|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
高性能聚酰亚胺/纳米石墨烯复合薄膜的制备
DOI: 10.3969/j.issn.1671-7627.2015.03.004, PP. 19-24
Keywords: 聚酰亚胺,纳米石墨烯,原位聚合,聚酰亚胺/纳米石墨烯复合薄膜
Abstract:
本文通过原位聚合的方法,在聚酰胺酸溶液中加入纳米石墨烯(gr)和硅烷偶联剂(kh550),制备不同gr质量分数的聚酰亚胺/纳米石墨烯(pi/gr)复合薄膜。采用傅里叶衰减全反射红外光谱仪(art-ft-ir)、静态热机械分析仪(tma)、扫描电子显微镜(sem)以及同步热分析仪(sta)表征pi/gr复合薄膜的性能和结构。结果表明:在偶联剂的作用下,gr可以较好地分散在聚酰亚胺基体中,同时偶联剂和gr的引入提高了复合薄膜的热稳定性;当gr质量分数达到15%时,pi/gr复合薄膜的弹性模量增加66.7%,达到3gpa左右;随着电流密度的提高,复合薄膜的比电容提高了48.4%。
| [1] | stankovichs,pinerrd,chenx,etal.stableaqueousdispersions
|
| [2] | longunj,irohjo.nano-graphene/polyimidecompositeswithextremelyhighrubberyplateaumodulus[j].carbon,2012,50(5):1823-1832.
|
| [3] | 王宏宇,侴菊,赵晖,等.可溶性聚酰亚胺的电化学行为[j].高等学校化学学报,1998,19(1):48-50.
|
| [4] | zhangyh,lusg,liyq,etal.novelsilicatube/polyimidecompositefilmswithvariablelowdielectricconstant[j].advancedmaterials,2005,17(8):1056-1059.
|
| [5] | 张力,吴俊涛,江雷.石墨烯及其聚合物纳米复合材料[j].化学进展,2014,26(4):560-571.
|
| [6] | patilaj,vickeryjl,scotttb,etal.aqueousstabilizationandself-assemblyofgraphenesheetsintolayeredbio-nanocompositesusingdna[j].advancedmaterials,2009,21(31):3159-3164.
|
| [7] | zhangdd,zuasz,hanabh.inorganic-organichybridporousmaterialsbasedongraphiteoxidesheets[j].carbon,2009,47(13):2993-3000.
|
| [8] | liangyy,wudq,fengxl,etal.dispersionofgraphenesheetsinorganicsolventsupportedbyionicinteractions[j].advancedmaterials,2009,21(17):1679-1683.
|
| [9] | zhangxq,fengyy,tangsd,etal.porphyincounteranioninimidazolium-modifiedgraphene-oxide[j].carbon,2010,48(1):211-216.
|
| [10] | 周宝珍,闫路瑶,曲顺志,等.原位聚合法制备聚苯胺/石墨烯导电复合材料的工艺[j].青岛科技大学学报:自然科学版,2014,35(3):287-293.
|
| [11] | lim,cushingsk,zhouxj,etal.fingerprintingphotoluminescenceoffunctionalgroupsingrapheneoxide[j].journalofmaterialschemistry,2012,22(45):23374-23379.
|
| [12] | ofgraphiticnanoplateletsviathereductionofexfoliatedgraphiteoxideinthepresenceofpoly(sodium4-styrenesulfonate)[j].journalofmaterialschemistry,2006,16(2):155-158.
|
| [13] | 何曼君.高分子物理[m].上海:复旦大学出版社,2007:339.
|
| [14] | yoonessim,shiy,scheimanda,etal.graphenepolyimidenanocomposites:thermal,mechanical,andhigh-temperatureshapememoryeffects[j].americanchemicalsocietynano,2012,6(9):7644-7655.
|
| [15] | changcc,chenwc.synthesisandopticalpropertiesofpolyimide-silicahybridthinfilms[j].chemistryofmaterials,2002,14(10):4242-4248.
|
| [16] | zhanglb,wangjq,wanghg,etal.preparation,mechanicalandthermalpropertiesoffunctionalizedgraphene/polyimidenanocomposites[j].composites:parta,2012,43(9):1537-1545.
|
| [17] | caid,songm.recentadvanceinfunctionalizedgraphene/polymernanocomposites[j].journalofmaterialschemistry,2010,20(37):7906-7915.
|
| [18] | kimh,abdalaaa,macoskocw.graphene/polymernanocomposites[j].macromolecules,2010,43(16):6515-6530.
|
| [19] | hoc,leej.syntheticpreparationsandphysicalandelectricalpropertiesofmainchaintypethermotropicliquidcrystallinepolyimide/sio2nanocomposites[j].journalofappliedpolymerscience,2006,100:1688-1704.
|
| [20] | 朱英,邢巍,赵晖,等.可溶性聚酰亚胺电化学反应机理的研究[j].电化学,1998,4(2):147-151.
|
| [21] | yanj,liujp,fanzj,etal.high-performancesupercapacitorelectrodesbasedonhighlycorrugatedgraphenesheets[j].carbon,2012,50(6):2179-2188.
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
