全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

水溶性配合物催化的稠油低温热裂解研究

, PP. 443-448

Keywords: 稠油,低温,清洁,催化热裂

Full-Text   Cite this paper   Add to My Lib

Abstract:

?在一种新型稠油低温裂解催化体系中合成了两个系列10个过渡金属配合物催化剂。该反应体系中水对原油热降解反应有一定的影响,合适的用量水/油(质量比)为0.3。部分合成水溶性催化剂180℃下对稠油热裂解具有明显的催化作用,催化剂n5的降凝作用效果最好,经催化水热降解改质反应后原油的凝点降低11.4℃;催化剂n2和n5的催化降黏效果较好,降黏率可达70%以上,催化剂n5的最佳用量为0.5%;热重分析和气相色谱分析显示原油热催化降解反应后轻质组分明显增加。

References

[1]  何贤杰,刘增洁,吴初国,盛昌明.我国石油安全评价及建议[j].国土资源情报,2012,(10):1-7.(hexian-jie,liuzeng-jie,wuchu-guo,shengchang-ming.thesecurityevaluationandrecommendationofchina'soil[j].landresourceinformation,2012,(10):1-7.)
[2]  杨凯,唐晓东,刘付臣.稠油井下改质降粘技术的研究进展[j].石油与天然气化工,2011,40(5):499-502.(yangkai,tangxiao-dong,liufu-chen.techniquesstudyprogressofheavyoildownholeupgradingandviscosityreduction[j].chemicalengineeringofoil&gas,2011,40(5):499-502.)
[3]  kataritzkyar,siskinm.aquathermolysis:reactionsoforganiccompoundswithsuperheatedwater[j].accchemres,1996,29(8):399-406.
[4]  吴川.双亲型稠油水热裂解降粘催化剂的合成及反应机理研究.北京:中国石油大学,2011.(wuchuan.synthesisofamphiphiliccatalystandstudyitsmechanismforheavyoilbyaquathermolysisreaction.beijing:chinauniversityofpetroleum,2011.)
[5]  程红晓,赵长喜,王晓东,郑会,徐立,陈军.催化降粘剂作用下河南稠油族组成变化研究[j].石油化工应用,2011,30(12):70-72.(chenghong-xiao,zhaochang-xi,wangxiao-dong,zhenghui,xuli,chenjun.studyonconstituentschangesofheavyoilsundertreatmentofcatalyticviscosity-reducingagent[j].petrochemicalindustryapplication,2011,30(12):70-72.)
[6]  clarkpd,hynejb,tyrerjd.chemistryoforganosulfurcompoundtypeoccurringinheavyoilsands:3.reactionofthiopheneandtetrahydro-thiophenewithvanadylandnickelsalts[j].fuel,1984,63(6):1649-1645.
[7]  刘永建,陈尔跃,闻守斌,刘春天.用油酸钼和石油磺酸盐强化辽河油田稠油降粘的研究[j].石油与天然气化工,2005,34(6):511-512.(liuyong-jian,chener-yue,wenshou-bin,liuchun-tian.thepreparationandevaluationofoil-solublecatalystforaquathermolysisofheavyoil[j].chemicalengineeringofoil&gas,2005,34(6):511-512.)
[8]  arnoldm,brownda,deego,erringtonw,haasew,herlihyk,kemptj,nimirh,wernerr.hydroxamate-bridgeddinuclearnickelcomplexesasmodelsforureaseinhibition[j].inorgchem,1998,37(12):2920-2925.
[9]  韩晓强,李爱军,刘琼.稠油含水对粘度影响探讨[j].新疆石油科技,2010,20(4):48-50.(hanxiao-qiang,liai-jun,liuqiong.studyoftheeffectofthewaterinheavyoilonviscosity[j].xijiangpetroleumscience&technology,2010,20(4):48-50.)
[10]  李恩田,王树立,赵会军,申龙涉,王为民.含水超稠油表观粘度的试验与研究[j].油气储运,2007,26(11):52-55.(lien-tian,wangshu-li,zhaohui-jun,shenlong-she,wangwei-min.experimentalstudyonapparentviscosityofwatercutsuper-heavyoils[j].oilandgasstorageandtransportation,2007,26(11):52-55.)
[11]  clarkpd,hynejb,tyrerjd.chemistryoforgansulfurcompoundtypeoccurringinheavyoilsands:4.thehightemperaturereactionofhiopheneandtetrahydro-thiophenewithaqueoussolutionofaluminiumandfirstrowtransition-metalcations[j].fuels,1987,66(5):1353-1357.
[12]  clarkpd,hynejb,tyrerjd.chemistryoforganosulfurcompoundtypeoccurringinheavyoilsands:5.reactionofthiopheneandtetrahydro-thiophenewithaqueousgroupⅷbmetalspeciesathightemperature[j].fuels,1987,66(5):1699-1702.
[13]  赵长喜,郑延成,陈奇,石步乾,程红晓.有机钼氧化体系对南阳稠油粘度的影响[j].石油天然气学报(江汉石油学院学报),2007,29(3):464-467.(zhaochang-xi,zhengyan-cheng,chenqi,shibu-qian,chenghong-xiao.effectofoxidatingsystemcontainingorganicmoonheavyoilviscosityofnanyangoilfield[j].journalofoilandgastechnology(j1jpi),2007,29(3):464-467.)
[14]  范洪福.辽河稠油水热裂解反应研究与应用[d].黑龙江:大庆石油学院,2002.(fanhong-fu.studyandapplicationofaquathermolysisforliaoheheavyoils[d].heilongjiang:northeastpetroleumuniversity,2002.)
[15]  nishiday,yamadak.lipoxygenase-likefunctionofsomebinucleariron(ⅱ)complexes[j].jchemsocdaltontrans,1990:3639-3641.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133