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先锋褐煤的热处理和水热处理改质

, PP. 1032-1037

Keywords: 先锋褐煤,热处理,水热处理,结构表征

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Abstract:

?通过先锋褐煤热处理和水热处理,结合处理煤结构与性质表征,研究了热处理和水热处理对先锋褐煤结构、抽提和溶胀性能的影响,探讨了热处理过程水的作用。结果表明,低于热解温度下的热处理以非共价键解缔合及部分弱共价键热解为主,水与煤的水热反应能够抑制水热处理过程中煤的热解和小分子化合物释放。高温热处理以热解和脱氧为主,水热反应可以稳定煤热解活性基团,避免其二次裂解和交联,在一定程度上提高处理煤的混合溶剂抽提率,改善其溶胀性能。

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