|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
吡啶离子液体催化作用下的fcc汽油烷基化脱硫
, PP. 442-448
Keywords: fcc汽油,吡啶,离子液体,烷基化,硫转移,脱硫
Abstract:
？合成一种br？nsted酸性离子液体[bpy]hso4,采用红外光谱和核磁共振对其进行表征。以[bpy]hso4为催化剂,对fcc汽油进行烷基化脱硫,考察反应温度、反应时间和剂油质量比对脱硫效果的影响及脱硫前后fcc汽油性质的变化,并对[bpy]hso4进行了再生。结果表明,在反应温度为65℃、反应时间为90min和剂油质量比为0.09的条件下,fcc汽油的硫含量从580.0μg/g降至6.4μg/g,脱硫率为98.90%,满足中国国ⅴ车用汽油硫含量标准(<10μg/g);脱硫前后硫分布变化表明,在[bpy]hso4的催化作用下,前170℃馏分油中硫化物大部分转移到后170℃重馏分中,重馏分中硫化物可采用加氢方法进行脱除;pona组成变化表明,烷基化脱硫过程对fcc汽油的烃类组成影响较小,且脱硫前后辛烷值变化不大;[bpy]hso4经萃取再生后可循环使用。
| [1] | 任杰,张运湘,慎炼.催化汽油氧气氧化及萃取脱硫的数学模拟[j].石油学报(石油加工),2010,26(1):60-63.(renjie,zhangyun-xiang,shenlian.mathematicalsimulationofdesulfurizationofcatalyticcrackinggasolinethroughoxygenoxidationandextraction[j].actapetrolsin(petprocesssection),2010,26(1):60-63.)
|
| [2] | 徐康文,冯丽娟,王景刚,李宁慧,李春虎.介孔cuo/sio2用于汽油氧化-吸附脱硫[j].石油学报(石油加工),2012,28(4):561-564.(xukang-wen,fengli-juan,wangjing-gang,lining-hui,lichun-hu.oxidation-adsorptiondesulfurizationgasolinebymesoporouscuo/sio2[j].actapetrolsin(petprocesssection),2012,28(4):561-564.)
|
| [3] | 任杰,袁海宽,吴利军,慎炼.催化汽油氧气氧化脱硫的反应动力学[j].化工学报,2010,61(1):66-71.(renjie,yuanhai-kuan,wuli-jun,shenlian.reactionkineticsforoxygenoxidationdesulfurizationofcatalyticcrackinggasoline[j].jchemindeng,2010,61(1):66-71.)
|
| [4] | dastanianm,seyedeyn-azadf.desulfurizationofgasolineovernanoporousnickel-loadedy-typezeoliteatambientconditions[j].indengchemres,2010,49(22):11254-11259.
|
| [5] | wangr,wanjb,liyh,sunhw.aninsightintoeffectofmethanoloncatalyticbehaviorofamberlyst35resinsforalkylationdesulfurizationoffluidcatalyticcrackinggasoline[j].fuel,2014,115:609-617.
|
| [6] | 黄蔚霞,李云龙,汪燮卿.离子液体在催化裂化汽油脱硫中的应用[j].化工进展,2004,23(3):297-299.(huangwei-xia,liyun-long,wangxie-qing.reducingsulfurcontentinfccnaphthabyusingionicliquid[j].chemindengprog,2004,23(3):297-299.)
|
| [7] | 唐晓东,郭巧霞,冯雪峰,金文中.fcc汽油烷基化脱硫的中试研究[j].石油炼制与化工,2011,42(1):37-39.(tangxiao-dong,guoqiao-xia,fengxue-feng,jinwen-zhong.pilotplanttestoffccgasolinedesulfurizationbyalkylation[j].petrolprocesspetrochem,2011,42(1):37-39.)
|
| [8] | 柯明,汤奕婷,曹文智,宋昭睁,蒋庆哲.离子液体在fcc汽油脱硫中的应用研究[j].西南石油大学学报(自然科学版),2010,32(3):145-149.(keming,tangyi-ting,caowen-zhi,songzhao-zheng,jiangqing-zhe.studyonapplicationofionicliquidsascatalystindesulfurizationffccgasoline[j].jsouthwestpetroluniv(sci&technoled),2010,32(3):145-149.)
