [29] | luxiaohua,maurerg.modelfordescribingactivity-coefficientsinmixedelectrolyteaqueous-solutions[j].aichejournal,1993(9):1527-1538.doi:10.1002/aic.690390912.
|
| [30] | luxiaohua,zhanglüzheng,wangyanru.predictionofactivitycoefficientsofelectrolytesinaqueoussolutionsathightemperatures[j].industrialandengineeringchemistryresearch,1996(5):1777-1784.doi:10.1021/ie950474k.
|
| [31] | abramsds,prausnitzjm.statisticalthermodynamicsofliquidmixtures-newexpressionforexcessgibbsenergyofpartlyorcompletelymisciblesystems[j].aichejournal,1975(1):116-128.doi:10.1002/aic.690210115.
|
| [32] | jixiaoyan,chendongliang,luxiaohua.determinationofdissolutionkineticsofk2so4crystalwithionselectiveelectrode[j].chemicalengineeringscience,2001,(24):7017-7024.doi:10.1016/s0009-2509(01)00333-5.
|
| [33] | liuchang,fengxin,luxiaohua.thestudyofdissolutionkineticsofk2so4crystalinaqueousethanolsolutionswithastatisticalratetheory[j].chinesejournalofchemicalengineering,2004(1):128-130.
|
| [34] | jixiaoyan,luxiaohua,zhanglüzheng.afurtherstudyofsolid-liquidequilibriumforthenacl-nh4cl-h2osystem[j].chemicalengineeringscience,2000,(21):4993-5001.doi:10.1016/s0009-2509(00)00113-5.
|
| [35] | zhanglüzheng,guiqiliang,luxiaoha.measurementofsolid-liquidequilibriabyaflow-cloud-pointmethod[j].journalofchemicalandengineeringdata,1998(1):32-37.doi:10.1021/je970176p.
|
| [36] | 吉晓燕,冯新,陆小华.固液相平衡级的通用算法[j].化工学报,1999(6):743-750.doi:10.3321/j.issn:0438-1157.1999.06.003.
|
| [37] | 冯新,刘畅,陆小华.芒硝法生产硫酸钾工艺的模拟与分析[j].高校化学工程学报,2000(6):583-587.doi:10.3321/j.issn:1003-9015.2000.06.013.
|
| [38] | 丁皓,吉晓燕,陆小华.高温高压下饱和湿空气焓与湿度的预测[j].化工学报,2002,(53):879-882.doi:10.3321/j.issn:0438-1157.2002.08.021.
|
| [39] | dinghao,luxiaohua,jixiaoyan.studyoncalculationsofhumidificationtowerwithhumidairturbinecycleathightemperatureandpressure[j].chinesejournalofchemicalengineering,2004(4):532-536.
|
| [40] | jixiaoyan,sugataptan,hertantoadidharma.saft1-rpmapproximationextendedtophaseequilibriaanddensitiesofco2-h2oandco2-h2o-naclsystems[j].industrialandengineeringchemistryresearch,2005,(22):8419-8427.doi:10.1021/ie050725h.
|
| [41] | jixiaoyan,sugataptan,hertantoadidharma.statisticalassociatingfluidtheorycoupledwithrestrictedprimitivemodeltorepresentaqueousstrongelectrolytes:multiple-saltsolutions[j].industrialandengineeringchemistryresearch,2005,(19):7584-7590.doi:10.1021/ie050488i.
|
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