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OALib Journal期刊
ISSN: 2333-9721
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co2加氢合成甲醇cu/zro2催化剂的失活因素
, PP. 1341-1345
Keywords: cu/zro2催化剂,甲醇合成,失活因素
Abstract:
？采用低温氮气吸脱附、x射线衍射(xrd)、电镜(tem)以及热重差热(tg-dsc)等手段,对不同反应时间下cu/zro2催化剂的物理结构、微观形貌以及积炭情况进行了表征,分析了催化剂的失活原因。结果表明,造成催化剂失活的主要因素是活性组分烧结;其次,表面积炭覆盖其活性中心也造成催化剂活性在一定程度上的降低;而催化剂比表面积对其活性的影响较小。
| [1] | rahimpourmr.atwo-stagecatalystbedconceptforconversionofcarbondioxideintomethanol[j].fuelprocesstechnol,2008,89(5):556-566.
|
| [2] | arenaf,barberak,italianog,bonurag,spadarol,frusterif.synthesis,characterizationandactivitypatternofcu-zno/zro2catalystsinthehydrogenationofcarbondioxidetomethanol[j].jcatal,2007,249(2):185-194.
|
| [3] | raudaskoskir,niemelabmv,keiskirl.theeffectofageingtimeonco-precipitatedcu/zno/zro2catalystsusedinmethanolsynthesisfromco2andh2[j].topcatal,2007,45(1/4):57-60.
|
| [4] | liux-m,lugq,yanz-f.nanocrystallinezirconiaascatalystsupportinmethanolsynthesis[j].applcatala,2005,279(1/2):241-245.
|
| [5] | kurtzm,wilmerh,genget,hinrichseno,muhlerm.deactivationofsupportedcoppercatalystsformethanolsynthesis[j].catallett,2003,86(1/3):77-81.
|
| [6] | twiggmv,spencerms.deactivationofsupportedcoppermetalcatalystsforhydrogenationreactions[j].applcatala,2001,212(1/2):161-174.
|
| [7] | sunjt,metcalfeis,sahilbzadam.deactivationofcu/zno/al2o3methanolsynthesiscatalystbysintering[j].indengchemres,1999,38(10):3868-3872.
|
| [8] | luany,xuh,yuc,liw,hous.effectsandcontrolofsteaminthesystemsofmethanolanddmesynthesisfromsyngasovercu-basedcatalysts[j].catallett,2008,125(3/4):271-276.
|
| [9] | 殷永泉,肖天存,苏继新,王海涛,鹿玉理.铜基甲醇合成催化剂的失活研究[j].分子催化,2000,14(5):373-378.(yinyong-quan,xiaotian-cun,suji-xin,wanghai-tao,luyu-li.studiesondeactivationofcu-basedcatalystformethanolsynthesis[j].journalofmolecularcatalysis(china),2000,14(5):373-378.)
|
| [10] | 殷永泉,肖天存,苏继新,王海涛,鹿玉理,李晋鲁,刘崇微,朱起明,李树本.工业甲醇合成催化剂的失活与再生研究[j].天然气化工,2000,25(2):34-36.(yinyong-quan,xiaotian-cun,sunji-xin,wanghai-tao,luyu-li,lijin-lu,liuchong-ming,lishu-ben.studiesondeactivationandregenerationofindustrialmethanolsynthesiscatalyst[j].naturalgaschemicalindustry,2000,25(2):34-36.)
|
| [11] | zhaix,shamotoj,xieh,tany,hany,tsubakin.studyonthedeactivationphenomenaofcu-basedcatalystformethanolsynthesisinslurryphase[j].fuel,2008,87(4/5):430-434.
|
| [12] | may,geq,liw,xuh.studyonthesulfurtoleranceofcatalystsforsyngastomethanol[j].catalcommun,2008,10(1):6-10.
|
| [13] | wuj,saitom,takeuchim,watanabet.thestabilityofcu/zno-basedcatalystsinmethanolsynthesisfromaco2-richfeedandfromaco-richfeed[j].applcatala,2001,218(1/2):235-240.
|
| [14] | 何刚,高勤卫.mk101催化剂提前失活的研究[j].石油与天然气化工,2009,38(2):105-108.(hegang,gaoqin-wei.deactivationstudyonmk101catalyst[j].chemicalengineeringofoil&gas,2009,38(2):105-108.)
|
| [15] | 庄会栋,白绍芬,刘欣梅,阎子峰.cu/zro2催化剂的结构及其co2加氢合成甲醇催化反应性能[j].燃料化学学报,2010,38(4):462-467.(zhuanghui-dong,baishao-fen,liuxin-mei,yanzi-feng.structureandperformanceofcu/zro2catalystforthesynthesisofmethanolfromco2hydrogenation[j].journaloffuelchemistryandtechnology,2010,38(4):462-467.)
|
| [16] | 翟旭芳,社本纯,解红娟,谭猗生,韩怡卓,椿范立.浆态相甲醇合成催化剂的失活机理[j].催化学报,2007,28(1):51-56.(zhaixu-fang,sheben-chun,xiehong-juan,tanqi-sheng,hanyi-zhuo,tsubakin.deactivationmechanismofcu-basedcatalystformethanolsynthesisinslurryphase[j].chinesejournalofcatalysis,2007,28(1):51-56.)
|
| [17] | 左宜赞,张强,韩明汉,王金福,王铁锋,王德峥,金涌.铜基甲醇催化剂的高温烧结[j].催化学报,2009,30(7):624-630.(zuoyi-zan,zhangqiang,hanming-han,wangjin-fu,wangtie-feng,wangde-zheng,jinyong.thesinteringofacu-basedmethanolsynthesiscatalyst[j].chinesejournalofcatalysis,2009,30(7):624-630.)
|
| [18] | 丰中田,裴学国,唐海涛.甲醇合成催化剂失活原因分析及延长使用寿命的方法[j].煤化工,2007,(4):41-43.(fengzhong-tian,peixue-guo,tanghai-tao.causesofdeactivationofcatalystformethanolsynthesisandmethodtoprolongitslifetime[j].coalchemicalindustry,2007,(4):41-43.)
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