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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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固体氧化物直接碳燃料电池阳极反应过程分析
, PP. 1100-1105
Keywords: 直接碳燃料电池,碳燃料,阳极反应,活性炭,半焦,石墨
Abstract:
？以氧化钇稳定的氧化锆(ysz)为电解质组装成直接碳燃料电池(dcfc),分别以活性炭(ac)、石墨(g)、神府半焦(sc)作为dcfc燃料,研究了碳燃料的特性、电池操作温度以及阳极反应气氛等对dcfc阳极反应过程的影响。结果表明,三种碳燃料在空气、co2气氛中氧化反应活性顺序为ac>sc>g,当三种碳材料作为dcfc燃料时,活性炭作为燃料的dcfc性能最好,半焦燃料次之,石墨作为燃料的dcfc性能最差,而且燃料反应活性与其表面含氧官能团、孔隙结构有关;dcfc的阳极反应过程存在碳燃料直接氧化为co2、co2与c反应转化为co,以及co氧化为co2等。
| [1] | debruijinf.thecurrentstatusoffuelcelltechnologyformobileandstationaryapplications[j].greenchem,2005,7:132-150.
|
| [2] | adamcr,sarbjitg,sukhvinderpsb,bradleypl,sankarb.reviewoffuelsfordirectcarbonfuelcells[j].energyfuels,2012,26:1471-1488.
|
| [3] | giddeys,badwalsps,kulkarnia,munningsc.acomprehensivereviewofdirectcarbonfuelcelltechnology[j].progenergycombustsci,2012,38(3):360-399.
|
| [4] | tsuchiyam,laibk,ramanathans.scalablenanostructuredmembranesforsolid-oxidefuelcells[j].natnanotechnol,2011,6:282-286.
|
| [5] | fanld,wangcy,zhub.lowtemperatureceramicfuelcellsusingallnanocompositematerials[j].nanoenergy,2012,1(4):631-639.
|
| [6] | zhub,razar,qinhy,fanld.single-componentandthree-componentfuelcells[j].jpowersources,2011,196(15):6362-6365.
|
| [7] | liurz,zhaoch,lijl,zengfr,wangsr,wentl,wenzy.anoveldirectcarbonfuelcellbyapproachoftubularsolidoxidefuelcells[j].jpowersources,2010,195(2):480-482.
|
| [8] | nvrnbergers,buarr,desclauxp,frankeb,rzepkam,stimmingu.directcarbonconversioninasofc-systemwithanon-porousanode[j].energyenvironsci,2010,3:150-153.
|
| [9] | wujf,yuanxz,wanghj,blancoam,martinjj,zhangjj.diagnostictoolsinpemfuelcellresearch:partielectrochemicaltechniques[j].intjhydrogenenergy,2008,33(6):1735-1746.
|
| [10] | kulkarnia,giddeys,badwalsps.electrochemicalperformanceofceria-gadoliniaelectrolytebaseddirectcarbonfuelcells[j].solidstateionics,2011,194(1):46-52.
|
| [11] | tangyb,liuj.effectofanodeandboudouardreactioncatalystsontheperformanceofdirectcarbonsolidoxidefuelcells[j].intjhydrogenenergy,2010,35(20):11188-11193.
|
| [12] | caodx,suny,wanggl.directcarbonfuelcell:fundamentalsandrecentdevelopments[j].jpowersources,2007,167(2):250-257.
|
| [13] | wachsmaned,leekt.loweringthetemperatureofsolidoxidefuelcells[j].science,2011,334:935-939.
|
| [14] | elleucha,yujs,boussettaa,halouanik,liyd.electrochemicaloxidationofgraphiteinanintermediatetemperaturedirectcarbonfuelcellbasedontwo-phaseselectrolyte[j].intjhydrogenenergy,2013,38(20):8514-8523.
|
| [15] | lisw,leeac,mitchellre,gvrtm.directcarbonconversioninaheliumfluidizedbedfuelcell[j].solidstateionics,2008,179(27/32):1549-1552.
|
| [16] | lic,shiyx,cains.effectofcontacttypebetweenanodeandcarbonaceousfuelsondirectcarbonfuelcellreactioncharacteristics[j].jpowersources,2011,196(10):4588-4593.
|
| [17] | wuyz,suc,zhangcm,ranr,shaozp.anewcarbonfuelcellwithhighpoweroutputbyintegratingwithinsitucatalyticreverseboudouardreaction[j].electrochemcommun,2009,11(6):1265-1268.
|
| [18] | chenmm,wangcy,niuxm,zhaos,tangj,zhub.carbonanodeindirectcarbonfuelcell[j].intjhydrogenenergy,2010,35(7):2732-2736.
|
| [19] | dudekm,tomczykp.compositefuelfordirectcarbonfuelcell[j].cataltoday,2011,176(1):388-392.
|
| [20] | elleucha,boussettaa,halouanik.analyticalmodelingofelectrochemicalmechanismsinco2andco/co2producingdirectcarbonfuelcell[j].jelectroanalchem,2012,668:99-106.
|
| [21] | sundmacherk,schultzbt,zhous,scottk,ginkelm,gillesed.dynamicsofthedirectmethanolfuelcell(dmfc):experimentsandmodel-basedanalysis[j].chemengsci,2001,56(2):333-341.
|
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