全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

链状与环状多糖调控caco3的仿生合成

, PP. 50-54

Keywords: 可溶性淀粉,β环糊精,晶体形貌,碳酸钙

Full-Text   Cite this paper   Add to My Lib

Abstract:

以可溶性淀粉、β环糊精及十二烷基硫酸钠(sds)为模板,在cacl2、na2co3体系中调控合成caco3晶体.研究了不同形貌caco3晶体成型原因.分别用红外光谱(ftir)、x射线衍射仪(xrd)、扫描电镜(sem)等技术对晶体的形貌和结构进行了观察和表征.结果表明:可溶性淀粉溶液中5d后得到以球霰石为主的球形caco3;环糊精溶液中5d后得到以球霰石为主的caco3层状聚集体,随着结晶时间的延长,产物中球霰石逐渐向方解石转化,sds的加入加快了球霰石向方解石的转化速度.

References

[1]  张春艳,谢安建,沈玉华,等.聚乙二醇对碳酸钙晶体生长影响的研究[j].安徽大学学报,2008,32(1):74-77.
[2]  zhangchunyan,xieanjian,shenyuhua,etal.morphologiesofcalciumcarbonatecrystallitesgrownfromaqueoussolutionscontainingpolyethyleneglycol[j].journalofanhuiuniversity,2008,32(1):74-77.
[3]  张秀英,廖照江,杨林,等.β环糊精与碳酸钙结晶的相互作用[j].化学学报,2003,61(1):69-73.
[4]  zhangxiuying,liaozhaojiang,yanglin,etal.interactionbetweenβcydodextrinandcrystallizationofcalciumcarbonate[j].actachimicasinica,2003,61(1):69-73.
[5]  michaelfb,williamjf,christopherrawlins,etal.hollowcalciumcarbonatemicrosphereformationinthepresenceofbiopolymersandadditives[j].crystgrowthdes,2009,9(1):534-545.
[6]  congrongjuan,robertp.theinfluenceofpeo/poly(vinylphenolcostyrenesulfate)aqueouscomplexstructureonflocculation[j].journalofcolloidandinterfacescience,2003,261:65-73.
[7]  付丽红,程惊秋,来国莉.明胶基质作用下碳酸钙的仿生合成[j].化学学报,2005,63(17):1626-1632.
[8]  fulihong,chengjingqiu,laiguoli.biomimeticsynthesisofcalciumcarbonatewiththeexistenceofthegelatinmatrix[j].actachimicasinica,2005,63(17):1626-1632.
[9]  matahwah,ramiahv,sandersonrd.calciumcarbonatecrystallizationinthepresenceofmodifiedpolysaccharidesandlinearpolymericadditives[j].journalofcrystalgrowth,2008,310:4561-4569.
[10]  kontrecj,kraljd,brecevicl,etal.influenceofsomepolysaccharidesontheproductionofcalciumcarbonatefillerparticles[j].journalofcrystalgrowth,2008,310:4554-4560.
[11]  yanglin,zhangxiuying,liaozhaojiang,etal.interfacialmolecularrecognitionbetweenpolysaccharidesandcalciumcarbonateduringcrystallization[j].journalofinorganicbiochemistry,2003,97:377-383.
[12]  raoms.kineticsandmechanismoftransformationofvateritetocalcite[j].bulletinofchemistrysocietyjapan,1973,46:1414-1417.
[13]  欧阳建明.基质调控碳酸钙生物矿化过程及其体外模拟的研究进展[j].功能材料,2005,36(2):173-175.
[14]  ouyangjianming.researchprogressonbiomineralizationprocessofcalciumcarbonatemediatedbyorganicmatrixanditssimulation[j].functionalmaterial,2005,36(2):173-175.
[15]  bukerbc,riekepc,tarasevichbj,etal.ceramicthinfilmformationonfunctionalizedinterfacethroughbiomimeticprocessing[j].science,1994,264(5155):48-55.
[16]  malkajp,dalase,kanellopouloudg,etal.calciteparticlesformationinthepresenceofsolublepolyvinylalcoholmatrix[j].powdertechnology,2007,177:17-76.
[17]  chenshaofeng,yushuhong,jiangjun,etal.polymorphdiscriminationofcaco3mineralinanethanol/watersolution:formationofcomplexvateritesuperstructuresandaragoniterods[j].chemistryofmaterials,2006,18(1):115-122.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133