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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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两种不对称四硫富瓦烯衍生物的合成、结构及电化学行为研究
, PP. 61-66
Keywords: 四硫富瓦烯(ttf),不对称偶联,晶体结构,循环伏安
Abstract:
以1,3-甲基二硫基-二硫醇-2-硫酮(化合物1)和1,3-环戊烯二硫基-二硫醇-2-硫酮(化合物5)为原料,在p(oet)3存在下,分别与1,3-二(氰乙硫基)-二硫醇-2-氧酮(化合物3)发生不对称偶联,得到了两个新型的不对称四硫富瓦烯衍生物(化合物6a和6b).对二者进行了熔点、ir、1hnmr、13cnmr、ms、ea等表征,解析了其晶体结构,并对它们的电化学行为做了初步的研究.
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