OALib Journal期刊
ISSN: 2333-9721
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超疏水透明涂层的模板沉积法制备及表征
DOI: 10.3969/j.issn.1671-7627.2014.01.003, PP. 13-18
Keywords: 超疏水,涂层,十六烷基三甲氧基硅烷,化学气相沉积
Abstract:
在常温常压下,以纳米炭粉为模板剂,利用正硅酸四乙酯(teos)在玻璃片表面进行化学气相沉积,经十六烷基三甲氧基硅烷(ctms)改性处理制得超疏水透明涂层。采用静态接触角(ca)、傅里叶交换红外光谱仪(ft-ir)、紫外光谱仪(uv)、热分析仪(tga)、交叉极化硅核磁共振谱仪(29sicpmasnmr)、x线光电子能谱仪(xps)和透射电子显微镜(tem)进行分析和表征。结果表明:teos的沉积时间对疏水涂层的接触角、滑动角及透光性均有一定的影响,最佳沉积时间为6h,接触角高达166.1°,滑动角为2.1°,透光率达91%。此透明超疏水涂层具有极好的耐潮性能,即使暴露在室温环境中30d,仍能保持良好的超疏水性能。
References
[1] | 高雪峰,江雷.天然超疏水生物表面研究的新进展[j].物理,2006,35(7):559-564.
|
[2] | ondat,shibuichis,satohn,etal.super-water-repellentfractalsurfaces[j].langmuir,1996,12:2125-2127.
|
[3] | mohammadska,yazdanshenasme.superhydrophobicantibacterialcottontextiles[j].jcolloidinterfsci,2010,351(1):293-298.
|
[4] | blosseyr.self-cleaningsurfaces-virtualrealities[j].natmater,2003,2(5):301-306.
|
[5] | mam,hillrm.superhydrophobicsurfaces[j].curropincolloidinterfacesci,2006,11(4):193-202.
|
[6] | 赵宁,卢晓英,张晓艳,等.超疏水表面的研究进展[j].化学进展,2007,19(6):860-871.
|
[7] | linj,chenh,feit,etal.highlytransparentandthermallystablesuperhydrophobiccoatingsfromthedepositionofsilicaaerogels[j].applsurfsci,2013,273:785-795.
|
[8] | lixm,reinhoudtd,crego-calamam.whatdoweneedforasuperhydrophobicsurface:areviewontherecentprogressinthepreparationofsuperhydrophobicsurfaces[j].chemsocrev,2007,36(8):1350-1368.
|
[9] | khorasanimt,mirzadehh,kermaniz.wettabilityofporouspolydimethylsiloxanesurface:morphologystudy[j].applsurfsci2005,242:339-345.
|
[10] | tadanagak,katatan,minamit.formationprocessofsuper-water-repellental2o3coatingfilmswithhightransparencybythesol-gelmethod[j].jamceramsoc,1997,80(12):3213-3216.
|
[11] | liuh,fengl,zhaij,etal.reversiblewettabilityofachemicalvapordepositionpreparedznofilmbetweensuperhydrophobicityandsuperhydrophilicity[j].langmuir,2004,20:5659-5661.
|
[12] | lim,zhaij,liuh,etal.electrochemicaldepositionofconductivesuperhydrophobiczincoxidethinfilms[j].jphychemb,2003,107(37):9954-9957.
|
[13] | linj,chenh,jiy,etal.functionallymodifiedmonodispersecore-shellsilicananoparticles:silanecouplingagentascappingandsizetuningagent[j].colloidssurfa,2012,411:111-121.
|
[14] | bauerf,gläselhj,deckeru,etal.trialkoxysilanegraftingontonanoparticlesforthepreparationofclearcoatpolyacrylatesystemswithexcellentscratchperformance[j].progorgcoat,2003,47(2):147-153.
|
[15] | linj,chenh,feit,etal.highlytransparentsuperhydrophobicorganic-inorganicnanocoatingfromtheaggregationofsilicananoparticles[j].colloidssurfa,2013,421:51-62.
|
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