|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
磺化salen金属配合物插层水滑石选择性催化氧化甘油制备二羟基丙酮的研究
, PP. 677-683
Keywords: 甘油,二羟基丙酮,磺化salen金属配合物,非均相催化剂,选择性氧化
Abstract:
？制备了一系列含不同金属离子的磺化salen金属配合物插层水滑石催化剂用于甘油催化氧化制备二羟基丙酮(dha)。利用x射线粉末衍射(xrd)、傅里叶变换红外光谱(ft-ir)及电感耦合等离子发射光谱(icp)分析手段对催化剂进行了表征。结果表明,磺化salen配体插入镁铝水滑石(ldh)层板间,金属离子与磺化salen配体配合,制备出磺化salen金属配合物插层的水滑石非均相催化剂。反应结果表明,含cr3+及含cu2+催化剂有利于h2o2活化,催化活性较高,含cu2+催化剂利于甘油脱氢,dha选择性较高。含cu2+催化剂用于甘油催化氧化反应时,在ph值为7、60℃条件下反应4h,甘油转化率为40.3%,dha选择性达到52.9%。
| [1] | 何延青,吴永强,闻建平.生物柴油生产及其副产物甘油的有效利用[j].中国油脂,2007,32(5):47-51.(heyan-qing,wuyong-qiang,wenjian-ping.productionofbiodieselandutilizationofitsby-productglycerol[j].chinaoilsfats,2007,32(5):47-51.)
|
| [2] | 许晓菁,陈询,晋明芬,武晓炜,王祥河.微生物法生产二羟基丙酮的研究进展[j].生物工程学报,2009,25(6):903-908.(xuxiao-jing,chenxun,jinming-fen,wuxiao-wei,wangxiang-he.advanceindihydroxyacetoneproductionbymicrobialfermentation[j].chinjbiotechnol,2009,25(6):903-908.)
|
| [3] | 宋如,钱仁渊,仝艳,云志.二羟基丙酮生产研究进展[j].化工技术与开发,2009,38(7):25-30.(songru,qianren-yuan,tongyan,yunzhi.researchadvancesindihydroxyacetoneproduction[j].technoldevchemind,2009,38(7):25-30.)
|
| [4] | 周洁,赵宁,肖福魁,魏伟,孙予罕.bi-pt催化剂在h-mordenite载体上的甘油选择性氧化[j].燃料化学学报,2012,40(11):1323-1327.(zhoujie,zhaoning,xiaofu-kui,weiwei,sunyu-han.selectiveoxidationofglyceroloverbi-ptcatalystonh-mordenite[j].jfuelchemtechnol,2012,40(11):1323-1327.)
|
| [5] | hiroshik,keiichit.selectiveoxidationofglycerolonaplatinum-bismuthcatalys[j].applcatala:gen,1993,96(2):217-228.
|
| [6] | 谢艳丽,赵振东,白洋,刘艳凤.含铂多金属催化剂的合成及其对甘油选择性催化氧化作用的研究[j].海南师范大学学报(自然科学版),2007,20(3):251-255,288.(xieyan-li,zhaozhen-dong,baiyang,liuyan-feng.studiesonthesynthesisofptm/cmulti-metallicbimetalliccatalystsandtheircatalyticpropertiesontheselectiveoxidationofglycerol[j].jhainannormuniv(natsci),2007,20(3):251-255,288.)
|
| [7] | nier,lingd,shenl,gaoj,chenp,houz.selectiveoxidationofglycerolwithoxygeninbase-freesolutionovermwcntssupportedptsballoynanoparticles[j].applcatalb:environ,2012,127:212-220.
|
| [8] | hirasawas,watanabeh,kizukat,nakagaway,tomishigek.performance,structureandmechanismofpd-agalloycatalystforselectiveoxidationofglyceroltodihydroxyacetone[j].jcatal,2013,300:205-216.
