全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

基于赤铁矿的生物质化学链燃烧过程中氮氧化物的释放特性

, PP. 490-498

Keywords: 化学链燃烧,生物质,赤铁矿,氮氧化物

Full-Text   Cite this paper   Add to My Lib

Abstract:

?在单批次进料固定床上,基于赤铁矿载氧体,研究了还原反应阶段反应温度和水蒸气量对谷壳的氮氧化物释放特性的影响。研究表明,碳转化率随反应温度升高而增加,但随水蒸气量呈先增加后下降,并在水蒸气量为1.0g/min时达到最大值。在实验条件下,还原阶段未检测到no2。随着反应温度由750℃升高到900℃,no的生成率增加,而n2o的生成率先增加后降低,在850℃时达到最大值。水蒸气量由0.5g/min升高到2.0g/min,n2o和no的生成率均增加,且no增加速率高于n2o。在反应后的载氧体中,检测到kalsi3o8存在,表明载氧体与生物质中的k元素发生反应。

References

[1]  柏继松.生物质燃烧过程氮和硫的迁移、转化特性研究[d].浙江:浙江大学,2012.(boji-song.nitrogenandsulfurconversionmechanismduringbiomasscombustion[d].zhejiang:zhejianguniversity,2012.)
[2]  zhouh,jensenad,glarborgp,kavaliauskasa.formationandreductionofnitricoxideinfixed-bedcombustionofstraw[j].fuel,2006,85(5/6):705-716.
[3]  wertherj,ogadt.sewagesludgecombustion[j].progenergycombustsci,1999,25(1):55-116.
[4]  prakashpk,sheebanarayanan.hydrogenproductionfromsteamgasificationofbiomassinfluenceofprocessparametersonhydrogenyield-areview[j].renewenergy,2014,66:570-579.
[5]  常丽萍.煤热解、气化过程中含氮化合物的生成与释放研究[d].太原:太原理工大学,2004.(changli-ping.studyontheformationandreleaseofnitrogen-containingcompoundsduringcoalpyrolysisandgasification[d].taiyuan:taiyuanuniversityoftechnology,2004.)
[6]  furimskye,ohtsukay.formationofnitrogen-containingcompoundsduringslowpyrolysisandoxidationofpetroleumcoke[j].energyfuels,1997,11(5):1073-1080.
[7]  johnssonje.formationandreductionofnitrogenoxidesinfluided-bedcombustion[j].fuel,1994,73(9):1398-1415.
[8]  glarborgp,jensenad,johnssonje.fuelnitrogenconversioninsolidfuelfiredsystems[j].progenergycombustsci,2003,29(2):89-113.
[9]  黄容,高瑗,高明,廖燕妮,陈佳烨.生物质灰渣物质特性和保水性的研究[j].水土保持学报,2013,(6):130-133.(huangrong,gaoyuan,gaoming,liaoyan-ni,chenjia-ye.studyonmaterialpropertiesandwaterabsorptioncapacityofbiomassash[j].jsoilwaterconserv,2013,(6):130-133.)
[10]  肖瑞瑞,陈雪莉,王辅臣,于广锁.不同生物质灰的理化特性[j].太阳能学报,2011,(3):364-369.(xiaorui-rui,chenxue-li,wangfu-chen,yuguang-suo.thephysicochemicalpropertiesofdifferentbiomassash[j].actaenergysolsin,2011,(3):364-369.)
[11]  leionh,mattissont,lyngfelta.solidfuelsinchemical-loopingcombustion[j].intjgreenhousegascontrol,2008,2(2):180-193.
[12]  leionh,mattissont,lyngfelta.theuseofpetroleumcokeasfuelinchemical-loopingcombustion[j].fuel,2007,86(12/13):1947-1958.
[13]  berguern,lyngfelta.designandoperationofa10kwthchemical-loopingcombustorforsolidfuels-testingwithsouthafricancoal[j].fuel,2008,872(12):2731-2726.
[14]  leionh,lyngfelta.johhanssonm,jerndale.mattissont.theuseofilmeniteasanoxygencarrierinchemical-loopingcombustion[j].chemengresdes,2008,86(9):1017-1026.
[15]  berguern,lyngfelta.theuseofpetroleumcokeasfuelina10kwthchemical-loopingcombustor[j].intjgreenhousegascontrol,2008,2(2):169-179.