|
| [9] | 张晓飞,徐新良,徐亚荣,王吉德.ti-mcm-41/h2o2·hcooh催化氧化模拟汽油中噻吩的选择氧化及动力学[j].石油学报(石油加工),2009,25(6):856-860.(zhangxiao-fei,xuxin-liang,xuya-rong,wangji-de.selectiveoxidayionandkineticsofti-mcm-41/h2o2·hcoohsystemforthiopheneinsimulatedgasoline[j].actapetrolsin(petprocesssection),2009,25(6):856-860.)
|
| [10] | 王青宁,张正才,谢振萍,吴应琴,李澜,焦林宏.凹凸棒黏土脱硫剂脱除rfcc汽油中的硫醇和硫醚[j].化工学报,2012,63(1):292-298.(wangqing-ning,zhangzheng-cai,xiezhen-ping,wuying-qin,lilan,jiaolin-hong.thiolandthioetherremovalfromrfccgasolinewithattapulgiteclay[j].jchemindeng,2012,63(1):292-298.)
|
| [11] | dupuyb,laforges,moraisc,bachmannc,magnouxp,richardf.alkylationof3-methylthiopheneby2-methyl-1-penteneoverhy,hbeaandhmcm-22acidiczeolites[j].applcatala:gen,2012,413-414:192-204.
|
| [12] | ariasm,laurentid,geantetc,vrinatm,hideyukii,yoshimuray.gasolinedesulfurizationbycatalyticalkylationoversilica-supportedheteropolyacids:frommodelreactiontorealfeedconversion[j].cataltoday,2008,130(1):190-194.
|
| [13] | ariasm,laurentid,bellirev,geantetc,vrinatm,yoshimuray.preparationofsupportedh3pw12040·6h2oforthiopheniccompoundsalkylationinfccgasoline[j].applcatala:gen,2008,348:142-147.
|
| [14] | 董森,王训遒,王亚涛,宁卓远,郭学华,付丽,李洪娟,陈志娟.氯铝酸离子液体的再生方法:中国,103521264a[p].2014-01-22.(dongsen,wangxun-qiu,wangya-tao,ningzhuo-yuan,guoxue-hua,fuli,lihong-juan,chenzhi-juan.amethodofchloroaluminateionicliquidregeneration:cn,103521264a[p].2014-01-22.)
|
| [15] | zhaods,wangyn,duaneh,zhangj.oxidationdesulfurizationoffuelusingpyridinium-basedionicliquidsasphase-transfercatalysts[j].fuelprocesstechnol,2010,91(12):1803-1806.
|
| [16] | shenlq,yinhb,wangal,luxf,zhangch,chenf,wangyt,chenhj.liquidphasecatalyticdehydrationofglyceroltoacroleinoverbrønstedacidicionicliquidcatalysts[j].jindengchem,2014,20(3):759-766.
|
| [17] | 王建龙,赵地顺,周二鹏,董芝.吡啶类离子液体在汽油萃取脱硫中的应用研究[j].燃料化学学报,2007,35(3):293-296.(wangjian-long,zhaodi-shun,zhouer-peng,dongzhi.desulfurizationofgasolinebyextractionwithn-alkyl-pyridinium-basedionicliquids[j].jfuelchemtechnol,2007,35(3):293-296.)
|
| [18] | zahngzk,liusl,zhuxx,wangqx,xuly.modificationofhβzeolitebyfluorineanditsinfluenceonolefinalkylationthiophenicsulfuringasoline[j].fuelprocesstechnol,2008,89(1):103-110.
|
| [19] | liuy,yangbl,yich,chent,liss.kineticsstudyof3-methylthiophenealkylationwithisobutylenecatalyzedbynkc-9ionexchangeresin[j].indengchemres,2011,50(16):9609-9616.
|
| [20] | 张泽凯,刘盛林,杜喜研,曾蓬,王清遐,徐龙伢.芳烃烷基化反应性能对烷基化脱除汽油中硫化物过程的影响[j].石油化工,2006,35(2):113-117.(zhangze-kai,liusheng-lin,duxi-yan,zengpeng,wangqing-xia,xulong-ya.alkylationsofaromticsandtheirinfluencesonthiophenesalkylationingasolineolefinicalkylationofthiophenicsulfur[j].petrochemtechnol,2006,35(2):113-117.)
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
