|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
双核金属酞菁的制备及其对二苯并噻吩的催化氧化性能
, PP. 1493-1499
Keywords: 双核酞菁钴,二苯并噻吩,催化氧化,脱硫
Abstract:
？采用微波法合成了双核酞菁钴,并采用红外光谱、紫外可见光谱、热重分析对其进行表征。以二苯并噻吩(dbt)为反应底物,考察双核酞菁钴对dbt催化氧化性能,筛选出较优催化剂,并进行脱硫反应工艺条件优化。结果表明,双核酞菁钴具有较好的催化性能,在室温下、双核酞菁钴用量为0.01g(cat)/5ml、空气流量为80ml/min、反应温度为40℃、反应1h,dbt脱硫率达到97.17%。催化剂重复使用5次,催化效果无明显下降。氧化产物经红外光谱、质谱分析为dbto2。对芳香烃及烯烃进行了催化氧化实验,发现该工艺对油品的质量基本无影响。
| [1] | 高庆毓,高跃.浅谈汽车尾气污染与治理[j].中国产经,2013,5:42-43.(gaoqing-yu,gaoyue.theautomobileexhaustpollutionandcontrol[j].industryofchina,2013,5:42-43.)
|
| [2] | 赵地顺,张娟,孙增涛,王佳蕾.活性炭负载tio2光催化氧化二苯并噻吩的研究[j].燃料化学学报,2008,36(3):322-325.(zhaodi-shun,zhangjuan,sunzeng-tao,wangjia-leistudyonphotocatalyticoxidationofdibenzothiophenebyactivatedcarbonsupportedtio2[j].journaloffuelchemistryandtechnology,2008,36(3):322-325.)
|
| [3] | jabbarnezhadp,haghighim,taghavinezhadp.sonochemicalsynthesisofnimo/al2o3-zro2nanocatalyst:effectofsonicationandzirconialoadingoncatalyticpropertiesandperformanceinhydrodesulfurizationreaction[j].fuelprocesstechnol,2014,126:392-401.
|
| [4] | wangh,wuy,liuzw,hel,yaozy,zhaowy.depositionofwo3onal2o3viaamicrowavehydrothermalmethodtopreparehighlydispersedw/al2o3hydrodesulfurizationcatalyst[j].fuel,2014,136:185-193.
|
| [5] | 裴玉同,罗勇,吴向阳,李建龙,宋家龙.改性nay分子筛吸附脱硫性能的研究[j].高校化学工程学报,2012,25(6):1078-1083.(peiyu-tong,luoyong,wuxiang-yang,lijian-long,songjia-long.performanceofadsorptivedesulfurizationovermodifiednayzeolite[j].journalofchemicalengineeringofchineseuniversities,2012,25(6):1078-1083.)
|
| [6] | 张傑,黄崇品,陈标华,李英霞,乔聪震.用离子液体萃取脱除汽油中的硫化物[j].燃料化学学报,2005,33(4):431-434.(zhangjie,huangchong-pin,chenbiao-hua,liying-xia,qiaocong-zhen.extractivedesulfurizationfromgasolineby[cu2cl3\[j].journaloffuelchemistryandtechnology,2005,33(4):431-434.)
|
| [7] | 戴咏川,亓玉台,赵德智,张会成.柴油在超声波/cu2+/h2o2中的氧化脱硫[j].燃料化学学报,2007,35(2):188-191.(daiyong-chuan,qiyu-taizhaode-zhi,zhanghui-cheng.ultrasoundoxidativedesulfurizationofdieseloilwithcopperionandhydrogenperoxide[j].journaloffuelchemistryandtechnology,2007,35(2):188-191.)
|
| [8] | chamackm,mahjoubar,aghayanh.cesiumsaltsoftungsten-substitutedmolybdophosphoricacidimmobilizedontoplateletmesoporoussilica:efficientcatalystsforoxidativedesulfurizationofdibenzothiophene[j].chemengj,2014,255:686-694.
|
| [9] | garcía-gutiérrezjl,laredogc,garcía-gutiérrezp,jimnez-cruzf.oxidativedesulfurizationofdieselusingpromisingheterogeneoustungstencatalystsandhydrogenperoxide[j].fuel,2014,138:118-125.
|
| [10] | muratas,muratak,kidenak,nomuram.anoveloxidativedesulfurizationsystemfordieselfuelswithmolecularoxygeninthepresenceofcobaltcatalystsandaldehydes[j].energyfuel,2004,18(l):116-121.
|
| [11] | huangz,baoh,yaoy,luw,chenw.novelgreenactivationprocessesandmechanismofperoxymonosulfatebasedonsupportedcobaltphthalocyaninecatalyst[j].applcatalb:environ,2014,154:36-43.
