OALib Journal期刊
ISSN: 2333-9721
费用:99美元
|
|
|
上转换材料复合介孔tio2晶须的可见光催化性能
DOI: doi:10.3969/j.issn.1671-7627.2012.02.009, PP. 39-43
Keywords: 介孔tio2晶须,y3al5o12:er,上转换材料,可见光催化
Abstract:
用溶胶凝胶法制备上转换发光材料y3al5o12:er。反射光谱、发射光谱表明:y3al5o12:er在480nm光的激发下,产生2个<387nm的紫外光发射峰。将上转换材料介孔tio2晶须复合成可见光催化剂,采用x线衍射仪(xrd)、场发射扫描电子显微镜(fesem)以及低温n2吸附脱附(bet)等对催化剂进行表征,通过光催化降解亚甲基蓝(mb),对催化剂的活性进行测试。结果表明:复合上转换材料的介孔tio2晶须在可见光下能够有效降解mb,10%y3al5o12:er的介孔tio2晶须的mb降解率为73%。
References
[1] | fujishimaa,hondak.electrochemicalphotolysisofwateratasemiconductorelectrode[j].nature,1972,238:37-38.
|
[2] | fengg,lius,xiuz,etal.visiblelightphotocatalyticactivitiesoftio2nanocrystalsdopedwithupconversionluminescenceagent[j].journalofphysicalchemistry:c,2008,112(35):13692-13699.
|
[3] | hem,luxh,fengx,etal.asimpleapproachtomesoporousfibroustitaniafrompotassiumdititanate[j].chemicalcommunications,2004,19:2202-2203.
|
[4] | 杨祝红,暴宁钟,郑仲,等.用溶剂热处理法制备tio2纤维及其光催化降解甲基橙的活性[j].催化学报,2002,23(6):539-542.
|
[5] | liw,liuc,zhouyx,etal.enhancedphotocatalyticactivityinanatase/tio2(b)coreshellnanofiber[j].journalofphysicalchemistry:c,2008,112(51):20539-20545.
|
[6] | yangdj,liuhw,zhengzf,etal.anefficientphotocatalyststructure:tio2(b)nanofiberswithashellofanatasenanocrystals[j].journaloftheamericanchemicalsociety,2009,131(49):17885-17893.
|
[7] | baiy,liw,liuc,etal.stabilityofptnanoparticlesandenhancedphotocatalyticperformanceinmesoporouspt(anatase/tio2(b))nanoarchitecture[j].journalofmaterialschemistry,2009,19(38):7055-7061.
|
[8] | xuhl,krolls.upconversiondynamicsiner3+:dopedyag[j].journalofluminescence,2005,111(3):191-198.
|
[9] | liutx,lixz,lifb.enhancedphotocatalyticactivityofce3+tio2hydrosolsinaqueousandgaseousphases[j].chemicalengineeringjournal,2010,157(2/3):475-482.
|
[10] | chenx,maoss.titaniumdioxidenanomaterials:synthesis,properties,modifications,andapplications[j].chemicalreviews,2007,107(7):2891-2959.
|
[11] | zhaow,suny,castellanofn.visiblelightinducedwaterdetoxificationcatalyzedbyptiidyesensitizedtitania[j].journaloftheamericanchemicalsociety,2008,130(38):12566-12567.
|
[12] | suw,zhangy,liz,etal.multivalencyiodinedopedtio2:preparation,characterization,theoreticalstudies,andvisiblelightphotocatalysis[j].langmuir,2008,24(7):3422-3428.
|
[13] | shchukind,ustinoviche,sviridovd,etal.effectofsilverdepositsonthephotocatalyticactivityoftitaniumdioxidefortheremovalof2chlorophenolinwater[j].photochemical&photobiologicalsciences,2004,3(1):142-144.
|
[14] | caoj,sunjz,lihy,etal.afacileroomtemperaturechemicalreductionmethodtotio2@cdscore/sheathheterostructurenanowires[j].journalofmaterialschemistry,2004,14(7):1203-1206.
|
[15] | wangj,lirh,zhangzh,etal.efficientphotocatalyticdegradationoforganicdyesovertitaniumdioxidecoatingupconversionluminescenceagentundervisibleandsunlightirradiation[j].appliedcatalysisa:general,2008,334(1/2):227-233.
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|