|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
两种热模拟体系下热解产物的相关性研究
Keywords: 热模拟实验,开放体系,封闭体系,资源量计算
Abstract:
？对南宁褐煤在封闭体系和开放体系下开展了热模拟实验，并对其在2种热模拟体系下的氢气、气态烃和液态烃产率的演化特征以及相互关系进行了研究。结果表明，在煤岩热解生烃过程中，封闭体系下液态烃出现的温度区间为250～600℃，开放体系下液态烃出现的温度区间为250～550℃。通过氢气、气态烃和液态烃产率的对比分析，发现液态烃是影响有机质发生缩聚反应的主要因素。2种热模拟体系下，氢气和气态烃产率分别与液态烃产率呈负相关关系，而氢气和气态烃产率呈正相关关系，且三者的总演化趋势相同，说明有机质演化是一个稳定的过程，和自身化学键的键能密切相关。在高温阶段，2种热模拟体系下的气态烃产率基本相同，因此在计算生气量时，产气率数据的选择要考虑演化程度的影响。
| [1] | seewaldjs,beniteznetsonbc,whelanjk.laboratoryandtheoreticalconstraintsonthegenerationandcompositionofnaturalgas[j].geochimicaletcosmochimicaacta,1998,62(9):1599-1617.
|
| [2] | liuquanyou.organicgeochemistryofn-alkanesfromtarimcoalwithdifferentmaterialsinpyrolysisunderclosedsystem[j].naturalgasgeoscience,2006,17(3):313-318.[刘全有.塔里木盆地煤岩在不同介质条件下热模拟实验中烷烃系列有机地球化学特征[j].天然气地球科学,2006,17(3):313-318.]
|
| [3] | beharf,vandenbrouckem.experimentalsimulationofgasgenerationfromcoalsandamarinekerogen[j].chemicalgeology,1995,126:247-260.
|
| [4] | huguoyi,lizhisheng,luoxia,etal.thecomparisionofgasgenerationpotentialandmodelbetweentwodifferentthermalsimulationsystems[j].actasedimentologicasinica,2004,22(4):718-723.[胡国艺,李志生,罗霞，等.两种热模拟体系下有机质生气特征对比[j].沉积学报,2004,22(4):718-723.]
|
| [5] | lushuangfang,wangmin,wangyuewen,etal.comparisonofsimulationresultsfromtheclasedandopenexperimentalsystemsanditssignificance[j].actasedimentologicasinica,2006,24(2):282-288.[卢双舫,王民,王跃文，等.密闭体系与开放体系模拟实验结果的比较研究及其意义[j].沉积学报,2006,24(2):282-288.]
|
| [6] | qinyong.laggingandreactionkineticmechanismofhydrocarbonregenerationfromorganicmattersincoals[j].earthscience:journalofchinauniversityofgeosciences,2000,25(3):278-282.[秦勇.煤中有机质二次生烃迟滞性及其反应动力学机制[j].中国地质大学学报:地球科学,2000,25(3):278-282.]
|
| [7] | gaogang.theevolutioncharacteristicsofgaseousproductsofhumiccoalanditsgeologicalsignificance[j].actasedimentologicasinica,1998,16(2)30-33.[高岗.腐殖煤气态产物演化特征的模拟实验研究[j].沉积学报,1998,16(2):30-33.]
|
| [8] | duanyi.thermalsmulationofgasgenerationofcoalrocksanditssignificancetracingcoalbedmethaneformation[j].naturgasindustry,2005,25(1):66-69.[段毅.煤岩生气热模拟及其对煤层气形成的示踪意义[j].天然气工业,2005,25(1):66-69.]
|
| [9] | beharf,vandenbrouckem.thermalcrackingofkerogeninopenandclosedsystems:determinationofkineticparametersandstoichiometriccoef-ficientsforoilandgasgeneration[j].organicgeochemistry,1997,26(5/6):321-339.
|
| [10] | tissotbp.petroleumformationandoccurrence[m].pertoleumindustrypress,1989:108-109.[蒂索.石油形成与分布[m].北京:石油工业出版社,1989:108-109.]
|
| [11] | dujg,jinzj.stablecarbonisotopecompositionsofgaseoushydrocarbonsproducedfromhighpressureandhightemperaturepyrolysisoflignite[j].organicgeochemistry,2003,34(1):97-104.
|
| [12] | jüntgenh.reviewofthekineticsofpyrolysisandhydropyrolysisinrelationtothechemicalconstitutionofcoal[j].fuel,1984,63:731-737.
|
| [13] | xuwc,tomitaa.effectoftemperatureontheflashpyrolysisofvariouscoals[j].fuel,1987,66:632-636.
|
| [14] | wangyuhua,houqijun,sundejun,etal.generationandevaluationofoilandgasresourcesmesozoicandcenozoicinthenorthernmarginoftheqaidambasin[m].beijing:sciencepress,2004:46-47.[王玉华,侯启军,孙德君,等.柴达木盆地北缘地区中新生代地层油气生成与资源评价[m].北京:科学出版社,2004:46-47.]
|
| [15] | oremwh,neazilsg,lertchhe,etal.experimentalearlysta-[jp]gecoalificationofapeatandapeatifiedwoodsamplefromindonesia[j].organicgeochemistry,1996，124(2):111-125.
|
| [16] | liuwenhui,zhangdianwei,wangxiaofeng,etal.influenceofhydrogenationandtsr(thermochemicalsulfatereduction)tonaturalgasisotopiccomposition[j].actapetrologicasinica,2006,22(8):2237-2242.[刘文汇,张殿伟,王晓峰,等.加氢和tsr反应对天然气同位素组成的影响[j].岩石学报,2006,22(8):2237-2242.]
|
| [17] | zhanggongcheng,lizengxue,heyuping,etal.coalgeochemistryofqiongdonggnanbasin[j].naturalgasgeoscience,2010,21(5):693-699.[张功成，李增学，何玉平，等.琼东南盆地煤地球化学特征[j].天然气地球科学,2010,21(5):693-699.]
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