|
| [12] | ghasemim,daudwrw,rahimnejadm,rezayim,fatemia,jafariy,somalumr,manzoura.copper-phthalocyanineandnickelnanoparticlesasnovelcathodecatalystsinmicrobialfuelcells[j].intjhydrogenenergy,2013,38(22):9533-9540.
|
| [13] | 许恒哲,乐园,陈建峰.超细酞菁蓝微粒的制备及其电泳性能的研究[j].高校化学工程学报,2009,23(4):639-643.(xuheng-zhe,leyuan,chenjian-feng.preparationofphthalocyaninebluenanocrystalsandtheirelectrophoreticproperties[j].journalofchemicalengineeringofchineseuniversities,2009,23(4):639-643.)
|
| [14] | 冯海霞,张智慧,朱志昂,严诗楷,王传忠.金属酞菁催化巯基乙醇氧化的研究[j].燃料化学学报,1998,26(6):516-520.(fenghai-xia,zhangzhi-hui,zhuzhi-ang,yanshi-kai,wangchuan-zhong.studyoncatalyzedoxidationof2-mercaptoehanolbymetallophthalocyanine[j].journaloffuelchemistryandtechnology,1998,26(6):516-520.)
|
| [15] | zhouxr,lij,wangxn,jink,maw.oxidativedesulfurizationofdibenzothiophenebasedonmolecularoxygenandironphthalocyanine[j].fuelprocesstechnol,2009,90(2):317-323.
|
| [16] | 赵地顺,任红威,马四国,刘翠微.催化裂化汽油的相转移催化氧化脱硫反应研究[j].化学学报,2006,64(20):2086-2090.(zhaodi-shun,renhong-wei,masi-guo,liucui-wei.studyofoxidativedesulfurizationoffluidcatalyticcrackinggasolinebyphasetransfercatalysis[j].actachimisinica,2006,64(20):2086-2090.)
|
| [17] | zhangj,lij,rent,huy,gej,zhaod.oxidativedesulfurizationofdibenzothiophenebasedonairandcobaltphthalocyanineinionicliquid[j].rscadv,2014,4(7):3206-3210.
|
| [18] | ilievv,mihaylovaa,bilyarskalp.oxidationofphenolsinaqueoussolution,catalyzedbymononuclearandpolynuclearmetalphthalocya,ninecomplexes[j].jmolcatala:chem,2002,184(1/2):121-130.
|
| [19] | yangj,vand,markmr.synthesisofbinuclearphthalocyaninessharingabenzeneornaphthalenering[j].tetrahedronlett,1993,34(33):5223-5226.
|
| [20] | 杨欣雨.溴代酞菁配合物的合成及其对锂/亚硫酰氯电池催化性能的研究[d].西安:西北大学,2009.(yangxin-yu.synthesisofbrominatedphthalocyaninecomplexesandtheirstudyoflithium/thionylchloridebatteriescatalyticproperties[d].xi-an:northwestuniversity,2009.)
|
| [21] | shiraih,hanabusak,kitamuram,masudae,hirabaruo,hojon.synthesisandpropertiesofmetalcomplexes[j].makromolchem,1984,185:2537-2542.
|
| [22] | 胡晓明.双核酞菁铁电催化性能研究[d].北京:北京工业大学,2012.(huxiao-ming.studyofelectriccatalyticpropertiesofbiunclearironpthalocyanine[d].beijing:beijinguniversityoftechnology,2012.)
|
| [23] | 陈文兴,姚玉元,吕素芳,陈海相,胡智文,余志成.平面双核金属酞菁衍生物的催化氧化性能[j].化工学报,2004,55(6):924-928.(chenwen-xing,yaoyu-yuan,lvsu-fang,chenxiang-hai,huzhi-wen,yuzhi-cheng.catalyticoxidationactivityofplanarbinuclearmetal-phthalocyaninederivatives[j].journalofchemicalindustryandengineering,2004,55(6):924-928.)
|
| [24] | libt,zhouxx,wangxj.hybridbinuclear-cobalt-phthalocyanineasoxygenreductionreactioncatalystinsinglechambermicrobialfuelcells[j].jpowersources,2014,272:320-327.
|
| [25] | 陈文兴,魏莉莉,汪进前,姚玉元,吕慎水,陈世良.平面双核铜酞菁催化氧化硫醇[j].中国科学:b辑,2006,36(4):299-303.(chenwen-xing,weili-li,wangqian-jin,yaoyu-yuan,lvshen-shui,chenshi-liang.planarbinuclearcopperphthalocyaninecatalyzedoxidationofthiols[j].scienceinchina:seriesb,2006,36(4):299-303.)
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