|
| [9] | liuss,sunkq,xubq.specificselectivityofau-catalyzedoxidationofglycerolandotherc3-polyolsinwaterwithoutthepresenceofabase[j].acscatal,2014,4(7):2226-2230.
|
| [10] | painterrm,pearsondm,waymouthrm.selectivecatalyticoxidationofglyceroltodihydroxyacetone[j].angewcheminted,2010,49(49):9456-9459.
|
| [11] | wangxl,wugd,wangf,dingkq,zhangf,liuxf,xueyb.base-freeselectiveoxidationofglycerolwith3%h2o2catalyzedbysulphonato-salen-chromium(iii)intercalatedldh[j].catalcommun,2012,28:73-76.
|
| [12] | crottic,farnettie.selectiveoxidationofglycerolcatalyzedbyironcomplexes[j].jmolcatala:chem,2015,396:353-359.
|
| [13] | wugd,wangxl,lijp,zhaon,weiw,sunyh.anewroutetosynthesisofsulphonato-salen-chromium(iii)hydrotalcites:highlyselectivecatalystsforoxidationofbenzylalcoholtobenzaldehyde[j].cataltoday,2008,131(1/4):402-407.
|
| [14] | wangj,weim,raogy,evansdg,duanx.structureandthermaldecompositionofsulfatedβ-cyclodextrinintercalatedinalayereddoublehydroxide[j].jsolidstatechem,2004,177(1):366-371.
|
| [15] | bhattacharjees,dinestj,andersonja.synthesisandapplicationoflayereddoublehydroxide-hostedcatalystsforstereoselectiveepoxidationusingmolecularoxygenorair[j].jcatal,2004,225(2):398-407.
|
| [16] | liudf,lüxq,lur.homogeneousandheterogeneousstyreneepoxidationcatalyzedbycopper(ii)andnickel(ii)schiffbasecomplexes[j].transitionmetalchem,2014,39(6):705-712.
|
| [17] | bhattacharjees,andersonja.comparisonoftheepoxidationofcyclohexene,dicyclopentadieneand1,5-cyclooctadieneoverldhhostedfeandmnsulfonato-salencomplexes[j].jmolcatala:chem,2006,249(1/2):103-110.
|
| [18] | cavanif,trifirof,vaccaria.hydrotalcite-typeanionicclays:preparation,propertiesandapplications[j].cataltoday,1991,11(2):173-301.
|
| [19] | yazdaniss,gonzalezr.anaerobicfermentationofglycerol:apathtoeconomicviabilityforthebiofuelsindustry[j].curropinbiotechnol,2007,18(3):213-219.
|
| [20] | brownda.skinpigmentationenhancers[j].jphotochemphotobiolb,2001,63(1/3):148-161.
|
| [21] | comberrn,reynoldsrc,friedrichjd,manguikianra,jrbuckheitrw,trussjw,shannonwm,secristjaiii.5,5-disubstitutedhydantoinssynthesesandanti-hivactivity[j].jmedchem,1992,35(19):3567-3572.
|
| [22] | garciar,bessonm,gallezotp.chemoselectivecatalyticoxidationofglycerolwithaironplatinummetals[j].applcatala:gen,1995,127(1/2):165-176.
|
| [23] | brandnera,lehnertk,bienholza,lucasm,clausp.productionofbiomass-derivedchemicalsandenergy:chemocatalyticconversionsofglycerol[j].topcatal,2009,52(3):278-287.
|
| [24] | singhs,patela.selectivegreenesterificationandoxidationofglycerolover12-tungstophosphoricacidanchoredtomcm-48[j].indengchemres,2014,53(38):14592-14600.
|
| [25] | shigeom.anion-exchangepropertiesofhydrotalcite-likecompounds[j].clayclayminer,1983,31(4):305-311.
|
| [26] | bhattacharjees,andersonja.synthesisandcharacterizationofnovelchiralsulfonato-salen-manganese(iii)complexinazinc-aluminiumldhhost[j].chemcommun,2004,(5):554-555.
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
