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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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马来酸酐接枝聚乳酸与淀粉共混物的研究
DOI: 10.3969/j.issn.1000-2006.2013.06.022, PP. 111-115
Keywords: 聚乳酸,接枝,淀粉,相容性
Abstract:
以2,5-二甲基-2,5-二叔丁基-过氧基-己烷为引发剂引发马来酸酐接枝聚乳酸,研究了反应时间、温度、引发剂用量、马来酸酐用量等不同接枝条件对接枝率的影响。结果表明,在固定聚乳酸与马来酸酐用量条件下的最佳接枝条件为:反应温度95℃,反应时间3h,引发剂用量1%。接枝聚乳酸与淀粉共混后,通过差示热量扫描(dsc)和吸水率测试发现,与未接枝聚乳酸/淀粉共混物相比,其玻璃化转变温度(tg)及吸水率降低,证明接枝聚乳酸与淀粉相容性提高。同时通过扫描电镜(sem)观察共混物表面形态,发现两者相容性有明显改善。
| [1] | juncl.reactiveblendingofbiodegradablepolymers:plaandstarch[j].journalofpolymersandtheenvironment,2000(8):33-37.
|
| [2] | 潘丽军,桂蕾,李延红,等.改性聚乳酸/淀粉复合材料的制备与性能表征[j].塑料科技,2009(2):28-31.panlj,guil,liyh,etal.preparationandcharacterizationofthemodifiedacrylic-starch/polylacticacidblends[j].plasticsscienceandtechnology,2009(2):28-31.
|
| [3] | 方显力,项尚林,缪健,等.聚乳酸固相接枝马来酸酐及与淀粉共混研究[j].包装工程,2007,11:31-37.fangxl,xiangsl,miaoj,etal.studyonsolid-phasegraftingmahontopoly(lacticacid)anditsblendingwithstarch[j].packagingengineering,2007,11:31-37.
|
| [4] | wucs.improvingpolylactide/starchbiocompositesbygraftingpolylactidewithacrylicacid-characterizationandbiodegradabilityassessment[j].macromolecularbioscience,2005(5):352-361.
|
| [5] | 邓芹英,刘岚,邓慧敏.波谱分析教程[m].北京:科学出版社,2003.
|
| [6] | 詹世平,陈淑花,张欣华,等.非晶态粉体玻璃化转变温度的测量方法与装置[j].化学工程,2007(5):52-55.zhansp,chensh,zhangxh,etal.anewmethodandequipmentofdeterminingglasstransitiontemperatureofamorphousmacromoleculepowders[j].chemicalengineering,2007(5):52-55.
|
| [7] | roccoam,pereirarp,felisbertimi.miscibility,crystallinityandmorphologicalbehaviorofbinaryblendsofpoly(ethyleneoxide)andpoly(methylvinylether-maleicacid)[j].polymer,2001,42(12):5199-5205.
|
| [8] | zhangjf,sunxs.mechanicalpropertiesofpla/starchcompositescompatibilizedbymaleicanhydride[j].biomacromolecules,2004,5:1446-1451.
|
| [9] | 张国栋,杨纪元,冯新德,等.聚乳酸的研究进展[j].化学进展,2000,12:89-102.zhanggd,yangjy,fengxd,etal.progressinstudyofpolylactides[j].progressinchemistry,2000,12:89-102.
|
| [10] | 马向东,刘大壮,孙培勤.氯化聚丙烯接枝马来酸酐接枝率的测定[j].粘结,2002,23:12-14.maxd,liudz,sunpq.determinationofgraftingyieldofmaleicanhydridegraftedchlorinatedpolypropylene[j].adhesioninchina,2002,23:12-14.
|
| [11] | manir,bhattacharym,tangj.functionalizationofpolyesterswithmaleicanhydridebyreactiveextrusion[j].polymerchemistry,1999,37(11):1693-1702.
|
| [12] | 李申,周晔,任天斌,等.聚乳酸/淀粉复合材料的制备及性能研究[j].塑料,2006(4):7-11.lis,zhouy,rentb,etal.preparationandpropertiesofpla/starchblends[j].plastics,2006(4):7-11.
|
| [13] | jacobsens,fritzhg.fillingofpoly(lacticacid)withnativestarch[j].polymerengineeringandscience,1996,36(22):2799-2804.
|
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