[16]  mattissont,lyngfelta,chop.theuseofironoxideasanoxygencarrierinchemical-loopingcombustionofmethanewithinherentseparationofco2[j].fuel,2001,80(13):1953-1962.
[17]  leionh,mattissont,lyngfelta.solidfuelsinchemical-loopingcombustion[j].intjgreenhousegascontrol,2008,2(2):180-193.
[18]  shenlh,wujh,xiaoj.experimentonchemicalloopingcombustionofcoalwithniobasedoxygencarrier[j].combustflame,2009,156(3):721-728.
[19]  mendiarat,abada,dediegolf,garcía-labianof,gaynp,adnezj.biomasscombustioninaclcsystemusinganironoreasanoxygencarrier[j].intjgreenhousegascontrol,2013,11(19):322-330.
[20]  guhm,shenlh,zhongzp,niux,gehj,zhouyf,xiaos,jiangsx.noreleaseduringchemicalloopingcombustionwithironoreasanoxygencarrier[j].chemengj,2015,264:211-220.
[21]  songt,shenlh,xiaoj,chendq,guhm,zhangsw.nitrogentransferoffuel-ninchemicalloopingcombustion[j].combustflame,2012,159(3):1286-1295.
[22]  sungrs,sangdk.chemical-loopingcombustionwithnioandfe2o3inathermobalanceandcirculatingfluidizedbedreactorwithdoubleloops[j].indengchemres,2006,45(8):2689-2696.
[23]  吴家桦,沈来宏,肖军,王雷,郝建刚.10kwth级串行流化床木屑化学链燃烧试验[j].化工学报,2009,60(8):2080-2088.(wujia-hua,shenlai-hong,xiaojun,wanglei,haojian-gang.experimentsonchemicalloopingcombustionofsawdustina10kwthinterconnectedfluidizedbed[j].jchemindeng,2009,60(8):2080-2088.)
[24]  shenlh,wujh,xiaoj,wangl,haojg.chemical-loopingcombustionofbiomassina10kwthreactorwithironoxideasanoxygencarrier[j].energyfuels,2009,23(5):2498-2505.
[25]  苟进胜,常建民,任学勇.生物质热解过程中氮元素迁移规律研究进展[j].科技导报,2012,(14):70-74.(goujin-sheng,changjian-min,renxue-yong.areviewonthereleasecharacterizationofnitrogenspeiciesduringbiomasspyrolysis[j].scitechnolrev,2012,(14):70-74.)
[26]  abelhap,gulyurtlu,cabritai.releaseofnitrogenprecursorsfromcoalandbiomassresiducesinabubblingfluidizedbed[j].energyfuels,2008,22(1):363-371.
[27]  黄振,何方,李新爱,赵坤,李海滨,赵增立.fe2o3-水蒸气生物质化学链共气化制合成气[j].太阳能学报,2013,34(12):2056-2062.(huangzhen,hefang,lixin-ai,zhaokun,lihai-bin,zhaozeng-li.syngasgeneratedbychemical-loopinggasificationofbiomassusingfe2o3asoxygencarrierinpresenceofsteam[j].actaenergysolsin,2013,34(12):2056-2062.)
[28]  kellerm,leionh,mattissont,lyngfelta.gasificationinhibitioninchemical-loopingcombustionwithsolidfuels[j].combustflame,2011,158(3):393-400.
[29]  guh,shenl,xiaoj,zhangs,songt,chemicalloopingcombustionofbiornass/coalwithnaturalironoreoxygencarrierinacontinuousreactor[j].energyfuels,20l1,5(1):446-455.
[30]  郝建刚,吴家桦,王雷,沈来宏,肖军.基于fe基载氧体的生物质化学链燃烧试验研究[j].锅炉技术,2010,(2):65-70.(haojian-gang,wujia-hua,wanglei,shenlai-hong,xiaojun.experimentsonchemicalloopingcombustionofbiomasswithafe2o3basedoxygencarrier[j].boilertechnol,2010,(2):65-70.)

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133